Search Results - "Craig, Gavin"

Pore-Networked Gels: Permanently Porous Ionic Liquid Gels with Linked Metal–Organic Polyhedra Networks by Wang, Zaoming, Ozcan, Aydin, Craig, Gavin A., Haase, Frederik, Aoyama, Takuma, Poloneeva, Daria, Horio, Keiji, Higuchi, Masakazu, Yao, Ming-Shui, Doherty, Cara M., Maurin, Guillaume, Urayama, Kenji, Bavykina, Anastasiya, Horike, Satoshi, Gascon, Jorge, Semino, Rocio, Furukawa, Shuhei

“…Porous liquids (PLs) are attractive materials because of their capability to combine the intrinsic porosity of microporous solids and the processability of…”
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Understanding the multiscale self-assembly of metal-organic polyhedra towards functionally graded porous gels by Legrand, Alexandre, Craig, Gavin A, Bonneau, Mickaele, Minami, Saori, Urayama, Kenji, Furukawa, Shuhei

“…Spatial heterogeneity and gradients within porous materials are key for controlling their mechanical properties and mass/energy transport, both in biological…”
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Self-assembly of metal–organic polyhedra into supramolecular polymers with intrinsic microporosity by Carné-Sánchez, Arnau, Craig, Gavin A., Larpent, Patrick, Hirose, Takashi, Higuchi, Masakazu, Kitagawa, Susumu, Matsuda, Kenji, Urayama, Kenji, Furukawa, Shuhei

“…Designed porosity in coordination materials often relies on highly ordered crystalline networks, which provide stability upon solvent removal. However, the…”
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A Coordinative Solubilizer Method to Fabricate Soft Porous Materials from Insoluble Metal–Organic Polyhedra by Carné‐Sánchez, Arnau, Craig, Gavin A., Larpent, Patrick, Guillerm, Vincent, Urayama, Kenji, Maspoch, Daniel, Furukawa, Shuhei

“…Porous molecular cages have a characteristic processability arising from their solubility, which allows their incorporation into porous materials. Attaining…”
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Porous Colloidal Hydrogels Formed by Coordination‐Driven Self‐Assembly of Charged Metal‐Organic Polyhedra by Wang, Zaoming, Craig, Gavin A., Legrand, Alexandre, Haase, Frederik, Minami, Saori, Urayama, Kenji, Furukawa, Shuhei

“…Introduction of porosity into supramolecular gels endows soft materials with functionalities for molecular encapsulation, release, separation and conversion…”
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Spatiotemporal Control of Supramolecular Polymerization and Gelation of Metal–Organic Polyhedra by Legrand, Alexandre, Liu, Li-Hao, Royla, Philipp, Aoyama, Takuma, Craig, Gavin A, Carné-Sánchez, Arnau, Urayama, Kenji, Weigand, Jan J, Lin, Chia-Her, Furukawa, Shuhei

“…In coordination-based supramolecular materials such as metallogels, simultaneous temporal and spatial control of their assembly remains challenging. Here, we…”
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Rhodium-Based Metal–Organic Polyhedra Assemblies for Selective CO2 Photoreduction by Ghosh, Ashta C, Legrand, Alexandre, Rajapaksha, Rémy, Craig, Gavin A, Sassoye, Capucine, Balázs, Gábor, Farrusseng, David, Furukawa, Shuhei, Canivet, Jérôme, Wisser, Florian M

“…Heterogenization of molecular catalysts via their immobilization within extended structures often results in a lowering of their catalytic properties due to a…”
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Three-Way Crystal-to-Crystal Reversible Transformation and Controlled Spin Switching by a Nonporous Molecular Material by Costa, José Sánchez, Rodríguez-Jiménez, Santiago, Craig, Gavin A, Barth, Benjamin, Beavers, Christine M, Teat, Simon J, Aromí, Guillem

“…Porous materials capable of hosting external molecules are paramount in basic and applied research. Nonporous materials able to incorporate molecules via…”
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Pseudo-5-Fold-Symmetrical Ligand Drives Geometric Frustration in Porous Metal–Organic and Hydrogen-Bonded Frameworks by Haase, Frederik, Craig, Gavin A, Bonneau, Mickaële, Sugimoto, Kunihisa, Furukawa, Shuhei

“…Reticular framework materials thrive on designability, but unexpected reaction outcomes are crucial in exploring new structures and functionalities. By…”
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Magnetic Properties of a Family of [MnIII 4LnIII 4] Wheel Complexes: An Experimental and Theoretical Study by Craig, Gavin A, Velmurugan, Gunasekaran, Wilson, Claire, Valiente, Rafael, Rajaraman, Gopalan, Murrie, Mark

“…The chelating ligand 1,3-bis­(tris­(hydroxymethyl)­methylamino)­propane (H6L) has been used to synthesize a family of octanuclear heterometallic complexes with…”
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Rhodium-Based Metal-Organic Polyhedra Assemblies for Selective CO 2 Photoreduction by Ghosh, Ashta C, Legrand, Alexandre, Rajapaksha, Rémy, Craig, Gavin A, Sassoye, Capucine, Balázs, Gábor, Farrusseng, David, Furukawa, Shuhei, Canivet, Jérôme, Wisser, Florian M

“…Heterogenization of molecular catalysts via their immobilization within extended structures often results in a lowering of their catalytic properties due to a…”
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Field-Induced Slow Relaxation in a Monometallic Manganese(III) Single-Molecule Magnet by Craig, Gavin A, Marbey, Jonathan J, Hill, Stephen, Roubeau, Olivier, Parsons, Simon, Murrie, Mark

“…High-field electron paramagnetic resonance spectroscopy shows that the structurally distorted MnIII ion in Na5[Mn­(l-tart)2]·12H2O (1; l-tart = l-tartrate) has…”
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Statistical Distribution of Binary Ligands within Rhodium–Organic Octahedra Tunes Microporosity in Their Assemblies by Tateishi, Tomoki, Troyano, Javier, Tokuda, Shun, Craig, Gavin A., Krause, Simon, López-Olvera, Alfredo, Ibarra, Ilich A., Furukawa, Shuhei

“…Structure–porosity relationships for metal–organic polyhedra (MOPs) are hardly investigated because they tend to be amorphized after activation, which inhibits…”
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Porous Metal‐Organic Cages Based on Rigid Bicyclo[2.2.2]oct‐7‐ene Type Ligands: Synthesis, Structure, and Gas Uptake Properties by Doñagueda Suso, Beatriz, Legrand, Alexandre, Weetman, Catherine, Kennedy, Alan R., Fletcher, Ashleigh J., Furukawa, Shuhei, Craig, Gavin A.

“…Three new ligands containing a bicyclo[2.2.2]oct‐7‐ene‐2,3,5,6‐tetracarboxydiimide unit have been used to assemble lantern‐type metal‐organic cages with the…”
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Improving the gas sorption capacity in lantern-type metal-organic polyhedra by a scrambled cage method by Doñagueda Suso, Beatriz, Wang, Zaoming, Kennedy, Alan R, Fletcher, Ashleigh J, Furukawa, Shuhei, Craig, Gavin A

“…The synthesis of multivariate metal-organic frameworks (MOFs) is a well-known method for increasing the complexity of porous frameworks. In these materials,…”
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Switchable gate-opening effect in metal-organic polyhedra assemblies through solution processing by Craig, Gavin A, Larpent, Patrick, Kusaka, Shinpei, Matsuda, Ryotaro, Kitagawa, Susumu, Furukawa, Shuhei

“…Gate-opening gas sorption is known for metal-organic frameworks, and is associated with structural flexibility and advantageous properties for sensing and gas…”
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Probing the origin of the giant magnetic anisotropy in trigonal bipyramidal Ni(ii) under high pressure by Craig, Gavin A, Sarkar, Arup, Woodall, Christopher H, Hay, Moya A, Marriott, Katie E R, Kamenev, Konstantin V, Moggach, Stephen A, Brechin, Euan K, Parsons, Simon, Rajaraman, Gopalan, Murrie, Mark

“…Understanding and controlling magnetic anisotropy at the level of a single metal ion is vital if the miniaturisation of data storage is to continue to evolve…”
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Pressure induced enhancement of the magnetic ordering temperature in rhenium(IV) monomers by Woodall, Christopher H., Craig, Gavin A., Prescimone, Alessandro, Misek, Martin, Cano, Joan, Faus, Juan, Probert, Michael R., Parsons, Simon, Moggach, Stephen, Martínez-Lillo, José, Murrie, Mark, Kamenev, Konstantin V., Brechin, Euan K.

“…Materials that demonstrate long-range magnetic order are synonymous with information storage and the electronics industry, with the phenomenon commonly…”
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Spin state switching in 2,6-bis(pyrazol-3-yl)pyridine (3-bpp) based Fe(II) complexes by Craig, Gavin A., Roubeau, Olivier, Aromí, Guillem

“…•The synthesis of the new family of 2,6-bis(pyrazol-3-yl)pyridine type ligands (3-bpp) is reviewed.•A focus on SCO compounds of 3-bpp ligands is made,…”
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In-depth investigation of large axial magnetic anisotropy in monometallic 3d complexes using frequency domain magnetic resonance and ab initio methods: a study of trigonal bipyramidal Co(ii) by Hay, Moya A, Sarkar, Arup, Craig, Gavin A, Bhaskaran, Lakshmi, Nehrkorn, Joscha, Ozerov, Mykhailo, Marriott, Katie E R, Wilson, Claire, Rajaraman, Gopalan, Hill, Stephen, Murrie, Mark

“…The magnetic properties of 3d monometallic complexes can be tuned through geometric control, owing to their synthetic accessibility and relative structural…”
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