Search Results - "Dale, A J"
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1
Ultrafast Observation of a Photoredox Reaction Mechanism: Photoinitiation in Organocatalyzed Atom-Transfer Radical Polymerization
Published in Journal of the American Chemical Society (31-01-2018)“…Photoredox catalysis has driven a revolution in the field of organic chemistry, but direct mechanistic insights into reactions of genuine synthetic utility…”
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2
Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N‐Aryl Anthranilamides
Published in Angewandte Chemie International Edition (02-10-2017)“…Diarylamines find use as metal ligands and as structural components of drug molecules, and are commonly made by metal‐catalyzed C−N coupling. However, the…”
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3
Heavy-Atom Kinetic Isotope Effects: Primary Interest or Zero Point?
Published in Journal of the American Chemical Society (22-12-2021)“…Chemists have many options for elucidating reaction mechanisms. Global kinetic analysis and classic transition-state probes (e.g., LFERs, Eyring) inevitably…”
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4
Systematic Evaluation of 1,2-Migratory Aptitude in Alkylidene Carbenes
Published in Journal of the American Chemical Society (03-02-2021)“…Alkylidene carbenes undergo rapid inter- and intramolecular reactions and rearrangements, including 1,2-migrations of β-substituents to generate alkynes. Their…”
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5
Taming Ambident Triazole Anions: Regioselective Ion Pairing Catalyzes Direct N‑Alkylation with Atypical Regioselectivity
Published in Journal of the American Chemical Society (01-05-2019)“…Controlling the regioselectivity of ambident nucleophiles toward alkylating agents is a fundamental problem in heterocyclic chemistry. Unsubstituted triazoles…”
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6
Synthesis and characterization of size-selective nanoporous polymeric adsorbents for blood purification
Published in Separation and purification technology (07-05-2009)“…Crosslinked polystyrene co-divinylbenzene adsorbent microspheres with median diameters between 40 and 300 μm, with an enhanced proportion of mesopores in the…”
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7
Effect of concentrate feed level on methane emissions from grazing dairy cows
Published in Journal of dairy science (01-11-2014)“…Although the effect of nutrition on enteric methane (CH4) emissions from confined dairy cattle has been extensively examined, less information is available on…”
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The effect of grazing intensity on the performance of high‐yielding dairy cows
Published in Grass and forage science (01-09-2018)“…The study evaluated the impact of High, Moderate and Low grazing intensities throughout the grazing season, within a rotational stocking system, on the…”
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9
Preparation of novel mesoporous carbons for the adsorption of an inflammatory cytokine (IL-1 β)
Published in Biomaterials (01-07-2004)“…Mesoporous carbons derived from two types of sulphonated styrene divinylbenzene copolymers (Macronet MN500HS and CT275, Purolite International Ltd) were…”
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10
A rapid and low-cost method for genomic DNA extraction from the cyanobacterium Synechocystis
Published in Biology methods and protocols (01-01-2020)“…Abstract A two-step method is reported for preparation of genomic DNA from the model cyanobacterium Synechocystis that can be performed with minimal equipment…”
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Impact of sampling and storage technique, and duration of storage, on the composition of fresh grass when analysed using near‐infrared reflectance spectroscopy
Published in Grass and forage science (01-12-2017)“…The objective of this study was to examine the effect of sampling technique (pluck or cut), storage duration (immediate analysis, 24‐h or 48‐h), storage…”
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12
Recurrent giant cell tumors of the tendon sheath
Published in The Journal of hand surgery (American ed.) (01-11-1999)“…Seventy patients underwent surgical excision of a giant cell tumor of the tendon sheath. The patients were monitored for an average of 3 years 4 months…”
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13
Effects of dry period length and concentrate protein content in late lactation on body condition score change and subsequent lactation performance of thin high genetic merit dairy cows
Published in Journal of dairy science (01-03-2017)“…Improving body condition score of thin cows in late lactation is necessary, because cows that are thin at drying off exhibit decreased fertility postpartum and…”
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14
The nature of the internal acid solution in sulfonated poly(styrene-co-divinylbenzene) resins
Published in Catalysis letters (2003)“…The acidities of a series of fully hydrated sulfonated poly(styrene-co-divinylbenzene) resins with varying levels of sulfonation from 0.80 to 5.25 mequiv g-1…”
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15
The effect of two contrasting concentrate allocation strategies on the performance of grazing dairy cows
Published in Grass and forage science (01-09-2016)“…The objective of this study was to examine the performance of grazing Holstein–Friesian dairy cows when equal quantities of concentrates were offered using…”
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16
Misrepresentation of Research Criteria by Orthopaedic Residency Applicants
Published in Journal of bone and joint surgery. American volume (01-12-1999)“…BackgroundPrevious studies have shown that applicants for postgraduate training may misrepresent research citations. We evaluated the research citations that…”
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17
Raman spectroscopy of sulfonated polystyrene resins
Published in Vibrational spectroscopy (01-12-2000)“…Raman spectroscopy has been applied to the determination of molecular structural features in sulfonated polystyrene resins. Comparison with model compounds has…”
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18
Effects of predicted milk yields sustained by grazed grass on dairy cow performance and concentrate requirements throughout the grazing season
Published in Grass and forage science (01-09-2016)“…The objective of this study was to examine the effects of predicted milk yields sustained by grazed grass (‘Milk‐from‐Grass’: LOW, MED or HIGH) and Parity…”
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19
Kinetics and Mechanism of Azole n−π-Catalyzed Amine Acylation
Published in Journal of the American Chemical Society (16-08-2023)“…Azole anions are highly competent in the activation of weak acyl donors, but, unlike neutral (aprotic) Lewis bases, are not yet widely applied as acylation…”
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Acidities and catalytic activities of persulfonated poly(styrene-co-divinylbenzene) ion-exchange resins
Published in Catalysis letters (01-04-2001)“…A series of macroporous sulfonated poly(styrene-co-divinylbenzene) ion-exchange resins with varying levels of sulfonation have been prepared. The acidities of…”
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