Search Results - "DUIN, Evert C"
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Mode of action uncovered for the specific reduction of methane emissions from ruminants by the small molecule 3-nitrooxypropanol
Published in Proceedings of the National Academy of Sciences - PNAS (31-05-2016)“…Ruminants, such as cows, sheep, and goats, predominantly ferment in their rumen plant material to acetate, propionate, butyrate, CO₂, and methane. Whereas the…”
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Elucidating the Process of Activation of Methyl-Coenzyme M Reductase
Published in Journal of bacteriology (01-07-2014)“…Methyl-coenzyme M reductase (MCR) catalyzes the reversible reduction of methyl-coenzyme M (CH3-S-CoM) and coenzyme B (HS-CoB) to methane and heterodisulfide…”
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Assembly of Methyl Coenzyme M Reductase in the Methanogenic Archaeon Methanococcus maripaludis
Published in Journal of bacteriology (01-04-2018)“…Methyl coenzyme M reductase (MCR) is a complex enzyme that catalyzes the final step in biological methanogenesis. To better understand its assembly, the…”
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Methanosarcina acetivorans contains a functional ISC system for iron-sulfur cluster biogenesis
Published in BMC microbiology (23-10-2020)“…The production of methane by methanogens is dependent on numerous iron-sulfur (Fe-S) cluster proteins; yet, the machinery involved in Fe-S cluster biogenesis…”
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The crystal structure of methanogen McrD, a methyl‐coenzyme M reductase‐associated protein
Published in FEBS open bio (01-08-2024)“…Methyl‐coenzyme M reductase (MCR) is a multi‐subunit (α2β2γ2) enzyme responsible for methane formation via its unique F430 cofactor. The genes responsible for…”
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2D/1D graphitic carbon nitride/titanate nanotubes heterostructure for efficient photocatalysis of sulfamethazine under solar light: Catalytic “hot spots” at the rutile–anatase–titanate interfaces
Published in Applied catalysis. B, Environmental (01-04-2020)“…[Display omitted] •2D/1D g-C3N4/TNTs composite was developed and showed high photocatalytic activity.•P25-type titania decorated on TNTs after in situ…”
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Formation of a Nickel−Methyl Species in Methyl-Coenzyme M Reductase, an Enzyme Catalyzing Methane Formation
Published in Journal of the American Chemical Society (12-09-2007)“…An organometallic methyl−nickel species was detected in the enzyme methyl-coenzyme M reductase (MCR). This is the key enzyme in microbial methane production…”
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Expression of divergent methyl/alkyl coenzyme M reductases from uncultured archaea
Published in Communications biology (20-10-2022)“…Methanogens and anaerobic methane-oxidizing archaea (ANME) are important players in the global carbon cycle. Methyl-coenzyme M reductase (MCR) is a key enzyme…”
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A New Mechanism for Methane Production from Methyl-Coenzyme M Reductase As Derived from Density Functional Calculations
Published in The journal of physical chemistry. B (28-02-2008)“…We propose a new DFT-based mechanism for methane production using the full F430 cofactor of MCR (methyl-coenzyme M reductase) along with a coordinated…”
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Paramagnetic Intermediates of (E)-4-Hydroxy-3-methylbut-2-enyl Diphosphate Synthase (GcpE/IspG) under Steady-State and Pre-Steady-State Conditions
Published in Journal of the American Chemical Society (20-10-2010)“…(E)-4-Hydroxy-3-methylbut-2-enyl diphosphate synthase (GcpE/IspG) converts 2-C-methyl-d-erythritol-2,4-cyclodiphosphate (MEcPP) into…”
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The two-electron reduced A cluster in acetyl-CoA synthase: Preparation, characteristics and mechanistic implications
Published in Journal of inorganic biochemistry (01-03-2023)“…Acetyl-CoA synthase (ACS) is a central enzyme in the carbon and energy metabolism of certain anaerobic species of bacteria and archaea that catalyzes the…”
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Biochar and surfactant synergistically enhanced PFAS destruction in UV/sulfite system at neutral pH
Published in Chemosphere (Oxford) (01-04-2024)“…The UV/sulfite-based advanced reduction process (ARP) emerges as an effective strategy to combat per- and polyfluoroalkyl substances (PFAS) pollution in water…”
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Enhanced sorption and destruction of PFAS by biochar-enabled advanced reduction process
Published in Chemosphere (Oxford) (01-09-2024)“…The biochar-enabled advanced reduction process (ARP) was developed for enhanced sorption (by biochar) and destruction of PFAS (by ARP) in water. First, the…”
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Posttranslational Methylation of Arginine in Methyl Coenzyme M Reductase Has a Profound Impact on both Methanogenesis and Growth of Methanococcus maripaludis
Published in Journal of bacteriology (15-01-2020)“…Catalyzing the key step for anaerobic production and/or oxidation of methane and likely other short-chain alkanes, methyl coenzyme M reductase (Mcr) and its…”
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The Active-Site [4Fe-4S] Cluster in the Isoprenoid Biosynthesis Enzyme IspH Adopts Unexpected Redox States during Ligand Binding and Catalysis
Published in Journal of the American Chemical Society (14-02-2024)“…(E)-4-Hydroxy-3-methylbut-2-enyl diphosphate reductase, or IspH (formerly known as LytB), catalyzes the terminal step of the bacterial methylerythritol…”
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Functional characterization of GcpE, an essential enzyme of the non-mevalonate pathway of isoprenoid biosynthesis
Published in FEBS letters (18-12-2002)“…The gcpE gene product controls one of the terminal steps of isoprenoid biosynthesis via the mevalonate independent 2-C-methyl-D-erythritol-4-phosphate (MEP)…”
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Quantitative, real-time in vivo tracking of magnetic nanoparticles using multispectral optoacoustic tomography (MSOT) imaging
Published in Journal of pharmaceutical and biomedical analysis (30-01-2020)“…[Display omitted] •SPIONs modified with Cy7 demonstrated superior detection sensitivity with MSOT compared to other nanoparticles in literature.•Quantitative…”
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Spin Density and Coenzyme M Coordination Geometry of the ox1 Form of Methyl-Coenzyme M Reductase: A Pulse EPR Study
Published in Journal of the American Chemical Society (21-12-2005)“…Methyl-coenzyme M reductase (MCR) catalyses the reduction of methyl-coenzyme M (CH3-S-CoM) with coenzyme B (H-S-CoB) to CH4 and CoM-S-S-CoB in methanogenic…”
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[2Fe-2S] to [4Fe-4S] Cluster Conversion in Escherichia coli Biotin Synthase
Published in Biochemistry (Easton) (30-09-1997)“…The type and properties of the Fe−S cluster in recombinant Escherichia coli biotin synthase have been investigated in as-prepared and dithionite-reduced…”
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Photoreduction of CHCl3 in Aqueous SPEEK/HCO2 – Solutions Involving Free Radicals
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (13-09-2018)“…Exposure of sulfonated poly(ether etherketone), SPEEK, in aqueous solutions to 350 nm photons induced reduction of CHCl3 to CH2Cl2 and chloride ions in the…”
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