Search Results - "Costanzo, Philip J"
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A Library of Thermoresponsive, Coacervate-Forming Biodegradable Polyesters
Published in Macromolecules (23-06-2015)“…We report on a new class of thermoresponsive biodegradable polyesters (TR-PE) inspired by polyacrylamides and elastin-like proteins (ELPs). The polyesters…”
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2
Thermally Driven Assembly of Nanoparticles in Polymer Matrices
Published in Macromolecules (29-05-2007)“…Thermally responsive bulk polymer films utilizing reversible Diels−Alder chemistry have been developed. Gold nanoparticles (AuNPs) were passivated with…”
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3
Synthesis and Characterization of Ionic Polymer Networks in a Room-Temperature Ionic Liquid
Published in ACS applied materials & interfaces (28-11-2012)“…Ionic liquid gels (ILGs) for potential use in ion transport and separation applications were generated via a free radical copolymerization of…”
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4
Polymer brushes under high load
Published in PloS one (13-03-2013)“…Polymer coatings are frequently used to provide repulsive forces between surfaces in solution. After 25 years of design and study, a quantitative model to…”
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5
Thermoresponsive, Optically Active Films Based On Diels–Alder Chemistry
Published in Chemistry of materials (11-12-2007)“…Reversible Diels–Alder chemistry was exploited to develop polymer films in which a change in optical clarity can be thermally triggered. SiO2 nanoparticles of…”
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6
Characterization of Reagent Pencils for Deposition of Reagents onto Paper-Based Microfluidic Devices
Published in Micromachines (Basel) (05-08-2017)“…Reagent pencils allow for solvent-free deposition of reagents onto paper-based microfluidic devices. The pencils are portable, easy to use, extend the…”
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7
Synthesis and Characterization of Poly(methyl acrylate) Grafted from Poly(thiophene) to Form Solid-State Fluorescent Materials
Published in Macromolecules (27-08-2002)“…This paper describes the synthesis and characterization of graft copolymers having a poly(thiophene) (PT) backbone with poly(methyl acrylate) (pMA) sidearms…”
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8
Experimental and Theoretical Exploration of the Kinetics and Thermodynamics of the Nucleophile-Induced Fragmentation of Ylidenenorbornadiene Carboxylates
Published in Journal of organic chemistry (18-08-2023)“…Ylidenenorbornadienes (YNDs), prepared by [4 + 2] cycloadditions between fulvenes and acetylene carboxylates, react with thiol nucleophiles to yield mixtures…”
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9
Unraveling Polymer Structures with RAFT Polymerization and Diels–Alder Chemistry
Published in Macromolecules (12-02-2019)“…Using Diels–Alders (DA) chemistry as a dynamic-covalent linkage, we explored the kinetic growth mechanism of polymer structures including starlike materials…”
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10
Reagent pencils: a new technique for solvent-free deposition of reagents onto paper-based microfluidic devices
Published in Lab on a chip (21-05-2015)“…Custom-made pencils containing reagents dispersed in a solid matrix were developed to enable rapid and solvent-free deposition of reagents onto membrane-based…”
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11
Ylidenenorbornadiene Carboxylates: Experimental Kinetic Analysis of a Nucleophile-Induced Fragmentation Reaction
Published in Organic letters (22-04-2022)“…Ylidenenorbornadienes (YNDs), prepared by [4 + 2] cycloadditions between fulvenes and acetylene carboxylates, react with beta-mercaptoethanol to yield a…”
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12
Directing the Deposition of Ferromagnetic Cobalt onto Pt-Tipped CdSe@CdS Nanorods: Synthetic and Mechanistic Insights
Published in ACS nano (23-10-2012)“…A methodology providing access to dumbbell-tipped, metal–semiconductor and metal oxide–semiconductor heterostructured nanorods has been developed. The…”
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13
Trials and adventures of the synthesis and evaluation of amphiphilic graft copolymers with dynamic topology
Published in Journal of polymer science (2020) (15-11-2022)“…Amphiphilic graft copolymers were prepared via a grafting through approach to yield materials with a hydrophilic backbone and hydrophobic arms. The thermally…”
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14
Development of Polymeric Phase Change Materials On the basis of Diels−Alder Chemistry
Published in Macromolecules (27-07-2010)“…Diels−Alder (DA) chemistry is increasing popular due to its simplicity and efficiency; however, one concept that has yet to be thoroughly explored is…”
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15
Synthetic design and investigation of novel polymeric surfactants
Published in Polymer (Guilford) (18-08-2015)“…A library of polymeric amphiphiles was prepared based on a one-pot methodology using reversible addition fragmentation chain transfer (RAFT) polymerization…”
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16
Exploring polymer solubility with thermally‐responsive Diels‐Alder monomers: Revisiting the monkey's fist
Published in Journal of polymer science (2020) (15-01-2022)“…Thermo‐responsive monomers were designed to contain a Diels‐Alder (DA) adduct such that cyclo‐reversion would yield either the maleimide or the furan unit…”
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17
Using Thiol–Gold Bond Formation To Bridge Surfaces with a Polymer Brush: SFA Experiments and MD Simulations
Published in Macromolecules (23-12-2013)“…Complementary interactions between functionalized surfaces are challenging to quantify, as both kinetics and thermodynamics are important. Optimal reaction…”
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18
Controlling Surface Energy and Wetability with Diels−Alder Chemistry
Published in Langmuir (16-03-2010)“…Reversible Diels−Alder chemistry was utilized to manipulate the surface energy of glass substrates. Hydrophobic dieneophiles were prepared and attached to…”
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19
Thermal-initiated hydroxyethyl methacrylate functionalization of multiwalled carbon nanotubes
Published in Journal of applied polymer science (15-07-2011)“…Multiwalled‐carbon nanotubes (MWCNTs) were functionalized via thermoinitiated free radical polymerization of 2‐hydroxyethyl methacrylate (HEMA) using benzoyl…”
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Controlling Dispersion and Migration of Particulate Additives with Block Copolymers and Diels−Alder Chemistry
Published in Langmuir (21-11-2006)“…Reversible Diels−Alder chemistry was exploited to develop thermo-responsive polymer films. Here, low molecular weight poly(styrene) (PS) and poly(ethylene…”
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