Search Results - "Crumlin, Ethan J."
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Highly durable, coking and sulfur tolerant, fuel-flexible protonic ceramic fuel cells
Published in Nature (London) (01-05-2018)“…Protonic ceramic fuel cells, like their higher-temperature solid-oxide fuel cell counterparts, can directly use both hydrogen and hydrocarbon fuels to produce…”
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Electrochemical Activation of CO2 through Atomic Ordering Transformations of AuCu Nanoparticles
Published in Journal of the American Chemical Society (21-06-2017)“…Precise control of elemental configurations within multimetallic nanoparticles (NPs) could enable access to functional nanomaterials with significant…”
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3
Unravelling the electrochemical double layer by direct probing of the solid/liquid interface
Published in Nature communications (31-08-2016)“…The electrochemical double layer plays a critical role in electrochemical processes. Whilst there have been many theoretical models predicting structural and…”
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4
Understanding the Oxygen Evolution Reaction Mechanism on CoOx using Operando Ambient-Pressure X-ray Photoelectron Spectroscopy
Published in Journal of the American Chemical Society (05-07-2017)“…Photoelectrochemical water splitting is a promising approach for renewable production of hydrogen from solar energy and requires interfacing advanced…”
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5
Dramatic differences in carbon dioxide adsorption and initial steps of reduction between silver and copper
Published in Nature communications (23-04-2019)“…Converting carbon dioxide (CO 2 ) into liquid fuels and synthesis gas is a world-wide priority. But there is no experimental information on the initial atomic…”
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6
The Donnan potential revealed
Published in Nature communications (06-10-2022)“…Selective transport of solutes across a membrane is critical for many biological, water treatment and energy conversion and storage systems. When a charged…”
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7
Ambient-Pressure XPS Study of a Ni–Fe Electrocatalyst for the Oxygen Evolution Reaction
Published in Journal of physical chemistry. C (04-02-2016)“…Chemical analysis of solid–liquid interfaces under electrochemical conditions has recently become feasible due to the development of new synchrotron radiation…”
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The Role of Adventitious Carbon in Photo-catalytic Nitrogen Fixation by Titania
Published in Journal of the American Chemical Society (14-11-2018)“…Photo-catalytic fixation of nitrogen by titania catalysts at ambient conditions has been reported for decades, yet the active site capable of adsorbing an…”
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9
Using “Tender” X-ray Ambient Pressure X-Ray Photoelectron Spectroscopy as A Direct Probe of Solid-Liquid Interface
Published in Scientific reports (07-05-2015)“…We report a new method to probe the solid-liquid interface through the use of a thin liquid layer on a solid surface. An ambient pressure XPS (AP-XPS)…”
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10
Structure, Chemistry, and Charge Transfer Resistance of the Interface between Li7La3Zr2O12 Electrolyte and LiCoO2 Cathode
Published in Chemistry of materials (25-09-2018)“…All-solid-state batteries promise significant safety and energy density advantages over liquid-electrolyte batteries. The interface between the cathode and the…”
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11
Dry Reforming of Methane on a Highly-Active Ni-CeO2 Catalyst: Effects of Metal-Support Interactions on C−H Bond Breaking
Published in Angewandte Chemie (International ed.) (20-06-2016)“…Ni‐CeO2 is a highly efficient, stable and non‐expensive catalyst for methane dry reforming at relative low temperatures (700 K). The active phase of the…”
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12
Multi-site electrocatalysts for hydrogen evolution in neutral media by destabilization of water molecules
Published in Nature energy (01-02-2019)“…High-performance hydrogen evolution reaction (HER) catalysts are compelling for the conversion of renewable electricity to fuels and feedstocks. The best HER…”
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13
In Situ and Theoretical Studies for the Dissociation of Water on an Active Ni/CeO2 Catalyst: Importance of Strong Metal-Support Interactions for the Cleavage of O-H Bonds
Published in Angewandte Chemie (International ed.) (23-03-2015)“…Water dissociation is crucial in many catalytic reactions on oxide‐supported transition‐metal catalysts. Supported by experimental and density‐functional…”
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Observing the Electrochemical Oxidation of Co Metal at the Solid/Liquid Interface Using Ambient Pressure X‑ray Photoelectron Spectroscopy
Published in The journal of physical chemistry. B (18-01-2018)“…Recent advances of ambient pressure X-ray photoelectron spectroscopy (AP-XPS) have enabled the chemical composition and the electrical potential profile at a…”
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15
Synthesis of Pt3Y and Other Early–Late Intermetallic Nanoparticles by Way of a Molten Reducing Agent
Published in Journal of the American Chemical Society (26-04-2017)“…Early–late intermetallic phases have garnered increased attention recently for their catalytic properties. To achieve the high surface areas needed for…”
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CO2 Activation on Cobalt Surface in the Presence of H2O: An Ambient-Pressure X-ray Photoelectron Spectroscopy Study
Published in Catalysis letters (01-06-2018)“…Co-based catalysts for CO 2 reduction to liquid fuels have been attracting increasing attention. In this work, the distribution of surface intermediates on a…”
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In Situ Ambient Pressure X-ray Photoelectron Spectroscopy Studies of Lithium-Oxygen Redox Reactions
Published in Scientific reports (08-10-2012)“…The lack of fundamental understanding of the oxygen reduction and oxygen evolution in nonaqueous electrolytes significantly hinders the development of…”
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18
Tailoring manganese oxide with atomic precision to increase surface site availability for oxygen reduction catalysis
Published in Nature communications (02-10-2018)“…Controlling the structure of catalysts at the atomic level provides an opportunity to establish detailed understanding of the catalytic form-to-function and…”
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Water Structure and Properties at Hydrophilic and Hydrophobic Surfaces
Published in Annual review of chemical and biomolecular engineering (07-06-2020)“…The properties of water on both molecular and macroscopic surfaces critically influence a wide range of physical behaviors, with applications spanning from…”
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Protection of inorganic semiconductors for sustained, efficient photoelectrochemical water oxidation
Published in Catalysis today (15-03-2016)“…•Protection layers stabilize Si, III–V, II–VI photoanodes in alkaline media.•Optical, electronic, and mechanistic studies described.•Wide range of working…”
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