Search Results - "Cooper, Benjamin F. T."

Cationic Crown Ether Complexes of Germanium(II) by Rupar, Paul A, Bandyopadhyay, Rajoshree, Cooper, Benjamin F.T, Stinchcombe, Michael R, Ragogna, Paul J, Macdonald, Charles L.B, Baines, Kim M

“…Fit for a king: Cationic complexes of GeII can be prepared by using crown ethers to stabilize and protect the germanium center. Three different crown ethers…”
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Non-Innocent Ligand Effects on Low-Oxidation-State Indium Complexes by Allan, Christopher J., Cooper, Benjamin F. T., Cowley, Hugh J., Rawson, Jeremy M., Macdonald, Charles L. B.

“…Attempts to coordinate neutral ligands to low oxidation state indium centers are often hindered by disproportionation pathways that produce elemental indium…”
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Experimental and Computational Insights into the Stabilization of Low-Valent Main Group Elements Using Crown Ethers and Related Ligands by Macdonald, Charles L. B, Bandyopadhyay, Rajoshree, Cooper, Benjamin F. T, Friedl, Warren W, Rossini, Aaron J, Schurko, Robert W, Eichhorn, S. Holger, Herber, Rolfe H

“…A series of tin­(II) triflate and chloride salts in which the cations are complexed by either cyclic or acyclic polyether ligands and which have…”
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Low-Valent Chemistry: An Alternative Approach to Phosphorus-Containing Oligomers by Kosnik, Stephanie C, Farrar, Gregory J, Norton, Erin L, Cooper, Benjamin F. T, Ellis, Bobby D, Macdonald, Charles L. B

“…A convenient preparative approach to low-valent phosphorus-rich oligomers is presented. Ligand substitution reactions involving anionic diphosphine ligands of…”
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Activation of Anisole by Organoplatinum(II) Complexes: Evidence for Rate-Determining C–H Activation by Bonnington, Kevin J, Zhang, Fenbao, Moustafa, Mahmoud M. Abd Rabo, Cooper, Benjamin F. T, Jennings, Michael C, Puddephatt, Richard J

“…A study of the basis of selectivity of C–H bond activation of anisole by electrophilic methylplatinum­(II) complexes is reported. Anisole reacts with…”
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Gas Production in the Bromate−Pyrocatechol Oscillator by Harati, Mohammad, Green, James R, Cooper, Benjamin F. T, Wang, Jichang

“…A significant amount of gas production has been observed in the bromate−pyrocatechol oscillator under high concentrations of bromate and pyrocatechol. The…”
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Preferred Bonding Motif for Indium Aminoethanethiolate Complexes:  Structural Characterization of (Me2NCH2CH2S)2InX/SR (X = Cl, I; R = 4-MeC6H4, 4-MeOC6H4) by Briand, Glen G, Cooper, Benjamin F. T, MacDonald, David B. S, Martin, Caleb D, Schatte, Gabriele

“…The metathesis reaction of InCl3 with Me2NCH2CH2SNa or the redox reaction of indium metal with elemental iodine and the disulfide (Me2NCH2CH2S)2 yield the…”
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Synthesis and Self-Association of Organoplatinum(IV) Boronic Acids by Safa, Muhieddine A, Abo-Amer, Anwar, Borecki, Aneta, Cooper, Benjamin F. T, Puddephatt, Richard J

“…Oxidative addition of ortho, meta, and para isomers of BrCH2C6H4B(OH)2 to dimethylplatinum(II) complexes gave the corresponding organoplatinum(IV) boronic…”
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A Convenient Method for the Preparation of N-Heterocyclic Bromophosphines: Excellent Precursors to the Corresponding N-Heterocyclic Phosphenium Salts by Dube, Jonathan W, Farrar, Gregory J, Norton, Erin L, Szekely, Kara L. S, Cooper, Benjamin F. T, Macdonald, Charles L. B

“…An in situ redox method is employed to prepare N-heterocyclic bromophosphines in good yield and purity. Such bromophosphines may be treated with a variety of…”
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The asymmetric total synthesis of (-)-securinine by Dhudshia, Bhartesh, Cooper, Benjamin F T, Macdonald, Charles L B, Thadani, Avinash N

“…The alkaloid (-)-securinine was synthesized in 18 steps and 16% overall yield from trans-4-hydroxy-l-proline…”
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Palladium(II) complexes with salicylideneimine based tridentate ligand and triphenylphosphine: Synthesis, structure and catalytic activity in Suzuki–Miyaura cross coupling reactions by Muthu Tamizh, Manoharan, Cooper, Benjamin F.T., Macdonald, Charles L.B., Karvembu, Ramasamy

“…Six square planar Pd(II) complexes have been prepared from the reactions between [Pd(PPh3)4] and salicylideneimine based tridentate ligands, and characterized…”
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The mechanism of oxidative addition of iodine to a dimethylplatinum(II) complex by Nabavizadeh, S. Masoud, Amini, Hashem, Rashidi, Mehdi, Pellarin, Kyle R., McCready, Matthew S., Cooper, Benjamin F.T., Puddephatt, Richard J.

“…The oxidative addition of iodine to [PtMe2(bipy)], 1, occurs easily with trans stereochemistry to give trans-[PtI2Me2(bipy)], 2a, which then equilibrates…”
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A 115 In solid-state NMR study of low oxidation-state indium complexes by Hamaed, Hiyam, Johnston, Karen E., Cooper, Benjamin F. T., Terskikh, Victor V., Ye, Eric, Macdonald, Charles L. B., Arnold, Donna C., Schurko, Robert W.

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(1,4,7,10,13,16-Hexaoxacyclooctadecane)dimethylindium(III) trifluoromethanesulfonate by Cooper, Benjamin F. T., Macdonald, Charles L. B.

“…In the title compound, [In(CH3)2(C12H24O6)](CF3O3S), two of the In—O distances within the cation are significantly shorter than the other four. The InIII…”
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"Crowned" Univalent Indium Complexes as Donors? Experimental and Computational Insights on the Valence Isomers of EE′X4 Species by Cooper, Benjamin F. T., Hamaed, Hiyam, Friedl, Warren W., Stinchcombe, Michael R., Schurko, Robert W., Macdonald, Charles L. B.

“…The use of the univalent indium reagent [In([18]crown‐6)][OTf] as a donor is investigated by its reactions with acceptors including InX3 (X=Cl, Br, I). The…”
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(1,4,7,10,13,16-Hexaoxacyclo-octa-deca-ne)dimethyl-indium(III) trifluoro-methane-sulfonate by Cooper, Benjamin F T, Macdonald, Charles L B

“…In the title compound, [In(CH(3))(2)(C(12)H(24)O(6))](CF(3)O(3)S), two of the In-O distances within the cation are significantly shorter than the other four…”
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Synthesis and structure of an indium(I) “crown sandwich” by Cooper, Benjamin F.T., Macdonald, Charles L.B.

“…The reaction of indium(I) trifluoromethanesulfonate, InOTf, with the crown ether 15-crown-5 produces the salt [In(15-crown-5) 2][OTf] regardless of the…”
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Crown ether complexes of tin(II) trifluoromethanesulfonate by Bandyopadhyay, Rajoshree, Cooper, Benjamin F.T., Rossini, Aaron J., Schurko, Robert W., Macdonald, Charles L.B.

“…The treatment of tin(II) trifluoromethanesulfonate with crown ethers of different sizes produces salts of three different cationic tin crown ether complexes in…”
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A 115In solid-state NMR study of low oxidation-state indium complexesElectronic Supplementary Information (ESI) available: Additional experimental details and NMR data. See DOI: 10.1039/c3sc52809j by Hamaed, Hiyam, Johnston, Karen E, Cooper, Benjamin F. T, Terskikh, Victor V, Ye, Eric, Macdonald, Charles L. B, Arnold, Donna C, Schurko, Robert W

“…115 In solid-state NMR (SSNMR) spectroscopy is applied to characterise a variety of low oxidation-state indium( i ) compounds. 115 In static wideline SSNMR…”
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"Crowned" univalent indium complexes as donors? Experimental and computational insights on the valence isomers of EE'X4 species by Cooper, Benjamin F T, Hamaed, Hiyam, Friedl, Warren W, Stinchcombe, Michael R, Schurko, Robert W, Macdonald, Charles L B

“…The use of the univalent indium reagent [In([18]crown-6)][OTf] as a donor is investigated by its reactions with acceptors including InX(3) (X=Cl, Br, I). The…”
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