Search Results - "Daniels, Grant C"
-
1
Tailoring Amphiphilic Copolymers for Improved Aqueous Foam Stability
Published in Langmuir (27-06-2023)“…Amphiphilic copolymers of various-molecular-weight (MW) poly(ethylene glycol) (PEG) were synthesized via reversible addition–fragmentation chain transfer…”
Get full text
Journal Article -
2
Synthesis and kinetics of disassembly for silyl-containing ethoxycarbonyls using fluoride ions
Published in RSC advances (01-01-2018)“…In this study, a series of silyl-containing ethoxycarbonates and ethoxycarbamates on electron poor anilines and phenols were synthesized and their kinetics of…”
Get full text
Journal Article -
3
Hydrolytically Stable and Thermo-Mechanically Tunable Poly(Urethane) Thermoset Networks that Selectively Degrade and Generate Reusable Molecules
Published in ACS applied materials & interfaces (18-05-2022)“…Cross-linked polymeric networks that possess tunable properties and degrade on-demand have broad applications in today’s society. Herein, we report on…”
Get full text
Journal Article -
4
-
5
Environmental Effects on Zirconium Hydroxide Nanoparticles and Chemical Warfare Agent Decomposition: Implications of Atmospheric Water and Carbon Dioxide
Published in ACS applied materials & interfaces (15-11-2017)“…Zirconium hydroxide (Zr(OH)4) has excellent sorption properties and wide-ranging reactivity toward numerous types of chemical warfare agents (CWAs) and toxic…”
Get full text
Journal Article -
6
Copolymer Reversible Addition-Fragmentation Chain Transfer Synthesis of Polyethylene Glycol (PEG) Functionalized with Hydrophobic Acrylates: A Study of Surface and Foam Properties
Published in Langmuir (19-04-2022)“…A series of amphiphilic statistical copolymers involving poly(ethylene glycol) monomethacrylate (PEGMA, −OH terminated, average Mn 200 molecular weight) and…”
Get full text
Journal Article -
7
Air Activated Self‐Decontaminating Polydicyclopentadiene PolyHIPE Foams for Rapid Decontamination of Chemical Warfare Agents
Published in Macromolecular rapid communications. (01-06-2018)“…The threat of chemical warfare agents (CWA) compels research into novel self‐decontaminating materials (SDM) for the continued safety of first‐responders,…”
Get full text
Journal Article -
8
Rapid Decontamination of Chemical Warfare Agent Simulant with Thermally Activated Porous Polymer Foams
Published in Industrial & engineering chemistry research (27-06-2018)“…Highly porous poly(dicyclopentadiene) (pDCPD) foam was synthesized via ring opening metathesis polymerization and high internal phase emulsion (HIPE)…”
Get full text
Journal Article -
9
Stabilization of Bilgewater Emulsions by Shipboard Oils
Published in ACS ES&T water (13-08-2021)“…The removal of oil from bilgewater is necessary for compliance with national and international maritime regulations; however, the formation of stable…”
Get full text
Journal Article -
10
Multi‐Functional Polyurethane Hydrogel Foams with Tunable Mechanical Properties for Wound Dressing Applications
Published in Macromolecular materials and engineering (01-03-2017)“…Polyurethane hydrogel foams synthesized through a facile one‐pot, solvent‐free process are described. The roles of polyethylene glycol (PEG) molecular weight,…”
Get full text
Journal Article -
11
Conformal Nanoscale Zirconium Hydroxide Films for Decomposing Chemical Warfare Agents
Published in ACS applied nano materials (26-04-2019)“…Amorphous zirconium hydroxide (ZH) has attracted recent attention for its high decomposition reactivity with chemical warfare agents (CWA). Conformal, 50 nm…”
Get full text
Journal Article -
12
Synergistic antimicrobial and surface free energy of sol–gel coatings containing fluorosilanes and quaternary ammonium salts
Published in Progress in organic coatings (01-06-2016)“…[Display omitted] •A two component hybrid polysiloxane was formulated and surface analyzed.•Fluorosilane and antimicrobial additives were incorporated to…”
Get full text
Journal Article -
13
Physicochemical investigation of chemical paint removers. II: Role and mechanism of phenol in the removal of polyurethane coatings
Published in Progress in organic coatings (01-11-2015)“…•Simplified polyurethane top-coatings were formulated for study.•Bulk and molecular-level effects of simplified paint removers were studied.•Phenol is observed…”
Get full text
Journal Article -
14
Hemostatic kaolin-polyurethane foam composites for multifunctional wound dressing applications
Published in Materials Science & Engineering C (01-10-2017)“…There are numerous challenges associated with the acute care of traumatic limb injuries in forward military settings. A lack of immediate medical facilities…”
Get full text
Journal Article -
15
PFAS removal from water using quaternary amine functionalized porous polymers
Published in Chemical engineering journal (Lausanne, Switzerland : 1996) (01-11-2024)“…[Display omitted] •Quaternary amine functionalized polyHIPEs were synthesized for PFAS capture.•The best performer removed >98 % of long-chain and >75 % of…”
Get full text
Journal Article -
16
Iridium-Catalyzed Hydrosilylation of Polymeric Olefins: Moving beyond Platinum-Based Catalysts for Surfactants
Published in Industrial & engineering chemistry research (29-05-2024)“…A series of surfactants utilizing various molecular weight allyloxy(poly(ethylene oxide)s (PEOs) and siloxanes were successfully synthesized via…”
Get full text
Journal Article -
17
Solution and foam properties of polyethylene oxide-lauryl acrylate random comb polymers and aggregation behavior with alkylpolyglycoside surfactants
Published in Colloids and surfaces. A, Physicochemical and engineering aspects (20-11-2024)“…Thirteen statistical comb polymers were synthesized with varied molecular weight. The polymers were evaluated for their surface activity, foamability, foam…”
Get full text
Journal Article -
18
Impact of Cross-Linker Structure on the Properties of Durable and Selectively Degradable Silyl-Containing Polyurethane Networks
Published in ACS applied polymer materials (26-07-2024)“…Polyurethane (PU) networks with covalent cross-links provide unique strength and durability, which has led to their use in numerous modern-day materials…”
Get full text
Journal Article -
19
Assessment of opioid surrogates for spectroscopic testing (Part III)
Published in Forensic chemistry (01-09-2022)“…[Display omitted] •Training for vibrational spectrometers will benefit from safe, opioid surrogates.•Spectra of 30 surrogates compared to heroin, fentanyl, &…”
Get full text
Journal Article -
20
Synthesis, Characterization and Kinetics of Selectively Triggered Disassembling Polyurethane Thermosets
Published 01-01-2019“…Cross-linked polymeric networks are found in numerous consumer, medical, and industrial materials. However, cross-linked polymer materials require harsh…”
Get full text
Dissertation