Nanostructured CeO2–Al2O3 Catalytic Powders for m-Xylene and Toluene Combustion
The bee’s nest-like nanostructured CeO2–Al2O3 powders were synthesized by combustion method using polyvinyl alcohol as a fuel and their catalytic activity were tested in the m-xylene and toluene combustion. The results showed that the catalytic reaction temperature increased monotonically from 200 t...
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Published in: | MATERIALS TRANSACTIONS Vol. 54; no. 6; pp. 1060 - 1062 |
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Main Authors: | , , , |
Format: | Journal Article |
Language: | English |
Published: |
Sendai
The Japan Institute of Metals and Materials
2013
Japan Science and Technology Agency |
Subjects: | |
Online Access: | Get full text |
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Summary: | The bee’s nest-like nanostructured CeO2–Al2O3 powders were synthesized by combustion method using polyvinyl alcohol as a fuel and their catalytic activity were tested in the m-xylene and toluene combustion. The results showed that the catalytic reaction temperature increased monotonically from 200 to 250°C and from 250 to 300°C for the 90% conversion of m-xylene and toluene, respectively, with the calcination temperature in the range of 450–850°C. For both combustions, the sample calcined at 450°C with a bee’s nest-like nanostructure and average pore size of 800 nm exhibited the highest catalytic activity. Among the samples calcined at 850°C, the lowest catalytic reaction temperature for the 90% conversion of m-xylene and toluene of 250 and 300°C, respectively, was found with the sample having the equimolar ratio of Ce/Al. |
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ISSN: | 1345-9678 1347-5320 |
DOI: | 10.2320/matertrans.M2013056 |