Search Results - "Cumpson, Peter J"
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Demonstration of chemistry at a point through restructuring and catalytic activation at anchored nanoparticles
Published in Nature communications (30-11-2017)“…Metal nanoparticles prepared by exsolution at the surface of perovskite oxides have been recently shown to enable new dimensions in catalysis and energy…”
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Depth profiling organic/inorganic interfaces by argon gas cluster ion beams: sputter yield data for biomaterials, in-vitro diagnostic and implant applications
Published in Surface and interface analysis (01-12-2013)“…Argon gas cluster ion beam sources are likely to become much more widely available on XPS and SIMS instruments in the next few years. Much attention has been…”
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3
Practical estimation of XPS binding energies using widely available quantum chemistry software
Published in Surface and interface analysis (01-01-2018)“…Chemical shifts observed in high‐resolution X‐ray photoelectron spectroscopy (XPS) spectra are normally used to determine the chemical state of the elements of…”
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Observations on X-ray enhanced sputter rates in argon cluster ion sputter depth profiling of polymers
Published in Surface and interface analysis (01-02-2013)“…Traditionally polymer depth profiling by X‐ray photoelectron spectroscopy (XPS) has been dominated by the damage introduced by the ion beam rather than the…”
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Estimation of inelastic mean free paths for polymers and other organic materials: use of quantitative structure-property relationships
Published in Surface and interface analysis (01-01-2001)“…Inelastic mean free path values are needed for quantitative XPS analysis of a range of important polymers and other organic materials. Measured reference data…”
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The Thickogram: a method for easy film thickness measurement in XPS
Published in Surface and interface analysis (01-06-2000)“…We describe a simple graphical method for measuring film thickness by XPS, which we call a Thickogram. This method can be used even when the film and substrate…”
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Argon cluster‐ion sputter yield: Molecular dynamics simulations on silicon and equation for estimating total sputter yield
Published in Surface and interface analysis (01-04-2022)“…Argon Gas Cluster‐Ion Beam sources have become widely‐used on X‐ray photoelectron spectroscopy (XPS) and secondary ion mass spectrometry (SIMS) instruments in…”
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Surface analysis characterisation of gum binders used in modern watercolour paints
Published in Applied surface science (28-02-2016)“…•XPS demonstrated the characterisation of top surface structures of the watercolours.•Water medium in the paint transforms structures and forms gum layer on…”
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Novel rhodium on carbon catalysts for the oxidation of benzyl alcohol to benzaldehyde: A study of the modification of metal/support interactions by acid pre-treatments
Published in Applied catalysis. A, General (25-01-2019)“…[Display omitted] •Rh on carbon catalysts were capable to oxidize benzyl alcohol under very mild conditions.•Carbon supports pre-treated with HNO3 led to…”
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Conversion of glucose to fructose over Sn and Ga-doped zeolite Y in methanol and water media
Published in Applied catalysis. A, General (25-07-2022)“…In this study, we use zeolite Y as a support for the synthesis of Sn and Ga doped zeolites aimed at the isomerization of glucose to fructose. Though these…”
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Rapid multivariate analysis of 3D ToF-SIMS data: graphical processor units (GPUs) and low-discrepancy subsampling for large-scale principal component analysis
Published in Surface and interface analysis (01-12-2016)“…Principal component analysis (PCA) and other multivariate analysis methods have been used increasingly to analyse and understand depth‐profiles in XPS, AES and…”
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Material dependence of argon cluster ion sputter yield in polymers: Method and measurements of relative sputter yields for 19 polymers
Published in Journal of vacuum science & technology. A, Vacuum, surfaces, and films (01-03-2013)“…There is a pressing need for reference data to allow sputter depth-profiling of polymers using cluster and polyatomic ion sources for the quantification of…”
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Multivariate analysis of extremely large ToFSIMS imaging datasets by a rapid PCA method
Published in Surface and interface analysis (01-10-2015)“…Principal component analysis (PCA) and other multivariate analysis methods have been used increasingly to analyse and understand depth profiles in X‐ray…”
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Optimal conditions for gas cluster ion beams in studying inorganic interface species: improved chemical information at a ZnO interface
Published in Surface and interface analysis (01-07-2016)“…We have observed for the first time a subtle chemical change in the oxidation state of Zn at the interface between a ZnO thin film and a glass substrate using…”
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Recent Developments in the Study of the Surface-Stability of Platinum and Platinum-Iridium Mass Standards: Quantifying mercury and carbon contamination on platinum-iridium alloy surfaces using XPS
Published in Johnson Matthey technology review (01-10-2014)“…We review developments in the study of the stability of platinum-iridium standard weights, in particular the kilogram prototypes manufactured from alloy…”
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Multivariate Auger Feature Imaging (MAFI) - a new approach towards chemical state identification of novel carbons in XPS imaging
Published in Surface and interface analysis (01-02-2015)“…The clear identification of allotropes and similar chemical states of carbon in XPS imaging can be made difficult because of the subtle differences observed in…”
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Reactive intercalation and oxidation at the buried graphene-germanium interface
Published in APL materials (01-07-2019)“…We explore a number of different electrochemical, wet chemical, and gas phase approaches to study intercalation and oxidation at the buried graphene-Ge…”
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Multispectral optical imaging combined in situ with XPS or ToFSIMS and principal component analysis
Published in Surface and interface analysis (01-12-2016)“…All X‐ray photoelectron spectroscopy (XPS) and time‐of‐flight secondary ion mass spectrometry (ToF‐SIMS) instruments have optical cameras to image the specimen…”
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Multivariate analysis studies of the ageing effect for artist's oil paints containing modern organic pigments
Published in Surface and interface analysis (01-10-2014)“…This work demonstrates the potential of surface analysis techniques to contribute to a better understanding for art conservators of the degradation of modern…”
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In situ ion beam sputter deposition and X‐ray photoelectron spectroscopy (XPS) of multiple thin layers under computer control for combinatorial materials synthesis
Published in Surface and interface analysis (01-01-2017)“…Deposition of ultra‐thin layers under computer control is a frequent requirement in studies of novel sensors, materials screening, heterogeneous catalysis, the…”
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