Search Results - "Dai, Xingchao"
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Constructing multiple active sites in iron oxide catalysts for improving carbonylation reactions
Published in Nature communications (17-08-2023)“…Surface engineering is a promising strategy to improve the catalytic activities of heterogeneous catalysts. Nevertheless, few studies have been devoted to…”
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2
Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
Published in Nature communications (25-11-2021)“…Diminishing fossil fuel resources and calls for sustainability are driving the urgent need for efficient valorization of renewable resources with high atom…”
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Active catalyst construction for CO2 recycling via catalytic synthesis of N-doped carbon on supported Cu
Published in Nature communications (13-06-2019)“…Bridging homogeneous and heterogeneous catalysis is a long-term pursuit in the field of catalysis. Herein, we report our results in integration of nano- and…”
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Synthesis of a molecularly defined single-active site heterogeneous catalyst for selective oxidation of N-heterocycles
Published in Nature communications (13-04-2018)“…Generally, a homogeneous catalyst exhibits good activity and defined active sites but it is difficult to recycle. Meanwhile, a heterogeneous catalyst can…”
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5
Highly Selective N‑Monomethylanilines Synthesis From Nitroarene and Formaldehyde via Kinetically Excluding of the Thermodynamically Favorable N,N-Dimethylation Reaction
Published in ACS catalysis (04-05-2018)“…The synthesis of N-monomethylamine remains a challenging topic because the N,N-dimethylation reaction is thermodynamically favorable. In this work, the…”
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6
Enhanced CO2 Adsorption on Nitrogen-Doped Carbon Materials by Salt and Base Co-Activation Method
Published in Materials (12-04-2019)“…Nitrogen-doped carbon materials with enhanced CO2 adsorption were prepared by the salt and base co-activation method. First, resorcinol-formaldehyde resin was…”
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7
Synthesis of Single Atom Based Heterogeneous Platinum Catalysts: High Selectivity and Activity for Hydrosilylation Reactions
Published in ACS central science (28-06-2017)“…Catalytic hydrosilylation represents a straightforward and atom-efficient methodology for the creation of C–Si bonds. In general, the application of…”
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8
Glycerol as a Building Block for Prochiral Aminoketone, N-Formamide, and N-Methyl Amine Synthesis
Published in ChemSusChem (23-11-2016)“…Prochiral aminoketones are key intermediates for the synthesis of optically active amino alcohols, and glycerol is one of the main biomass‐based alcohols…”
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9
Carbon-catalysed reductive hydrogen atom transfer reactions
Published in Nature communications (02-04-2015)“…Generally, transition metal catalysts are essential for the reductive hydrogen atom transfer reaction, which is also known as the transfer hydrogenation…”
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10
Development of a General Non-Noble Metal Catalyst for the Benign Amination of Alcohols with Amines and Ammonia
Published in Chemistry : a European journal (11-03-2013)“…The N‐alkylation of amines or ammonia with alcohols is a valuable route for the synthesis of N‐alkyl amines. However, as a potentially clean and economic…”
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Methylation of amines, nitrobenzenes and aromatic nitriles with carbon dioxide and molecular hydrogen
Published in Chemical science (Cambridge) (01-01-2014)“…CO sub(2)/H sub(2) was successfully employed in alkylation reactions by performing CO sub(2) reduction and amine N-methylation in one-pot. In the presence of a…”
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12
Catalytic Activity Enhancement on Alcohol Dehydrogenation via Directing Reaction Pathways from Single- to Double-Atom Catalysis
Published in Journal of the American Chemical Society (23-03-2022)“…To further improve the intrinsic reactivity of single-atom catalysts (SACs), the controllable modification of a single site by coordinating with a second…”
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13
Confinement of atomically dispersed Rh catalysts within porous monophosphine polymers for regioselective hydroformylation of alkenes
Published in Journal of catalysis (01-09-2021)“…One-pot encapsulation of single-atom Rh catalysts within porous monophosphine polymers was reported for regioselective heterogeneous hydroformylation of…”
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14
Alcohol Amination Catalyzed by Copper Powder as a Self‐Supported Catalyst
Published in ChemSusChem (05-07-2019)“…Catalytic alcohol amination is a sustainable reaction for N‐alkyl amine synthesis. Homogeneous and supported copper catalysts have long been studied for this…”
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Sustainable Co‐Synthesis of Glycolic Acid, Formamides and Formates from 1,3‐Dihydroxyacetone by a Cu/Al2O3 Catalyst with a Single Active Sites
Published in Angewandte Chemie International Edition (08-04-2019)“…Glycolic acid (GA), as important building block of biodegradable polymers, has been synthesized for the first time in excellent yields at room temperature by…”
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Sustainable Co‐Synthesis of Glycolic Acid, Formamides and Formates from 1,3‐Dihydroxyacetone by a Cu/Al 2 O 3 Catalyst with a Single Active Sites
Published in Angewandte Chemie International Edition (08-04-2019)“…Abstract Glycolic acid (GA), as important building block of biodegradable polymers, has been synthesized for the first time in excellent yields at room…”
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17
Construction of Highly Active and Selective Molecular Imprinting Catalyst for Hydrogenation
Published in Journal of the American Chemical Society (27-09-2023)“…Surface molecular imprinting (MI) is one of the most efficient techniques to improve selectivity in a catalytic reaction. Heretofore, a prerequisite to…”
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Aerobic Oxidative Synthesis of Formamides from Amines and Bioderived Formyl Surrogates
Published in Angewandte Chemie International Edition (21-06-2024)“…Herein we present a new strategy for the oxidative synthesis of formamides from various types of amines and bioderived formyl sources (DHA, GLA and GLCA) and…”
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Inside Cover: Aerobic Oxidative Synthesis of Formamides from Amines and Bioderived Formyl Surrogates (Angew. Chem. Int. Ed. 26/2024)
Published in Angewandte Chemie International Edition (21-06-2024)“…Valuable formamides were “pulled out of the hat” upon reaction of amines with biomass‐based starting materials such as 1,3‐dihydroxyacetone, glycolaldehyde and…”
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Green synthesis of N-alkylamines and amides via the building and transformation of carbonyl-containing molecules
Published in Current opinion in green and sustainable chemistry (01-04-2020)“…N-alkylamines and amides were important organic synthesis building stock and intermediates, and their synthesis has been one of the intense topics for…”
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