Search Results - "Dairo, Taiwo O"
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Scope and Mechanism of Iridium Porphyrin-Catalyzed S–H Insertion Reactions between Thiols and Diazo Esters
Published in Organometallics (27-02-2017)“…The insertion of carbenes derived from ethyl diazoacetate (EDA), methyl diazoacetate (MDA), methyl phenyldiazoacetate (MPDA), and methyl (p-tolyl)diazoacetate…”
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Reactivity Comparison of Primary Aromatic Amines and Thiols in E–H Insertion Reactions with Diazoacetates Catalyzed by Iridium(III) Tetratolylporphyrin
Published in Organometallics (08-05-2017)“…A detailed kinetic study is described for the insertion of carbenes from methyl diazoacetate into the N–H bond of aniline, using Ir(TTP)CH3 (TTP =…”
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Aerobic Oxidation of Cyclic Amines to Lactams Catalyzed by Ceria-Supported Nanogold
Published in Catalysis letters (01-11-2016)“…The oxidative transformation of cyclic amines to lactams, which are important chemical feedstocks, is efficiently catalyzed by CeO 2 -supported gold…”
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Addition of Amines to a Carbonyl Ligand: Syntheses, Characterization, and Reactivities of Iridium(III) Porphyrin Carbamoyl Complexes
Published in Organometallics (12-05-2014)“…Treatment of (carbonyl)chloro(meso-tetra-p-tolylporphyrinato)iridium(III), (TTP)Ir(CO)Cl (1), with excess primary amines at 23 °C in the presence of Na2CO3…”
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