Search Results - "Dai, Huiguang"
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Nickel and Iron Pincer Complexes as Catalysts for the Reduction of Carbonyl Compounds
Published in Accounts of chemical research (21-07-2015)“…The reductions of aldehydes, ketones, and esters to alcohols are important processes for the synthesis of chemicals that are vital to our daily life, and the…”
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2
Switching the Selectivity of Cobalt-Catalyzed Hydrogenation of Nitriles
Published in ACS catalysis (05-10-2018)“…Previous studies of base metals for catalytic hydrogenation of nitriles to primary amines or secondary aldimines focus on designing complexes with elaborate…”
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Journal Article -
3
Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols
Published in Journal of the American Chemical Society (04-06-2014)“…Hydrogenation of esters is vital to the chemical industry for the production of alcohols, especially fatty alcohols that find broad applications in consumer…”
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4
i-shaped antibody engineering enables conformational tuning of biotherapeutic receptor agonists
Published in Nature communications (20-01-2024)“…The ability to leverage antibodies to agonize disease relevant biological pathways has tremendous potential for clinical investigation. Yet while antibodies…”
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5
Iron Dihydride Complexes: Synthesis, Reactivity, and Catalytic Applications
Published in Israel journal of chemistry (01-12-2017)“…Iron dihydride complexes often play important roles in catalytic reactions that employ reducing agents such as H2, boranes, and silanes. Development of more…”
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6
Experimental Evidence of syn H–N–Fe–H Configurational Requirement for Iron-Based Bifunctional Hydrogenation Catalysts
Published in Inorganic chemistry (03-05-2021)“…Iron hydrides supported by a pincer ligand of the type HN(CH2CH2PR2)2 (RPNHP) are versatile hydrogenation catalysts. Previous efforts have focused on using CO…”
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7
Computational Mechanistic Study of Fe-Catalyzed Hydrogenation of Esters to Alcohols: Improving Catalysis by Accelerating Precatalyst Activation with a Lewis Base
Published in ACS catalysis (05-12-2014)“…DFT calculations have been performed to gain mechanistic insight into ester hydrogenation to alcohols (exemplified by PhCO2CH3 +2H2 → PhCH2OH + CH3OH),…”
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8
Primary and Secondary Coordination Sphere Effects on the Structure and Function of S‑Nitrosylating Azurin
Published in Journal of the American Chemical Society (20-09-2023)“…Much progress has been made in understanding the roles of the secondary coordination sphere (SCS) in tuning redox potentials of metalloproteins. In contrast,…”
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Recent advances in tuning redox properties of electron transfer centers in metalloenzymes catalyzing the oxygen reduction reaction and H2 oxidation important for fuel cell design
Published in Current opinion in electrochemistry (01-12-2021)“…Current fuel cell catalysts for the oxygen reduction reaction (ORR) and H2 oxidation use precious metals and, for ORR, require high overpotentials. In…”
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10
Iron and Cobalt Based Catalysts for the Hydrogenation of Esters, Amides and Nitriles
Published 01-01-2018“…This dissertation focuses on the hydrogenation of challenging substrates, such as esters, amides and nitriles catalyzed by earth abundant metals including iron…”
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Dissertation -
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Stepwise nitrosylation of the nonheme iron site in an engineered azurin and a molecular basis for nitric oxide signaling mediated by nonheme iron proteins
Published in Chemical science (Cambridge) (21-05-2021)“…Mononitrosyl and dinitrosyl iron species, such as {FeNO} 7 , {FeNO} 8 and {Fe(NO) 2 } 9 , have been proposed to play pivotal roles in the nitrosylation…”
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12
Recent advances in tuning redox properties of electron transfer centers in metalloenzymes catalyzing oxygen reduction reaction and H2 oxidation important for fuel cells design
Published in Current opinion in electrochemistry (01-12-2021)“…Current fuel-cell catalysts for oxygen reduction reaction (ORR) and H 2 oxidation use precious metals and, for ORR, require high overpotentials. In contrast,…”
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Journal Article -
13
Dynamic behavior of Maglev vehicle/guideway system with control
Published 01-01-2005“…Magnetic levitation (Maglev) is an innovative transportation technology. A high speed maglev train uses non-contact magnetic levitation, guidance and…”
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Dissertation -
14
Dynamic behavior of Maglev vehicle/guideway system with control
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Dissertation