Search Results - "Cunningham, Ethan M"
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Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn2+(H2O)n (n = 1–20)
Published in International journal of molecular sciences (02-06-2021)“…Investigating metal-ion solvation—in particular, the fundamental binding interactions—enhances the understanding of many processes, including hydrogen…”
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Infrared Spectroscopy of NaCl(CH3OH) n Complexes in Helium Nanodroplets
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (20-10-2016)“…Infrared (IR) spectra of complexes between NaCl and methanol have been recorded for the first time. These complexes were formed in liquid helium nanodroplets…”
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3
Infrared Multiple Photon Dissociation Spectroscopy Confirms Reversible Water Activation in Mn+(H2O) n , n ≤ 8
Published in The journal of physical chemistry letters (14-04-2022)“…Controlled activation of water molecules is the key to efficient water splitting. Hydrated singly charged manganese ions Mn+(H2O) n exhibit a size-dependent…”
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Carbon Dioxide and Water Activation by Niobium Trioxide Anions in the Gas Phase
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (20-04-2023)“…Transition metals are important in various industrial applications including catalysis. Due to the current concentration of CO2 in the atmosphere, various ways…”
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Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride–Hydroxide HAlOH+(H2O)n−1, n=9–14
Published in Angewandte Chemie International Edition (26-07-2021)“…Hydrated singly charged aluminum ions eliminate molecular hydrogen in a size regime from 11 to 24 water molecules. Here we probe the structure of…”
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Surface or Internal Hydration – Does It Really Matter?
Published in Journal of the American Society for Mass Spectrometry (01-03-2023)“…The precise location of an ion or electron, whether it is internally solvated or residing on the surface of a water cluster, remains an intriguing question…”
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Infrared Signature of Structural Isomers of Gas–Phase M+(N2O) n (M = Cu, Ag, Au) Ion–Molecule Complexes
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-10-2017)“…Gas-phase metal ion–ligand complexes offer model environments to study molecular interactions that are key to many catalytic processes. Here, we present a…”
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Infrared spectroscopy of closed s-shell gas-phase M+(N2O)n (M = Li, Al) ion-molecule complexes
Published in Molecular physics (02-11-2019)“…We present the results of a combined experimental and computational study of the structures of gas-phase M + (N 2 O) n (M = Li, Al) complexes. Infrared spectra…”
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Frontispiece: Getting Ready for the Hydrogen Evolution Reaction: The Infrared Spectrum of Hydrated Aluminum Hydride–Hydroxide HAlOH+(H2O)n−1, n=9–14
Published in Angewandte Chemie International Edition (26-07-2021)“…Gas‐Phase Chemistry The infrared spectrum of hydrated aluminum hydride–hydroxide HAlOH+(H2O)n−1 is reported in the Communication by Chi‐Kit Siu, Martin K…”
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Infrared Spectroscopy of Au+(CH4)n Complexes and Vibrationally-Enhanced C–H Activation Reactions
Published in Topics in catalysis (2018)“…A combined spectroscopic and computational study of gas-phase Au + (CH 4 ) n ( n = 3–8) complexes reveals a strongly-bound linear Au + (CH 4 ) 2 core…”
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Metastable Aluminum Atoms Floating on the Surface of Helium Nanodroplets
Published in Physical review letters (12-06-2015)“…Metal atoms have proved to be sensitive probes of the properties of superfluid helium nanodroplets. To date, all experiments on the doping of helium droplets…”
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Auf zur Wasserstoffentwicklung: Das Infrarot-Spektrum von hydratisiertem Aluminiumhydrid-Hydroxid HAlOH + (H 2 O) n -1 , n= 9-14
Published in Angewandte Chemie (26-07-2021)“…Abstract Hydratisierte Al + ‐Ionen eliminieren H 2 in einem Bereich von 11 bis 24 Wassermolekülen. Wir untersuchten die Struktur von HAlOH + (H 2 O) n−1 ,…”
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Frontispiz: Auf zur Wasserstoffentwicklung: Das Infrarot‐Spektrum von hydratisiertem Aluminiumhydrid‐Hydroxid HAlOH+(H2O)n−1, n=9–14
Published in Angewandte Chemie (26-07-2021)“…Gasphasenchemie Das Infrarotspektrum von hydratisiertem Aluminiumhydridhydroxid HAlOH+(H2O)n−1 wird in der Zuschrift von Chi‐Kit Siu, Martin K. Beyer et al…”
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Auf zur Wasserstoffentwicklung: Das Infrarot‐Spektrum von hydratisiertem Aluminiumhydrid‐Hydroxid HAlOH+(H2O)n−1, n=9–14
Published in Angewandte Chemie (26-07-2021)“…Hydratisierte Al+‐Ionen eliminieren H2 in einem Bereich von 11 bis 24 Wassermolekülen. Wir untersuchten die Struktur von HAlOH+(H2O)n−1, n=9–14, durch…”
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Carbon dioxide binding to metal oxides: Infrared spectroscopy of NbO2+(CO2)n and TaO2+(CO2)n complexes
Published in International journal of mass spectrometry (01-01-2019)“…[Display omitted] •CO2 complexes efficiently with NbO2+ and TaO2+ relevant to sequestration by MOFs.•DFT simulations allow clear structural determination of…”
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Carbon dioxide binding to metal oxides: Infrared spectroscopy of NbO2+(CO2) and TaO2+(CO2) complexes
Published in International journal of mass spectrometry (01-01-2019)Get full text
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Asymmetric Solvation of the Zinc Dimer Cation Revealed by Infrared Multiple Photon Dissociation Spectroscopy of Zn 2 + (H 2 O) n ( n = 1-20)
Published in International journal of molecular sciences (02-06-2021)“…Investigating metal-ion solvation-in particular, the fundamental binding interactions-enhances the understanding of many processes, including hydrogen…”
Get full text
Journal Article -
18
Elucidating the structures of cationic metal-nitrous oxide complexes using infrared action spectroscopy
Published 01-01-2019“…Gas-phase metal ion-molecule complexes provide model environments within which to study fundamental molecular interactions involved in ligand activation and…”
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Dissertation -
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Frontispiz: Auf zur Wasserstoffentwicklung: Das Infrarot‐Spektrum von hydratisiertem Aluminiumhydrid‐Hydroxid HAlOH + (H 2 O) n −1 , n= 9–14
Published in Angewandte Chemie (26-07-2021)Get full text
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