Search Results - "Cook, Amanda K"
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Mechanism of the Palladium-Catalyzed Arene C–H Acetoxylation: A Comparison of Catalysts and Ligand Effects
Published in Journal of the American Chemical Society (04-03-2015)“…This article describes detailed mechanistic studies focused on elucidating the impact of pyridine ligands on the Pd-catalyzed C–H acetoxylation of benzene…”
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Catalyst-controlled selectivity in the C–H borylation of methane and ethane
Published in Science (American Association for the Advancement of Science) (25-03-2016)“…The C–H bonds of methane are generally more kinetically inert than those of other hydrocarbons, reaction solvents, and methane functionalization products…”
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3
The mechanism of oxidative addition of Pd(0) to Si-H bonds: electronic effects, reaction mechanism, and hydrosilylation
Published in Chemical science (Cambridge) (13-10-2021)“…The oxidative addition of Pd to Si-H bonds is a crucial step in a variety of catalytic applications, and many aspects of this reaction are poorly understood…”
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Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes
Published in Angewandte Chemie International Edition (26-09-2011)“…Less is more: The rational optimization and general applicability of the catalytic system Pd(OAc)2/pyridine is described (see scheme). The catalyst shows…”
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Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes
Published in Organic letters (01-11-2013)“…This report describes the use of an oxidant and a ligand to control site selectivity in the Pd(OAc)2-catalyzed C–H acetoxylation of simple arenes. The use of…”
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The Influence of Silane Steric Bulk on the Formation and Dynamic Behavior of Silyl Palladium Hydrides
Published in Organometallics (25-04-2022)“…Silanes play a versatile role in catalytic transformations, acting as hydride sources, transmetalation reagents, and starting materials in the synthesis of…”
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Alkyne Hydroamination Catalyzed by Silica-Supported Isolated Zn(II) Sites
Published in Organometallics (14-05-2018)“…Hydroamination is an atom-economical reaction to form C–N bonds, which are ubiquitous in organic compounds. Hydroamination has seen prolific advancements and…”
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Three-Electrode Study of Electrochemical Ionomer Degradation Relevant to Anion-Exchange-Membrane Water Electrolyzers
Published in ACS applied materials & interfaces (27-04-2022)“…Among existing water electrolysis (WE) technologies, anion-exchange-membrane water electrolyzers (AEMWEs) show promise for low-cost operation enabled by the…”
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9
Alkene Isomerization Using a Heterogeneous Nickel-Hydride Catalyst
Published in Journal of the American Chemical Society (21-05-2024)“…Transition metal-catalyzed alkene isomerization is an enabling technology used to install an alkene distal to its original site. Due to their well-defined…”
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10
Modular Ni(0)/Silane Catalytic System for the Isomerization of Alkenes
Published in Organometallics (28-02-2022)“…Alkenes are used ubiquitously as starting materials and synthetic targets in all areas of chemistry. Controlling their geometry and position along a chain is…”
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Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K2S2O8
Published in ACS catalysis (05-04-2013)“…This manuscript describes the development of Pd catalysts with pyridinium-substituted pyridine ligands for the C–H oxygenation of benzene with potassium…”
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12
Understanding the Lewis Acidity of Co(II) Sites on a Silica Surface
Published in Inorganic chemistry (17-07-2017)“…Heterogeneous catalysts consisting of isolated transition-metal sites dispersed on the surface of metal oxide supports are commonly used in the chemical…”
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Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes
Published in Angewandte Chemie (26-09-2011)“…Die gezielte Optimierung und generelle Anwendbarkeit des Katalysatorsystems Pd(OAc)2/Pyridin werden vorgestellt. Das System ist hoch aktiv in der…”
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Oxygen Evolution Electrocatalysis in Acids: Atomic Tuning of the Stability Number for Submonolayer IrO x on Conductive Oxides from Molecular Precursors
Published in ACS catalysis (20-01-2023)“…Proton-exchange-membrane water electrolyzers (PEMWEs) produce high-purity H2, withstand load fluctuations, and operate with a pure-water feed but require…”
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15
(NHC)Ni(0)-Catalyzed Branched-Selective Alkene Hydrosilylation with Secondary and Tertiary Silanes
Published in ACS catalysis (16-09-2022)“…Hydrosilylation is a valuable approach for the construction of organosilanes, which are precursors to silicone materials that are widely incorporated in our…”
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Three-Electrode Study of Electrochemical Ionomer Degradation Relevant to Anion-Exchange-Membrane Water Electrolyzers
Published in ACS applied materials & interfaces (18-04-2022)“…Among existing water electrolysis (WE) technologies, anion-exchange-membrane water electrolyzers (AEMWEs) show promise for low-cost operation enabled by the…”
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17
Palladium Catalysts Containing Pyridinium-Substituted Pyridine Ligands for the C–H Oxygenation of Benzene with K 2 S 2 O 8
Published in ACS catalysis (05-04-2013)Get full text
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Back Cover: Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes (Angew. Chem. Int. Ed. 40/2011)
Published in Angewandte Chemie International Edition (26-09-2011)“…Palladium/pyridine catalyst systems for efficient, nondirected CH oxygenation of simple arenes are described by M. S. Sanford and co‐workers in their…”
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Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes
Published in Angewandte Chemie International Edition (26-09-2011)Get full text
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20
Rucktitelbild: Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes (Angew. Chem. 40/2011)
Published in Angewandte Chemie (26-09-2011)Get full text
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