Search Results - "Costil, Romain"
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1
Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media
Published in Angewandte Chemie International Edition (17-05-2021)“…Amphiphilic molecules, comprising hydrophobic and hydrophilic moieties and the intrinsic propensity to self‐assemble in aqueous environment, sustain a…”
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Journal Article -
2
Atropisomerism in Diarylamines: Structural Requirements and Mechanisms of Conformational Interconversion
Published in Angewandte Chemie International Edition (12-10-2020)“…In common with other hindered structures containing two aromatic rings linked by a short tether, diarylamines may exhibit atropisomerism (chirality due to…”
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Journal Article -
3
Heavily Substituted Atropisomeric Diarylamines by Unactivated Smiles Rearrangement of N‐Aryl Anthranilamides
Published in Angewandte Chemie International Edition (02-10-2017)“…Diarylamines find use as metal ligands and as structural components of drug molecules, and are commonly made by metal‐catalyzed C−N coupling. However, the…”
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Journal Article -
4
Self‐Assembly of Photoresponsive Molecular Amphiphiles in Aqueous Media
Published in Angewandte Chemie (17-05-2021)“…Amphiphilic molecules, comprising hydrophobic and hydrophilic moieties and the intrinsic propensity to self‐assemble in aqueous environment, sustain a…”
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Journal Article -
5
Medium‐Sized‐Ring Analogues of Dibenzodiazepines by a Conformationally Induced Smiles Ring Expansion
Published in Angewandte Chemie International Edition (13-11-2017)“…Analogues of dibenzodiazepines, in which the seven‐membered nitrogen heterocycle is replaced by a 9–12‐membered ring, were made by an unactivated Smiles…”
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Journal Article -
6
Chemically Driven Rotatory Molecular Machines
Published in Angewandte Chemie International Edition (04-10-2022)“…Molecular machines are at the frontier of biology and chemistry. The ability to control molecular motion and emulating the movement of biological systems are…”
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Journal Article -
7
Directing Coupled Motion with Light: A Key Step Toward Machine-Like Function
Published in Chemical reviews (10-11-2021)“…Molecular photoactuators can control shape and chemical or physical properties of the responsive system they are embedded in. These effects are usually…”
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Journal Article -
8
Coupling Rotary Motion to Helicene Inversion within a Molecular Motor
Published in Angewandte Chemie International Edition (11-11-2024)“…Towards complex coupled molecular motions, the remote handedness inversion of a helicene moiety was achieved by a rotary molecular motor. The use of a…”
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Journal Article -
9
Stereodivergent Chirality Transfer by Noncovalent Control of Disulfide Bonds
Published in Journal of the American Chemical Society (16-03-2022)“…Controlling dynamic stereochemistry is an important challenge, as it is not only inherent to protein structure and function but often governs supramolecular…”
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Journal Article -
10
Modulation of a Supramolecular Figure‐of‐Eight Strip Based on a Photoswitchable Stiff‐Stilbene
Published in Chemistry : a European journal (23-06-2020)“…The preparation, assembly and dynamic properties of photoswitchable bisphosphine ligands based on the stiff‐stilbene scaffold are reported. Directional bonding…”
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Journal Article -
11
Light- and Temperature-Controlled Hybridization, Chiral Induction and Handedness of Helical Foldamers
Published in Angewandte Chemie International Edition (31-10-2024)“…Helical foldamers have attracted much attention over the last decades given their resemblance to certain biomacromolecules and their potential in domains as…”
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Journal Article -
12
Effect of charge-transfer enhancement on the efficiency and rotary mechanism of an oxindole-based molecular motor
Published in Chemical science (Cambridge) (02-06-2021)“…Harvesting energy and converting it into mechanical motion forms the basis for both natural and artificial molecular motors. Overcrowded alkene-based…”
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Journal Article -
13
Coupled Rocking Motion in a Light-Driven Rotary Molecular Motor
Published in Journal of organic chemistry (05-01-2024)“…Coupled motion is ubiquitous in Nature as it forms the base for the direction, amplification, propagation, and synchronization of movement. Herein, we present…”
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Journal Article -
14
Coupling Rotary Motion to Helicene Inversion within a Molecular Motor
Published in Angewandte Chemie (11-11-2024)“…Towards complex coupled molecular motions, the remote handedness inversion of a helicene moiety was achieved by a rotary molecular motor. The use of a…”
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Journal Article -
15
Restricted rotation in sterically hindered diarylamines : structural requirements, synthesis, and applications of a new class of atropisomers
Published 01-01-2019“…Although the stereochemistry of most atropisomers arises from slow rotation about a C-C bond, the ability of the nitrogen atom to adopt a planar geometry…”
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Dissertation -
16
Chemically Driven Rotatory Molecular Machines
Published in Angewandte Chemie (04-10-2022)“…Molecular machines are at the frontier of biology and chemistry. The ability to control molecular motion and emulating the movement of biological systems are…”
Get full text
Journal Article -
17
Light‐ and Temperature‐Controlled Hybridization, Chiral Induction and Handedness of Helical Foldamers
Published in Angewandte Chemie (31-10-2024)“…Abstract Helical foldamers have attracted much attention over the last decades given their resemblance to certain biomacromolecules and their potential in…”
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Journal Article -
18
Medium‐Sized‐Ring Analogues of Dibenzodiazepines by a Conformationally Induced Smiles Ring Expansion
Published in Angewandte Chemie (13-11-2017)“…Analogues of dibenzodiazepines, in which the seven‐membered nitrogen heterocycle is replaced by a 9–12‐membered ring, were made by an unactivated Smiles…”
Get full text
Journal Article -
19
Atropisomerism in Diarylamines: Structural Requirements and Mechanisms of Conformational Interconversion
Published in Angewandte Chemie (12-10-2020)“…In common with other hindered structures containing two aromatic rings linked by a short tether, diarylamines may exhibit atropisomerism (chirality due to…”
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Journal Article -
20
Light‐Driven Spiral Deformation of Supramolecular Helical Microfibers by Localized Photoisomerization
Published in Advanced optical materials (01-01-2022)“…Stimuli‐responsive mechanical deformations widely occur in biological systems but the design of biomimetic shape‐changing materials, especially those based on…”
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Journal Article