Search Results - "Costa, José Sanchez"
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Influence of Sample Preparation, Temperature, Light, and Pressure on the Two-Step Spin Crossover Mononuclear Compound [Fe(bapbpy)(NCS)2]
Published in Chemistry of materials (24-03-2009)“…The three phases of the mononuclear two-step spin crossover compound [Fe(bapbpy)(NCS)2] (1) are characterized by powder X-ray diffraction, Mössbauer…”
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2
Photoswitching of the Dielectric Constant of the Spin-Crossover Complex [Fe(L)(CN)2]⋅H2O
Published in Angewandte Chemie International Edition (27-02-2006)“…Photoswitching of the dielectric constant has been observed for the first time in the spin‐crossover complex [Fe(L)(CN)2]⋅H2O…”
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3
Unusual Solvent Dependence of a Molecule-Based FeII Macrocyclic Spin-Crossover Complex
Published in European journal of inorganic chemistry (01-10-2014)“…This work illustrates in detail the reversible hydration–dehydration process of a molecule‐based material, which involves a drastic change of the switchable…”
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4
Controlled Copper-Mediated Chlorination of Phenol Rings under Mild Conditions
Published in Inorganic chemistry (11-06-2007)“…The very unusual case of copper-mediated chlorination of phenol rings under mild conditions at room temperature is reported. Reaction of the ligand…”
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5
Three-Way Crystal-to-Crystal Reversible Transformation and Controlled Spin Switching by a Nonporous Molecular Material
Published in Journal of the American Chemical Society (12-03-2014)“…Porous materials capable of hosting external molecules are paramount in basic and applied research. Nonporous materials able to incorporate molecules via…”
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6
Reversible single-crystal-to-single-crystal transformations in coordination compounds induced by external stimuli
Published in Coordination chemistry reviews (01-02-2022)“…•Reversible single-crystal to single-crystal transformations (SCSC) in Coordination Compounds.•Reversible Structural transformations can be followed via single…”
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Effect of ligand substitution in [Fe(H-trz)2(trz)]BF4 spin crossover nanoparticles
Published in French-Ukrainian journal of chemistry (2015)“…Spin crossover iron(II) 1,2,4-triazole-based coordination compounds in the form of nanoparticles were prepared using a reverse microemulsion technique. Ligand…”
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Reversible Chromism of Tethered Ruthenium(II) Complexes in the Solid State
Published in Inorganic chemistry (01-05-2023)“…Tethered ruthenium(II) complexes [Ru(η6:κ1-arene:N)Cl2] (where arene:N is 2-aminobiphenyl (1) and 2-benzylpyridine (2)) can convert into their open-tethered…”
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9
Spin-state-dependent electrical conductivity in single-walled carbon nanotubes encapsulating spin-crossover molecules
Published in Nature communications (11-03-2021)“…Spin crossover (SCO) molecules are promising nanoscale magnetic switches due to their ability to modify their spin state under several stimuli. However, SCO…”
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10
Tracking the Light‐Induced Excited‐State Dynamics and Structural Configurations of an Extraordinarily Long‐Lived Metastable State at Room Temperature
Published in Chemistry : a European journal (21-08-2020)“…Time‐resolved X‐ray (Tr‐XAS) and optical transient absorption (OTA) spectroscopy on the pico‐microsecond timescale coupled with density functional theory…”
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11
A switchable iron-based coordination polymer toward reversible acetonitrile electro-optical readout
Published in Chemical science (Cambridge) (21-07-2019)“…Efficient and low cost detection of harmful volatile organic compounds (VOCs) is a major health and environmental need in industrialized societies. For this,…”
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12
On the dielectric properties of the spin crossover complex [Fe(bpp)2] [BF4]2
Published in Physica status solidi. A, Applications and materials science (01-09-2006)“…The thermal variation of the dielectric constant in the spin crossover complex [Fe(bpp)2] [BF4]2 displays a 16 K large hysteresis loop centered around 178 K…”
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Current Switching Coupled to Molecular Spin-States in Large-Area Junctions
Published in Advanced materials (Weinheim) (01-09-2016)“…The fabrication of large‐area vertical junctions with a molecular spin‐crossover complex displaying concerted changes of spin degrees of freedom and…”
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14
Spin Crossover-Assisted Modulation of Electron Transport in a Single-Crystal 3D Metal–Organic Framework
Published in Chemistry of materials (08-08-2023)“…Molecule-based spin crossover (SCO) materials display likely one of the most spectacular switchable processes. The SCO involves reversible changes in their…”
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15
Two-Step Spin Crossover 3D Hofmann-Type Coordination Polymers Including a Functional Group in the Organic Moiety
Published in Crystal growth & design (07-06-2023)“…Spin crossover (SCO) complexes can switch between two electronic states in response to various stimuli. Coordination complexes can be assembled to form…”
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16
A typical example of a photomagnetic study carried out on a spin-crossover material
Published in Bulletin of materials science (01-11-2006)“…The light-induced excited spin state trapping (LIESST) is a well known phenomenon in an iron(II) spin-crossover (SCO) material which offers some interesting…”
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17
Playing with the weakest supramolecular interactions in a 3D crystalline hexakis[60]fullerene induces control over hydrogenation selectivity
Published in Chemical science (Cambridge) (01-07-2021)“…Weak forces can play an essential role in chemical reactions. Controlling such subtle forces in reorganization processes by applying thermal or chemical…”
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Coupled Crystallographic Order-Disorder and Spin State in a Bistable Molecule: Multiple Transition Dynamics
Published in Chemistry : a European journal (07-03-2011)“…A novel bispyrazolylpyridine ligand incorporating lateral phenol groups, H4L, has led to an FeII spin‐crossover (SCO) complex, [Fe(H4L)2][ClO4]2⋅H2O⋅2 (CH3)2CO…”
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A Three‐Dimensional Dynamic Supramolecular “Sticky Fingers” Organic Framework
Published in Angewandte Chemie (International ed.) (18-02-2019)“…Engineering high‐recognition host–guest materials is a burgeoning area in basic and applied research. The challenge of exploring novel porous materials with…”
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Chemical Modification of a Bridging Ligand Inside a Metal-Organic Framework while Maintaining the 3D Structure
Published in European Journal of Inorganic Chemistry (01-04-2008)“…A new metal–organic framework (MOF) with amino groups situated inside the pores has been synthesized. This MOF has been modified by post‐synthesis with two…”
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