Search Results - "Dadmun, Mark"
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A New Model for the Morphology of P3HT/PCBM Organic Photovoltaics from Small-Angle Neutron Scattering: Rivers and Streams
Published in ACS nano (28-06-2011)“…Organic photovoltaics (OPVs) have attracted increasing interest as a lightweight, low-cost, and easy to process replacement for inorganic solar cells…”
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2
Interlayer diffusion of surface segregating additives to improve the isotropy of fused deposition modeling products
Published in Polymer (Guilford) (12-09-2018)“…It is well known that 3D printed parts prepared by fused deposition modeling (FDM) exhibit large anisotropy of mechanical properties. For instance, the…”
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Bimodal molecular weight samples improve the isotropy of 3D printed polymeric samples
Published in Polymer (Guilford) (28-07-2017)“…Parts prepared by the fused deposition modeling (FDM) 3D printing process suffer from poor interfacial adhesion between layers. This is due to poor diffusion…”
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4
Reactive Processing in Extrusion-Based 3D Printing to Improve Isotropy and Mechanical Properties
Published in Macromolecules (10-09-2019)“…Minimizing anisotropy in parts prepared by fused deposition modeling remains a key area of research in the development of robust and mechanically useful…”
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5
Deep Eutectic Solvents: A Review of Fundamentals and Applications
Published in Chemical reviews (10-02-2021)“…Deep eutectic solvents (DESs) are an emerging class of mixtures characterized by significant depressions in melting points compared to those of the neat…”
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Liquid Structure and Transport Properties of the Deep Eutectic Solvent Ethaline
Published in The journal of physical chemistry. B (25-06-2020)“…A range of techniques including physical property measurements, neutron scattering experiments, ab initio molecular dynamics, and classical molecular dynamics…”
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7
Unraveling the Mechanism of Nanoscale Mechanical Reinforcement in Glassy Polymer Nanocomposites
Published in Nano letters (08-06-2016)“…The mechanical reinforcement of polymer nanocomposites (PNCs) above the glass transition temperature, T g, has been extensively studied. However, not much is…”
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More Efficient Chemical Recycling of Poly(ethylene terephthalate) by Intercepting Intermediates
Published in ChemSusChem (04-10-2024)“…The research presented in this paper offers insight into the availability of intermediates in the depolymerization of Polyethylene Terephthalate (PET) to be…”
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Big Effect of Small Nanoparticles: A Shift in Paradigm for Polymer Nanocomposites
Published in ACS nano (24-01-2017)“…Polymer nanocomposites (PNCs) are important materials that are widely used in many current technologies and potentially have broader applications in the future…”
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10
Dynamics at the Polymer/Nanoparticle Interface in Poly(2-vinylpyridine)/Silica Nanocomposites
Published in Macromolecules (11-03-2014)“…The static and dynamic properties of poly(2-vinylpyridine)/silica nanocomposites are investigated by temperature modulated differential scanning calorimetry,…”
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11
Controlling Interfacial Dynamics: Covalent Bonding versus Physical Adsorption in Polymer Nanocomposites
Published in ACS nano (26-07-2016)“…It is generally believed that the strength of the polymer–nanoparticle interaction controls the modification of near-interface segmental mobility in polymer…”
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12
Illumination of Conjugated Polymer in Solution Alters Its Conformation and Thermodynamics
Published in Macromolecules (10-05-2016)“…The importance of chain structure in conjugated polymer-based material active layers and its relation to device efficiencies in OPVs, organic field…”
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13
Illumination alters the structure of gels formed from the model optoelectronic material P3HT
Published in Polymer (Guilford) (13-01-2017)“…Studying the gelation process of conjugated optoelectronic polymers has often been employed as a means of better understanding the final morphology and…”
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14
Unexpected Molecular Weight Effect in Polymer Nanocomposites
Published in Physical review letters (22-01-2016)“…The properties of the interfacial layer between the polymer matrix and nanoparticles largely determine the macroscopic properties of polymer nanocomposites…”
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15
Evolution of microscopic heterogeneity and dynamics in choline chloride-based deep eutectic solvents
Published in Nature communications (11-01-2022)“…Deep eutectic solvents (DESs) are an emerging class of non-aqueous solvents that are potentially scalable, easy to prepare and functionalize for many…”
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16
Elucidating the Kinetic and Thermodynamic Driving Forces in Polymer Blend Film Self-Stratification
Published in Macromolecules (09-10-2018)“…Self-assembly of immiscible polymer blend films during deposition presents an attractive avenue to fabricate structured multicomponent thin films. Depth…”
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17
The effect of illumination on the depth profile of thermally annealed MEH‐PPV/dPS blends
Published in Journal of polymer science. Part B, Polymer physics (01-08-2017)“…ABSTRACT Due to its simplicity and cost‐effectiveness, single solution casting of organic optoelectronics has grown in popularity for device fabrication to…”
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Relative Size of the Polymer and Nanoparticle Controls Polymer Diffusion in All-Polymer Nanocomposites
Published in Macromolecules (09-04-2019)“…The dynamics of polymers in an all-polymer nanocomposite that are composed of soft cross-linked polystyrene nanoparticles and linear polystyrene have been…”
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Polymer Chain Diffusion in All-Polymer Nanocomposites: Confinement vs Chain Acceleration
Published in Journal of physical chemistry. C (27-08-2020)“…All-polymer nanocomposites, in which soft, polymer-based nanoparticles are dispersed in the polymer matrix, have received great interest lately due to their…”
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Tuning the Morphology and Performance of Low Bandgap Polymer:Fullerene Heterojunctions via Solvent Annealing in Selective Solvents
Published in Advanced functional materials (27-08-2014)“…Low bandgap polymer (LBG):fullerene mixtures are some of the most promising organic photovoltaic active layers. Unfortunately, there are no post‐deposition…”
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