Search Results - "D’Alessandro, Deanna M"

Mixed Valency as a Strategy for Achieving Charge Delocalization in Semiconducting and Conducting Framework Materials by Murase, Ryuichi, Leong, Chanel F, D’Alessandro, Deanna M

“…The fundamentally important phenomenon of mixed valency has been discussed in detail over the past 50 years, predominantly in the context of dinuclear…”
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Carbon Dioxide Capture: Prospects for New Materials by D'Alessandro, Deanna M, Smit, Berend, Long, Jeffrey R

“…The escalating level of atmospheric carbon dioxide is one of the most pressing environmental concerns of our age. Carbon capture and storage (CCS) from large…”
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Strong CO2 Binding in a Water-Stable, Triazolate-Bridged Metal−Organic Framework Functionalized with Ethylenediamine by Demessence, Aude, D’Alessandro, Deanna M, Foo, Maw Lin, Long, Jeffrey R

“…Reaction of CuCl2·2H2O with 1,3,5-tris(1H-1,2,3-triazol-5-yl)benzene (H3BTTri) in DMF at 100 °C generates the metal−organic framework…”
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Microwave-Assisted Solvothermal Synthesis and Optical Properties of Tagged MIL-140A Metal–Organic Frameworks by Liang, Weibin, Babarao, Ravichandar, D’Alessandro, Deanna M

“…A series of tagged MIL-140A-R frameworks have been synthesized using a microwave-assisted solvothermal method. Compared with their UiO-66-R polymorphs, the…”
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Visible Light Stimulated Bistable Photo-Switching in Defect Engineered Metal–Organic Frameworks by Shepherd, Nicholas D, Wang, Tiesheng, Ding, Bowen, Beves, Jonathon E, D’Alessandro, Deanna M

“…The incorporation of photoactive donor–acceptor Stenhouse adduct (DASA) moieties into Metal–Organic Frameworks (MOFs) provides a new route to the development…”
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Photo‐ and Electronically Switchable Spin‐Crossover Iron(II) Metal–Organic Frameworks Based on a Tetrathiafulvalene Ligand by Wang, Hai‐Ying, Ge, Jing‐Yuan, Hua, Carol, Jiao, Cheng‐Qi, Wu, Yue, Leong, Chanel F., D'Alessandro, Deanna M., Liu, Tao, Zuo, Jing‐Lin

“…A major challenge is the development of multifunctional metal–organic frameworks (MOFs), wherein magnetic and electronic functionality can be controlled…”
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Current trends and future challenges in the experimental, theoretical and computational analysis of intervalence charge transfer (IVCT) transitions by D'Alessandro, Deanna M, Keene, F Richard

“…Mixed-valence chemistry has a long and rich history which is characterised by a strong interplay of experimental, theoretical and computational studies. The…”
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Building a Porous Molecular Machine That Replicates Natural Enzymes by D’Alessandro, Deanna M

“…An artificial enzyme with record catalytic activity for organophosphorus degradation has been created from a crown-ether threaded covalent organic framework…”
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Electronic Spin Qubit Candidates Arrayed within Layered Two-Dimensional Polymers by Oanta, Alexander K., Collins, Kelsey A., Evans, Austin M., Pratik, Saied Md, Hall, Lyndon A., Strauss, Michael J., Marder, Seth R., D’Alessandro, Deanna M., Rajh, Tijana, Freedman, Danna E., Li, Hong, Brédas, Jean-Luc, Sun, Lei, Dichtel, William R.

“…Molecular electronic spin qubits are promising candidates for quantum information science applications because they can be reliably produced and engineered via…”
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Prospects for electroactive and conducting framework materials by Murase, Ryuichi, Ding, Bowen, Gu, Qinyi, D'Alessandro, Deanna M

“…Electroactive and conducting framework materials, encompassing coordination polymers and metal-organic frameworks, have captured the imagination of the…”
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3D Printing of Monoliths Using TIFSIX-Ni-Based Formulations for the Electric Swing Adsorption of CO2 by Kearns, Eleanor R., Xia, Qingbo, Gillespie, Rohan, Proschogo, Nicholas, Doheny, Patrick W., Solomon, Marcello B., D’Alessandro, Deanna M.

“…The hybrid ultraporous material TIFSIX-Ni ([Ni­(pyrazine)2(TiF6)] n ) was incorporated into a composite ink for the first time for the three-dimensional (3D)…”
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Linking defects, hierarchical porosity generation and desalination performance in metal-organic frameworks by Liang, Weibin, Li, Lin, Hou, Jingwei, Shepherd, Nicholas D, Bennett, Thomas D, D'Alessandro, Deanna M, Chen, Vicki

“…Composite membranes with defective metal-organic frameworks (MOFs) connect the emerging fields of MOF topological modification, MOF-polymer interfacial…”
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Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron() incorporating tetrathiafulvalene by Qiu, Ya-Ru, Cui, Long, Cai, Pei-Yu, Yu, Fei, Kurmoo, Mohamedally, Leong, Chanel F, D'Alessandro, Deanna M, Zuo, Jing-Lin

“…In designing multifunctional materials for potential switches that can be used as memory devices, the high-spin (HS) to low-spin (LS) crossover (SCO)…”
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The Electrochemical Transformation of the Zeolitic Imidazolate Framework ZIF-67 in Aqueous Electrolytes by Usov, Pavel M., McDonnell-Worth, Ciaran, Zhou, Fengling, MacFarlane, Douglas R., D’Alessandro, Deanna M.

“…[Display omitted] Metal-Organic Frameworks (MOFs) can serve as precursors to a range of useful materials including porous catalysts and supercapacitors. The…”
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Intervalence Charge Transfer (IVCT) in Trinuclear and Tetranuclear Complexes of Iron, Ruthenium, and Osmium by D'Alessandro, Deanna M, Keene, F. Richard

“…This review discusses the fundamental electron transfer properties of trinuclear and tetranuclear complexes through the analysis of their intervalence charge…”
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Untangling Complex Redox Chemistry in Zeolitic Imidazolate Frameworks Using Fourier Transformed Alternating Current Voltammetry by Usov, Pavel M, Simonov, Alexandr N, Bond, Alan M, Murphy, Michael J, D’Alessandro, Deanna M

“…Two zeolitic imidazolate frameworks, ZIF-67 and ZIF-8, were interrogated for their redox properties using Fourier transformed alternating current voltammetry,…”
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Multi-Redox Responsive Behavior in a Mixed-Valence Semiconducting Framework Based on Bis-[1,2,5]-thiadiazolo-tetracyanoquinodimethane by Murase, Ryuichi, Hudson, Timothy A., Aldershof, Thomas S., Nguyen, Ky V., Gluschke, Jan G., Kenny, Elise P., Zhou, Xiuwen, Wang, Tiesheng, van Koeverden, Martin P., Powell, Benjamin J., Micolich, Adam P., Abrahams, Brendan F., D’Alessandro, Deanna M.

“…The two-dimensional (2-D) framework, [Cu­(BTDAT)­(MeOH)] {BTDAT = bis-[1,2,5]-thiadiazolo-tetracyanoquinodimethane}, possesses remarkable multi-step redox…”
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Rare‐Earth Metal Tetrathiafulvalene Carboxylate Frameworks as Redox‐Switchable Single‐Molecule Magnets by Su, Jian, Yuan, Shuai, Li, Jing, Wang, Hai‐Ying, Ge, Jing‐Yuan, Drake, Hannah F., Leong, Chanel F., Yu, Fei, D'Alessandro, Deanna M., Kurmoo, Mohamedally, Zuo, Jing‐Lin, Zhou, Hong‐Cai

“…Using the redox‐active tetrathiafulvalene tetrabenzoate (TTFTB4−) as the linker, a series of stable and porous rare‐earth metal–organic frameworks (RE‐MOFs),…”
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High-spin ground states via electron delocalization in mixed-valence imidazolate-bridged divanadium complexes by Bechlars, Bettina, D'Alessandro, Deanna M., Jenkins, David M., Iavarone, Anthony T., Glover, Starla D., Kubiak, Clifford P., Long, Jeffrey R.

“…The field of molecular magnetism has grown tremendously since the discovery of single-molecule magnets, but it remains centred around the superexchange…”
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Site Isolation Leads to Stable Photocatalytic Reduction of CO2 over a Rhenium-Based Catalyst by Liang, Weibin, Church, Tamara L., Zheng, Sisi, Zhou, Chenlai, Haynes, Brian S., D'Alessandro, Deanna M.

“…A porous organic polymer incorporating [(α‐diimine)Re(CO)3Cl] moieties was produced and tested in the photocatalytic reduction of CO2, with NEt3 as a…”
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