Search Results - "Connick, William B."
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Tuning two-electron transfer in terpyridine-based platinum() pincer complexes
Published in RSC advances (05-07-2019)“…An important factor in obtaining reversible multi-electron transfer is overcoming large changes in coordination geometry. One strategy is to use ligands that…”
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Enhancing Vapochromic Properties of Platinum(II) Terpyridine Chloride Hexaflouro Phosphate in Terms of Sensitivity through Nanocrystalization for Fluorometric Detection of Acetonitrile Vapors
Published in Crystals (Basel) (01-04-2024)“…The vapochromic properties of [Pt(tpy)Cl](PF6) crystals in the presence of acetonitrile and its effect on the crystal structure as well as the fluorescence…”
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Synthesis, Luminescence, and Structure of a Polymorphic Polyfluorinated Diiodoplatinum(II) Diimine Complex
Published in Inorganic chemistry (19-08-2019)“…PtI2(5,5′-bis(HCF2CH2OCH2)-2,2′-bpy)], 55-2FH-PtI 2 , is the first example of a substituted fluorinated diiodoplatinum diimine complex that exhibits…”
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Structure of a Crystalline Vapochromic Platinum(II) Salt
Published in Inorganic chemistry (03-03-2008)“…Square-planar cations of the orange form of [Pt(Me2bzimpy)Cl](PF6)·DMF [Me2bzimpy = 2,6-bis(N-methylbenzimidazol-2-yl)pyridine] stack along the b axis in a…”
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A New Class of Platinum(II) Vapochromic Salts
Published in Journal of the American Chemical Society (18-02-2004)“…Luminescent chloride and hexaflurophosphate salts of Pt(Me2bzimpy)Cl+ (Me2bzimpy = 2,6-bis(1-methylbenzimidazol-2-yl)pyridine) are reported. As solids, both…”
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Solid-state materials for anion sensing in aqueous solution: highly selective colorimetric and luminescence-based detection of perchlorate using a platinum(II) salt
Published in Chemical communications (Cambridge, England) (01-01-2010)“…The PF(6)(-) salt of a platinum(II) complex changes from yellow to red and becomes intensely luminescent upon exposure to aqueous ClO(4)(-). The response is…”
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Radio-Fluorogenic Gel Dosimetry with Coumarin
Published in Bioengineering (Basel) (10-07-2018)“…Gel dosimeters are attractive detectors for radiation therapy, with properties similar to biological tissue and the potential to visualize volumetric dose…”
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Measuring the photon depth dose distribution produced by a medical linear accelerator in a water-equivalent radio-fluorogenic gel
Published in Journal of radioanalytical and nuclear chemistry (01-03-2016)“…The present work describes use of a water-equivalent radio-fluorogenic gel dosimeter for measurement of a depth dose distribution from a medical linear…”
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Excited-State Self-Quenching Reactions of Square Planar Platinum(II) Diimine Complexes in Room-Temperature Fluid Solution
Published in Inorganic chemistry (12-07-1999)Get full text
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Photooxidation of Platinum(II) Diimine Dithiolates
Published in Journal of the American Chemical Society (03-12-1997)“…The violet color of Pt(bpy)(bdt) (bpy = 2,2‘-bipyridine; bdt = 1,2-benzenedithiolate) is due to a Pt/S → diimine charge-transfer transition; the emission…”
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Halide exchange studies of novel Pd() NNN-pincer complexes
Published in RSC advances (15-08-2019)“…Palladium( ii ) complexes with an NNN type pincer ligand (pip 2 NNN = 2,6-bis(piperdyl-methyl)pyridine) are synthesized and characterized. Electronic and 1 H…”
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Linear-Chain Structures of Platinum(II) Diimine Complexes
Published in Inorganic chemistry (26-02-1997)“…The structures of three linear-chain platinum(II) diimine complexes have been determined [Pt···Pt, Å]: Pt(bpm)Cl2·0.5(nmp) (3) [3.411(1), 3.371(1)],…”
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Emission Spectroscopic Properties of the Red Form of Dichloro(2,2‘-bipyridine)platinum(II). Role of Intermolecular Stacking Interactions
Published in Inorganic chemistry (09-10-1996)“…The structure of the red form of Pt(bpy)Cl2 (bpy = 2,2‘-bipyridine) has been studied by variable-temperature X-ray crystallography. The stack of square-planar…”
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An Outer-Sphere Two-Electron Platinum Reagent
Published in Journal of the American Chemical Society (26-03-2003)“…A strategy for designing cooperative outer-sphere two-electron platinum reagents is demonstrated. The novel platinum(II) complex, [Pt(tpy)(pip2NCN)][BF4]…”
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A colorimetric/luminescence sensor for detecting MeCN in water: Towards direct detection of dissolved organic contaminants
Published in Sensors and actuators. B, Chemical (15-02-2021)“…Highlights •Molecular recognition of organic contaminants in water by a linear Pt(II) complex.•Highly targeted luminescence and colorimetric response of the…”
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pH-Mediated Colorimetric and Luminescent Sensing of Aqueous Nitrate Anions by a Platinum(II) Luminophore@Mesoporous Silica Composite
Published in ACS applied materials & interfaces (14-04-2021)“…Increased levels of nitrate (NO3 –) in the environment can be detrimental to human health. Herein, we report a robust, cost-effective, and scalable, hybrid…”
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Water’s Role in Polymorphic Platinum(II) Complexes
Published in Inorganic chemistry (04-10-2021)“…Solvent plays a vital role in the recrystallization process and resulting crystallinity of materials. This role is of such importance that it can control the…”
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Platinum(II) Monomer and Dimer Complexes with a Bis(oxazolinyl)phenyl Pincer Ligand
Published in Inorganic chemistry (08-09-2015)“…A series of platinum(II) complexes with the formulas Pt(phebox)(L)+ (phebox– = 1,3-bis(4,4′-dimethyl-2′-oxazolinyl)phenyl anion; L = pyridine (py),…”
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Vapoluminescence hysteresis in a platinum(II) salt-based humidity sensor: Mapping the vapochromic response to water vapor
Published in Sensors and actuators. B, Chemical (15-05-2022)“…In an effort to address the scarcity of chemical sensors that can record precise, reproducible, and sensitive changes in humidity, this work reports a…”
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