Search Results - "Coombs, Deborah L."

Transition metal boryl and borylene complexes: substitution and abstraction chemistry by Aldridge, Simon, Coombs, Deborah L.

“…In this article, an account is given of recent developments in the chemistry of transition metal complexes of boron. Particular emphasis has been placed on the…”
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[(eta 5-C5H5)Fe(CO)2]2B(2,4,6-Me3C6H2): synthesis, spectroscopic and structural characterization of a transition metal complex containing an unsupported bridging borylene ligand by Aldridge, Simon, Coombs, Deborah L, Jones, Cameron

“…The synthesis and characterisation of the dinuclear iron complex [(eta 5-C5H5)Fe(CO)2]2B(2,4,6-Me3C6H2) containing an unsupported bridging borylene ligand are…”
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Influence of Ligand Steric Bulk in the Synthesis of Transition-Metal Borylene Complexes by Coombs, Deborah L, Aldridge, Simon, Coles, Simon J, Hursthouse, Michael B

“…The differing steric requirements of phenyl and mesityl substituents have been shown to influence reactivity in asymmetric transition-metal haloboryl complexes…”
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Cationic Terminal Borylene Complexes: Interconversion of Amino and Alkoxy Borylenes by an Unprecedented Meerwein-Ponndorf Hydride Transfer by Kays (née Coombs), Deborah L., Day, Joanna K., Aldridge, Simon, Harrington, Ross W., Clegg, William

“…It's all new to B: In the reaction of borylene complex 1 with benzophenone, a Meerwein–Ponndorf β‐hydride transfer from the aminoborylene ligand to the…”
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Cationic Terminal Borylenes by Halide Abstraction:  Synthesis and Spectroscopic and Structural Characterization of an FeB Double Bond by Coombs, Deborah L, Aldridge, Simon, Jones, Cameron, Willock, David J

“…The synthesis and the spectroscopic and structural characterization of the cationic terminal borylene complex [Cp*Fe(CO)2(BMes)]+ are reported. Halide…”
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Admissions file review: applying the multiple independent sampling (MIS) methodology by Hanson, Mark D, Kulasegaram, Kulamakan Mahan, Coombs, Deborah L, Herold, Jodi

“…Although multiple independent sampling (MIS) has been adapted for admissions interviews, its application for assessing written materials in the admissions file…”
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Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue by Aldridge, Simon, Jones, Cameron, Gans-Eichler, Timo, Stasch, Andreas, Kays (née Coombs), Deborah L., Coombs, Natalie D., Willock, David J.

“…Charge changes everything: The cationic terminal aminoborylene complex [CpFe(CO)2(BNCy2)]+[BArF4]− (1, Cy= cyclohexyl, ArF=3,5‐(CF3)2C6H3; Fe orange, B green,…”
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FeB Double Bonds:  Synthetic, Structural, and Reaction Chemistry of Cationic Terminal Borylene Complexes by Coombs, Deborah L, Aldridge, Simon, Rossin, Andrea, Jones, Cameron, Willock, David J

“…Application of halide abstraction chemistry to asymmetric haloboryl complexes (η5-C5Me5)Fe(CO)2B(ER n )X leads to the first synthetic route to cationic…”
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Substitution, abstraction and addition chemistry of low-coordinate gallium and indium ligand systems by Coombs, Natalie D., Bunn, Natalie R., Kays (née Coombs), Deborah L., Day, Joanna K., Ooi, Li-Ling, Aldridge, Simon

“…Substitution, abstraction and addition processes are shown to be viable chemistries for the modification of ligand systems featuring heavier group 13 element…”
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Crystal Structure of 1,3,6-Tribromocarbazole by COWLEY, Andrew, JOHNSTON, David, KAYS (née COOMBS), Deborah, WATKIN, David

“…The crystal structure properties of 1,3,6-tribromocarbazole (1) are: orthorhombic, space group Pna21 with a = 17.3110(3)Å, b = 4.5608(2)Å, c = 14.9606(2)Å, V =…”
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Cationic Terminal Borylene Complexes: A Synthetic and Mechanistic Investigation of MB Metathesis Chemistry by Kays (née Coombs), Deborah L., Day, Joanna K., Ooi, Li-Ling, Aldridge, Simon

“…Halide ion chemistry has been exploited to generate the cationic terminal borylene complex 1, which reacts with Ph3PS or Ph3AsO to form 3 and 4. In the case…”
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Cationic Terminal Borylenes by Halide Abstraction:  Synthesis and Spectroscopic and Structural Characterization of an FeB Double Bond by Coombs, Deborah L., Aldridge, Simon, Jones, Cameron, Willock, David J.

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Substitution chemistry of sterically demanding boryl ligands by Coombs, Deborah L., Aldridge, Simon, Jones, Cameron

“…The synthetic and reaction chemistry of the asymmetric aryl(bromo)boryl complexes (η5‐C5H5)Fe(CO)2B(Ar)Br [Ar = 2,4,6‐Me3C6H2, Mes (3);…”
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FeB Double Bonds:  Synthetic, Structural, and Reaction Chemistry of Cationic Terminal Borylene Complexes by Coombs, Deborah L., Aldridge, Simon, Rossin, Andrea, Jones, Cameron, Willock, David J.

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Structures of the Metallated Trihalogallate and Indate Ions [η5-C5Me5)Fe(CO)2InI3]- and [(η5-C5H5)Fe(CO)2GaI2Br] by Aldridge, Simon, Kays (née Coombs), Deborah L., Bunn, Natalie R., Coombs, Natalie D., Ooi, Li-ling

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Cationic Terminal Borylene Complexes: Interconversion of Amino and Alkoxy Borylenes by an Unprecedented Meerwein-Ponndorf Hydride Transfer by Kays (née Coombs), Deborah L., Day, Joanna K., Aldridge, Simon, Harrington, Ross W., Clegg, William

“…Alles neu für B: Bei der Reaktion des Borylenkomplexes 1 mit Benzophenon führt eine Meerwein‐Ponndorf‐β‐Hydridübertragung vom Aminoborylen‐Liganden auf das…”
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Cationic Terminal Borylene Complexes: A Synthetic and Mechanistic Investigation of MB Metathesis Chemistry by Kays (née Coombs), Deborah L., Day, Joanna K., Ooi, Li-Ling, Aldridge, Simon

“…Durch Halogenidabstraktion entsteht der kationische terminale Borylenkomplex 1, der mit Ph3PS oder Ph3AsO zu 3 und 4 reagiert. Bei der entsprechenden…”
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Thoughts and Suggestions on the Social Problem and Things in General (1888-1889) by Thompson, Phillips, Coombs, Deborah L., Kealey, Gregory S., Berton, Pierre

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Complementary anion binding by bidentate boron-containing Lewis acids by Coombs, Natalie D., Aldridge, Simon, Wiltshire, Gavin, Kays (née Coombs), Deborah L., Bresner, Christopher, Ooi, Li-ling

“…Anion binding by the pyroborates (catB) 2O ( 1, cat = O 2C 6H 4-1,2) and ( S, S-Ph 2C 2H 2O 2B) 2O ( 2) has been investigated by spectroscopic, structural and…”
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Cationic Terminal Borylene Complexes: Structure/Bonding Analysis and [4+1] Cycloaddition Reactivity of a BN Vinylidene Analogue by Aldridge, Simon, Jones, Cameron, Gans-Eichler, Timo, Stasch, Andreas, Kays (née Coombs), Deborah L., Coombs, Natalie D., Willock, David J.

“…Eine Ladung verändert alles: Der kationische terminale Aminoborylenkomplex [CpFe(CO)2(BNCy2)]+[BArF4]− (1, Cy=Cyclohexyl, ArF=3,5‐(CF3)2C6H3; Fe orange, B…”
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