Search Results - "Dacheux, Nicolas"
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Crystal chemistry of the monazite structure
Published in Journal of the European Ceramic Society (01-06-2011)“…The AXO 4 monazite-type compounds form an extended family that is described in this review in terms of field of stability versus composition. All the…”
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Coffinite formation from UO2+x
Published in Scientific reports (22-07-2020)“…Most of the highly radioactive spent nuclear fuel (SNF) around the world is destined for final disposal in deep-mined geological repositories. At the end of…”
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Monoclinic Form of the Rhabdophane Compounds: REEPO4·0.667H2O
Published in Crystal growth & design (01-10-2014)“…Hydrated rhabdophane with a general formula REEPO4·nH2O (REE: La → Dy) has been always considered to crystallize in the hexagonal system. A recent…”
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Thermodynamics of formation of coffinite, USiO4
Published in Proceedings of the National Academy of Sciences - PNAS (26-05-2015)“…Coffinite, USiO4, is an important U(IV) mineral, but its thermodynamic properties are not well-constrained. In this work, two different coffinite samples were…”
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Thermodynamics and Stability of Rhabdophanes, Hydrated Rare Earth Phosphates REPO4 · n H2O
Published in Frontiers in chemistry (17-12-2018)“…Rare earth phosphates comprise a large family of compounds proposed as possible nuclear waste disposal forms. We report structural and thermodynamic properties…”
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Multiparametric Dissolution of Thorium–Cerium Dioxide Solid Solutions
Published in Inorganic chemistry (21-11-2011)“…The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of oxalate precursors was studied by varying independently several…”
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Impact of ruthenium metallic particles on the dissolution of UO2 in nitric acid
Published in Npj Materials degradation (03-05-2022)“…UO 2 pellets incorporating 3 mol.% of Ru was prepared by using a wet chemistry route and then characterised. The speciation, morphology, as well as spatial…”
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A multiparametric study on the dissolution of synthetic brannerite
Published in Npj Materials degradation (02-06-2021)“…Brannerite, UTi 2 O 6 is reported to occur in various uraniferous deposits worldwide. Natural brannerite specimens are found in the amorphous state and are…”
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In Situ HT-ESEM Observation of CeO2 Grain Growth During Sintering
Published in Journal of the American Ceramic Society (01-11-2012)“…The CeO2 sintering and grain growth kinetics were determined from in situ experiments performed using an environmental scanning electron microscope (ESEM)…”
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11
Oxidative dissolution of (U,Ce)O2 materials in aqueous solutions containing H2O2
Published in Npj Materials degradation (21-04-2023)“…Homogeneous and heterogeneous U 1-x Ce x O 2 (with 0≤ x≤ 0.25) materials were prepared via wet and dry chemistry routes, respectively before being submitted to…”
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CO2 sequestration by carbonation of olivine: a new process for optimal separation of the solids produced
Published in Green processing and synthesis (28-01-2019)“…CO sequestration by reaction with abundant, reactive minerals such as olivine has often been considered. The most straightforward, direct process consists in…”
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Understanding the solid/liquid interface evolution during the dissolution of Nd-doped UO2 by macro-/microscopic dual approach
Published in Corrosion science (01-09-2023)“…The chemical durability of Nd-doped UO2 samples was studied using an innovative macro-/microscopic dual approach method. The starting precursor was first…”
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Occurence of an Octanuclear Motif of Uranyl Isophthalate with Cation–Cation Interactions through Edge-Sharing Connection Mode
Published in Inorganic chemistry (04-07-2011)“…An uranyl isophthalate has been hydrothermally synthesized at 200 °C for 24 h, from a mixture of uranyl nitrate, isophthalic acid, and hydrazine in water. It…”
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Uranium removal from mining water using Cu substituted hydroxyapatite
Published in Journal of hazardous materials (15-06-2020)“…[Display omitted] •Cu-substituted Hap samples with controlled copper content were synthesized.•Cu-Hap samples were used as sorbent materials for immobilizing…”
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In pursuit of the rhabdophane crystal structure: from the hydrated monoclinic LnPO{sub 4}.0.667H{sub 2}O to the hexagonal LnPO{sub 4} (Ln = Nd, Sm, Gd, Eu and Dy)
Published in Journal of solid state chemistry (15-05-2017)“…The dehydration process of the hydrated rhabdophane LnPO{sub 4}.0.667H{sub 2}O (Ln = La to Dy) was thoroughly studied over the combination of in situ high…”
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Chemical and environmental stability of monazite-cheralite solid solutions Ln1-2xCaxThxPO4 (Ln = Pr, Nd; x = 0–0.15): A thermodynamic study
Published in Applied geochemistry (01-01-2023)“…Monazite-cheralite ceramics are a promising waste form for actinides. To elucidate the long-term behavior of this matrix in aqueous solutions, this study…”
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Dissolution of Th$_{0.25}$U$_{0.75}$O$_2$ sintered pellets: Impact of nitrate ions and nitrous acid
Published in Hydrometallurgy (01-09-2021)“…In order to gain insights on the kinetics of the dissolution of Gen(IV) MOX fuels, sintered pellets of Th$_{0.25}$U$_{0.75}$O$_2$ were prepared as surrogates…”
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In pursuit of the rhabdophane crystal structure: from the hydrated monoclinic LnPO4.0.667H2O to the hexagonal LnPO4 (Ln = Nd, Sm, Gd, Eu and Dy)
Published in Journal of solid state chemistry (01-05-2017)“…The dehydration process of the hydrated rhabdophane LnPO4.0.667H2O (Ln = La to Dy) was thoroughly studied over the combination of in situ high resolution…”
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In situ Raman monitoring of studtite formation under alpha radiolysis in $^{18}$O-labeled water
Published in Journal of nuclear materials (01-11-2024)“…Studtite [(UO$_2$)(O$_2$)(H$_2$O)$_2$]·2(H$_2$O) is a secondary phase precipitating during the alteration of uranium-bearing materials. The mechanistic link…”
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