Search Results - "Dagorne, Samuel"
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Group 1 and 2 and Early Transition Metal Complexes Bearing N‑Heterocyclic Carbene Ligands: Coordination Chemistry, Reactivity, and Applications
Published in Chemical reviews (24-09-2014)“…The authors examine group 1 and 2 and early transition metal complexes bearing N-heterocyclic carbene ligands with regard to coordination chemistry,…”
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2
Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications
Published in Coordination chemistry reviews (01-11-2020)“…•.- NHC-supported group 3-7 metal complexes reported since 2014 are reviewed. - An emphasis on their fundamental reactivity and applications is provided. -…”
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Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates
Published in Coordination chemistry reviews (01-06-2013)“…► Coordination chemistry of Ga(III) and In(III) to prepare well-defined charge-neutral, cationic and anionic complexes. ► Synthetic methodologies and…”
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Group 13 metal (Al, Ga, In, Tl) complexes supported by heteroatom-bonded carbene ligands
Published in Coordination chemistry reviews (01-09-2014)“…•The synthesis, structural characterization and reactivity of group 13 metal heteroatom-bonded complexes is reviewed.•N-Heterocyclic carbene (NHC) group 13…”
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Synthesis, Characterization, and Applications of Group 13 Cationic Compounds
Published in Chemical reviews (01-10-2008)“…A study of the structure, synthesis, and catalysis of group 13 cationic compounds is presented. These compounds are widely used in many applications, including…”
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A robust zirconium N-heterocyclic carbene complex for the living and highly stereoselective ring-opening polymerization of rac-lactide
Published in Chemical communications (Cambridge, England) (01-01-2012)“…A readily accessible and robust Zr-NHC complex was found to polymerize rac-lactide in a highly controlled, living and stereoselective manner to afford…”
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NHC Bis-Phenolate Aluminum Chelates: Synthesis, Structure, and Use in Lactide and Trimethylene Carbonate Polymerization
Published in Organometallics (27-10-2014)“…A novel family of Al(III) complexes supported by a tridentate, dianionic N-heterocyclic carbene bis-phenolate ligand ((OCO)2–) was prepared via various…”
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Synthesis and Structural Characterization of Various N,O,N-Chelated Aluminum and Gallium Complexes for the Efficient ROP of Cyclic Esters and Carbonates: How Do Aluminum and Gallium Derivatives Compare ?
Published in Organometallics (28-01-2013)“…The novel Al and Ga coordination compounds 4, 5, 7, and 8 of the type (NON)AlX (NON2– = {RNC6H4}2O2–; 4, R = Cy, X = Me; 5, R = C5H9, X = OCH2Ph; 7, R = C6F5,…”
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N‐Heterocyclic Carbene Based Tri‐organyl‐Zn–Alkyl Cations: Synthesis, Structures, and Use in CO2 Functionalization
Published in Chemistry : a European journal (24-04-2017)“…Tri‐organyl and tricoordinate N‐heterocyclic carbene (NHC) Zn–NHC alkyl cations [(nNHC)2Zn‐Me]+ (nNHC=C2‐bonded‐IMes/‐IDipp; 3+ and 4+;…”
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Tridentate Complexes of Group 10 Bearing Bis-Aryloxide N‑Heterocyclic Carbene Ligands: Synthesis, Structural, Spectroscopic, and Computational Characterization
Published in Organometallics (08-09-2014)“…A series of group 10 complexes featuring chelating tridentate bis-aryloxide N-heterocyclic carbenes were synthesized and characterized by using different…”
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Synthesis, Characterization and Catalytic Activity of NHC Gold(I) Polyoxometalate Complexes
Published in Chemistry : a European journal (27-08-2018)“…The new hybrid NHC gold(I) acetonitrile polyoxometalate complexes {[Au(IPr)(MeCN)+][H+]3[SiW12O404−] (1), [Au(IPr)(MeCN)+][H+]2[PMo12O403−] (2),…”
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Stereoselective Synthesis of Biphenolate/Binaphtolate Titanate and Zirconate Alkoxide Species: Structural Characterization and Use in the Controlled ROP of Lactide
Published in Inorganic chemistry (15-10-2012)“…Well-defined biphenol/binaphtolate group 4 alkoxide salt species [(Ph-Biphen-O)2M(O i Pr)]Li(THF) (2a, M = Ti; 4a, M = Zr) and [(Ph-binapht-O)2M(O i…”
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Perfluoroaryl Zinc Catalysts Active in Cyclohexene Oxide Homopolymerization and Alternating Copolymerization with Carbon Dioxide
Published in Catalysts (01-09-2022)“…The zinc complex Zn(C6F5)2(toluene) (1) behaves as a very active and selective catalyst in cyclohexene oxide (CHO) polymerization to produce poly(cyclohexene…”
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Exclusive Papers of the Editorial Board Members and Topical Advisory Panel Members of Catalysts in Section “Catalysis in Organic and Polymer Chemistry”
Published in Catalysts (01-07-2024)“…Herein, I would like to provide an overview of this Special Issue, published in the Organic and Polymer Chemistry Section of Catalysis, comprising…”
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Electrochemical studies of 1-ferrocenylmethyl-3-methyl-imidazolium iodide and 1-(ferrocenylmethyl)-3-mesityl-imidazolium iodide: redox potential and substituent effects
Published in Bulletin of the Chemical Society of Ethiopia (12-01-2021)“…The electrochemical behavior of 1-ferrocenylmethyl-3-(methyl)-imidazolium iodide (or mesityl) imidazolium was studied by cyclic voltammetry at glassy carbon…”
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A Discrete Five-Coordinated Cationic Aluminum Complex Supported by a Fluorinated Dialkoxy-Diimino Salen-like Ligand: Synthesis, Structure, and Use in Polymerization Catalysis
Published in Organometallics (12-04-2010)“…Methyl abstraction from a neutral aluminum complex stabilized by a salen-like fluorinated dialkoxide-diimino ligand yields the corresponding cationic species,…”
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Mechanistic Studies on the Copper-Catalyzed Hydrosilylation of Ketones
Published in European Journal of Inorganic Chemistry (01-02-2010)“…The copper‐catalyzed asymmetric hydrosilylation of ketones is an efficient method for the synthesis of chiral enantiopure secondary alcohols. Herein, we…”
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Recent Developments on the Use of Group 13 Metal Complexes in Catalysis
Published in ChemCatChem (21-06-2018)“…The present Minireview highlights the most representative and emerging developments reported since 2012 on the use of well‐defined group 13 metal species in…”
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Sterically Bulky NHC Adducts of GaMe3 and InMe3 for H2 Activation and Lactide Polymerization
Published in Inorganics (01-01-2018)“…The sterically bulky Ga(III) and In(III) (IPr*)MMe3 adducts (1 and 2) and (SItBu)MMe3 adducts (3 and 4) (M = Ga, In; IPr* =…”
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Synthesis and Structures of Cationic Aluminum and Gallium Amidinate Complexes
Published in Journal of the American Chemical Society (19-01-2000)“…Aluminum and gallium amidinate complexes, {RC(NR‘)2}MMe2 (R, R‘ = alkyl; M = Al, Ga), react with the “cationic activators” [Ph3C][B(C6F5)4] and B(C6F5)3 to…”
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