Search Results - "Cool, Terrill A"
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Biofuel Combustion Chemistry: From Ethanol to Biodiesel
Published in Angewandte Chemie (International ed.) (10-05-2010)“…Biofuels, such as bio-ethanol, bio-butanol, and biodiesel, are of increasing interest as alternatives to petroleum-based transportation fuels because they…”
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Photoionization mass spectrometry and modeling studies of the chemistry of fuel-rich dimethyl ether flames
Published in Proceedings of the Combustion Institute (2007)“…Reaction paths are identified for dimethyl ether (DME) combustion using modeling of new data from fuel-rich DME flat flames. A molecular-beam flame-sampling…”
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3
Recent contributions of flame-sampling molecular-beam mass spectrometry to a fundamental understanding of combustion chemistry
Published in Progress in energy and combustion science (01-04-2009)“…Flame-sampling molecular-beam mass spectrometry of premixed, laminar, low-pressure flat flames has been demonstrated to be an efficient tool to study…”
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"Imaging" combustion chemistry via multiplexed synchrotron-photoionization mass spectrometry
Published in Physical chemistry chemical physics : PCCP (01-01-2008)“…The combination of multiplexed mass spectrometry with photoionization by tunable-synchrotron radiation has proved to be a powerful tool to investigate…”
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Isomer-specific combustion chemistry in allene and propyne flames
Published in Combustion and flame (01-11-2009)“…A combined experimental and modeling study is performed to clarify the isomer-specific combustion chemistry in flames fueled by the C 3H 4 isomers allene and…”
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Isomer-Specific Fuel Destruction Pathways in Rich Flames of Methyl Acetate and Ethyl Formate and Consequences for the Combustion Chemistry of Esters
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-05-2007)“…The influences of fuel-specific destruction pathways on flame chemistry are determined for two isomeric ester fuels, methyl acetate, CH3(CO)OCH3, and ethyl…”
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Isomer-Specific Influences on the Composition of Reaction Intermediates in Dimethyl Ether/Propene and Ethanol/Propene Flame
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (02-10-2008)“…This work provides experimental evidence on how the molecular compositions of fuel-rich low-pressure premixed flames are influenced as the oxygenates dimethyl…”
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Enols Are Common Intermediates in Hydrocarbon Oxidation
Published in Science (American Association for the Advancement of Science) (24-06-2005)“…Models for chemical mechanisms of hydrocarbon oxidation rely on spectrometric identification of molecular structures in flames. Carbonyl (keto) compounds are…”
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Benzene precursors and formation routes in a stoichiometric cyclohexane flame
Published in Proceedings of the Combustion Institute (2007)“…Benzene formation was found to be dominated by stepwise radical dehydrogenation of cyclohexane in a stoichiometric flat flame of cyclohexane/O 2/32.5% Ar,…”
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Identification of C5Hx Isomers in Fuel-Rich Flames by Photoionization Mass Spectrometry and Electronic Structure Calculations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (06-04-2006)“…The isomeric composition of C(5)H(x) (x = 2-6, 8) flame species is analyzed for rich flames fueled by allene, propyne, cyclopentene, or benzene. Different…”
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Identification and Chemistry of C4H3 and C4H5 Isomers in Fuel-Rich Flames
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (16-03-2006)“…Quantitative identification of isomers of hydrocarbon radicals in flames is critical to understanding soot formation. Isomers of C4H3 and C4H5 in flames fueled…”
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12
Combustion Chemistry of Enols: Possible Ethenol Precursors in Flames
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (09-03-2006)“…Before the recent discovery that enols are intermediates in many flames, they appeared in no combustion models. Furthermore, little is known about enols' flame…”
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Photoionization mass spectrometric studies and modeling of fuel-rich allene and propyne flames
Published in Proceedings of the Combustion Institute (2007)“…Flame-sampling photoionization mass spectrometry is used for measurements of the absolute molar composition of fuel-rich ( ϕ = 1.8) low-pressure laminar flames…”
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14
Kinetic model for the decomposition of DMMP in a hydrogen/oxygen flame
Published in Combustion and flame (01-04-1999)“…A kinetic model of the combustion chemistry of a hydrogen/oxygen base flame, doped with dimethyl methylphosphonate, a useful simulant for chemical warfare…”
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A laser and molecular beam mass spectrometer study of low-pressure dimethyl ether flames
Published in Proceedings of the Combustion Institute (2000)“…The oxidation of dimethyl ether (DME) was studied in low-pressure, premixed flames using a new molecular beam mass spectrometer (MBMS) and laser diagnosties…”
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Absolute photoionization cross-sections of some combustion intermediates
Published in International journal of mass spectrometry (2012)“…[Display omitted] ► Absolute photoionization cross-sections for 30 combustion intermediates. ► Updated accurate cross-sections for allene. ► First measurement…”
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The kinetics of the combustion of trichloroethylene for low Cl/H ratios
Published in Combustion and flame (2000)“…A kinetic model has been developed for the combustion of trichloroethylene (TCE) under low Cl/H ratio conditions. Flame species concentration profiles,…”
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Near-threshold absolute photoionization cross-sections of some reaction intermediates in combustion
Published in International journal of mass spectrometry (01-02-2008)“…The use of photoionization mass spectrometry for the development of quantitative kinetic models for the complex combustion chemistry of both conventional…”
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Absolute cross-sections for dissociative photoionization of some small esters
Published in International journal of mass spectrometry (01-05-2010)“…The first measurements of absolute cross-sections for near-threshold molecular and dissociative photoionization are presented for 11 small esters (methyl…”
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Photoionization cross sections for reaction intermediates in hydrocarbon combustion
Published in International journal of mass spectrometry (01-12-2005)“…Previously unmeasured absolute photoionization cross sections are presented for eight common reaction intermediates found in the combustion of many simple…”
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