Search Results - "Cronauer, Donald C"
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Fischer−Tropsch Synthesis: An In-Situ TPR-EXAFS/XANES Investigation of the Influence of Group I Alkali Promoters on the Local Atomic and Electronic Structure of Carburized Iron/Silica Catalysts
Published in Journal of physical chemistry. C (06-05-2010)“…The promoting impact of alkali metals (i.e., Li, Na, K, Rb, Cs) on the carburization rate of Fe in Fe/Si catalysts was investigated by X-ray absorption…”
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Influence of Cs Loading on Pt/m-ZrO2 Water–Gas Shift Catalysts
Published in Catalysts (01-05-2021)“…Certain alkali metals (Na, K) at targeted loadings have been shown in recent decades to significantly promote the LT-WGS reaction. This occurs at alkali doping…”
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Na Promotion of Pt/m-ZrO2 Catalysts for the Steam Reforming of Formaldehyde
Published in Catalysts (01-11-2022)“…The decomposition selectivity of formaldehyde during steam reforming was explored using unpromoted and sodium promoted Pt/m-ZrO2 catalysts, and the Na content…”
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Influence of Cs Promoter on Ethanol Steam-Reforming Selectivity of Pt/m-ZrO2 Catalysts at Low Temperature
Published in Catalysts (01-09-2021)“…The decarboxylation pathway in ethanol steam reforming ultimately favors higher selectivity to hydrogen over the decarbonylation mechanism. The addition of an…”
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Promoting the Selectivity of Pt/m-ZrO2 Ethanol Steam Reforming Catalysts with K and Rb Dopants
Published in Nanomaterials (Basel, Switzerland) (29-08-2021)“…The ethanol steam reforming reaction (ESR) was investigated on unpromoted and potassium- and rubidium-promoted monoclinic zirconia-supported platinum…”
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CO2 Hydrogenation: Na Doping Promotes CO and Hydrocarbon Formation over Ru/m-ZrO2 at Elevated Pressures in Gas Phase Media
Published in Nanomaterials (Basel, Switzerland) (24-03-2023)“…Sodium-promoted monoclinic zirconia supported ruthenium catalysts were tested for CO2 hydrogenation at 20 bar and a H2:CO2 ratio of 3:1. Although increasing…”
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Fischer-Tropsch Synthesis: The Characterization and Testing of Pt-Co/SiO2 Catalysts Prepared with Alternative Cobalt Precursors
Published in Reactions (Basel, Switzerland) (01-06-2021)“…Different low-cost cobalt precursors (acetate, chloride) and thermal treatments (air calcination/H2 reduction versus direct H2-activation) were investigated to…”
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Substitution of Co with Ni in Co/Al2O3 Catalysts for Fischer–Tropsch Synthesis
Published in Catalysts (01-03-2020)“…The effect of cobalt substitution with nickel was investigated for the Fischer−Tropsch synthesis reaction. Catalysts having different Ni/Co ratios were…”
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CO Hydrogenation: Exploring Iridium as a Promoter for Supported Cobalt Catalysts by TPR-EXAFS/XANES and Reaction Testing
Published in Catalysis letters (01-07-2011)“…The price of iridium currently trends at about half the cost of platinum, the latter being a typical reduction promoter for Co/Al 2 O 3 Fischer–Tropsch (FT)…”
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Effect of sodium loading on Pt/ZrO2 during ethanol steam reforming
Published in Applied catalysis. A, General (25-01-2021)“…[Display omitted] •Ethoxy and acetate are intermediates during the ethanol steam reforming.•Acetate decarboxylation is favored at 1.8 %Na and higher…”
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Hydrodeoxygenation of phenol over zirconia supported Pd bimetallic catalysts. The effect of second metal on catalyst performance
Published in Applied catalysis. B, Environmental (15-09-2018)“…[Display omitted] •The addition of a second metal (Cu.Ag,Zn,Sn) to Pd/ZrO2 formed Pd-alloys.•The formation of Pd-alloys increased the selectivity to…”
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Low temperature water-gas shift: Optimization of K loading on Pt/m-ZrO2 for enhancing CO conversion
Published in Applied catalysis. A, General (25-05-2020)“…[Display omitted] •Below 1.7 % K loading - No major red shift in formate ν(CH) band or improvement in LT-WGS rate•2.6 % K loading - Optimum loading for…”
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Effect of pretreatment conditions on acidity and dehydration activity of CeO2-MeOx catalysts
Published in Applied catalysis. A, General (25-07-2020)“…[Display omitted] •Metal oxide was added to modify the acid-base characteristics of ceria.•Pretreatment conditions (H2, air) has a profound effect on both…”
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Isotope effect in formaldehyde steam reforming on Pt/m-ZrO2: Insight into chemical promotion by alkalis
Published in Catalysis communications (01-05-2023)“…Infrared spectroscopy, temperature programmed reaction mass spectrometry (TP-reaction/MS), and catalyst testing were used to investigate alkali promotion of…”
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Fischer-Tropsch synthesis: Direct cobalt nitrate reduction of promoted Co/TiO2 catalysts
Published in Fuel (Guildford) (01-06-2019)“…[Display omitted] •H2 activated air calcined PtCo/TiO2 catalyst had larger, more reducible Co0 clusters.•The Co clusters sintered in Fischer-Tropsch synthesis:…”
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Fischer-Tropsch synthesis: Foregoing calcination and utilizing reduction promoters leads to improved conversion and selectivity with Co/silica
Published in Applied catalysis. A, General (05-06-2018)“…•Air calcined Co/SiO2 produce large, easily reduced, Co particles and low Co site densities.•Direct reduction of cobalt nitrate particles on silica yield…”
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The influence of catalysts on biofuel life cycle analysis (LCA)
Published in Sustainable Materials and Technologies (01-04-2017)“…Catalysts play an important role in biofuel production but are rarely included in biofuel life cycle analysis (LCA). In this work, we estimate the…”
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Ga and In modified ceria as supports for cobalt-catalyzed Fischer-Tropsch synthesis
Published in Applied catalysis. A, General (25-10-2017)“…[Display omitted] •Ga or In was introduced to ceria by co-precipitation using urea hydrolysis.•H2-TPR XANES showed that Ga or In addition increased the Ce3+…”
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Fischer–Tropsch synthesis: Comparisons between Pt and Ag promoted Co/Al2O3 catalysts for reducibility, local atomic structure, catalytic activity, and oxidation–reduction (OR) cycles
Published in Applied catalysis. A, General (15-08-2013)“…•Ag metal is currently ∼2% of the price of Pt; both facilitate Co oxide reduction.•Pt coordination with Co at the atomic level, even up to 5% by weight.•Ag…”
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Fischer−Tropsch Synthesis: Influence of Mn on the Carburization Rates and Activities of Fe-Based Catalysts by TPR-EXAFS/XANES and Catalyst Testing
Published in Journal of physical chemistry. C (24-03-2011)“…Fe-based catalysts containing different amounts of Mn were tested for Fischer−Tropsch synthesis using a stirred tank reactor at 270 °C, 1.21 MPa, and H2:CO =…”
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