Search Results - "Colussi, Agustin J."
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Sonochemical Decomposition of Phenol: Evidence for a Synergistic Effect of Ozone and Ultrasound for the Elimination of Total Organic Carbon from Water
Published in Environmental science & technology (01-11-2006)“…Advanced oxidation processes (AOPs) for water and wastewater treatment are often handicapped by their inability to completely eliminate total organic carbon…”
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Role of Nitrogen Dioxide in the Production of Sulfate during Chinese Haze-Aerosol Episodes
Published in Environmental science & technology (06-03-2018)“…Haze events in China megacities involve the rapid oxidation of SO2 to sulfate aerosol. Given the weak photochemistry that takes place in these optically thick…”
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3
Fenton chemistry at aqueous interfaces
Published in Proceedings of the National Academy of Sciences - PNAS (14-01-2014)“…In a fundamental process throughout nature, reduced iron unleashes the oxidative power of hydrogen peroxide into reactive intermediates. However,…”
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4
HONO emissions from snow surfaces
Published in Environmental research letters (01-10-2008)“…Photochemical production of NOx and HONO from surface snow can significantly impact the NOx, OH, and O3 budgets in the overlying atmosphere. NOx production is…”
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5
Mechanism of Hydrogen Peroxide Formation on Sprayed Water Microdroplets
Published in Journal of the American Chemical Society (02-08-2023)“…How is H2O2 formed in sprayed water is not well understood. It is believed to involve the association of HO• radicals spontaneously generated from HO– ions by…”
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Enhanced Acidity of Acetic and Pyruvic Acids on the Surface of Water
Published in Langmuir (07-08-2018)“…Understanding the acid–base behavior of carboxylic acids on aqueous interfaces is a fundamental issue in nature. Surface processes involving carboxylic acids…”
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Stability of Monoterpene-Derived α‑Hydroxyalkyl-Hydroperoxides in Aqueous Organic Media: Relevance to the Fate of Hydroperoxides in Aerosol Particle Phases
Published in Environmental science & technology (07-04-2020)“…The α-hydroxyalkyl-hydroperoxides [R–(H)C(−OH)(−OOH), α-HH] produced in the ozonolysis of unsaturated organic compounds may contribute to secondary organic…”
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Artificial Photosynthesis of C1–C3 Hydrocarbons from Water and CO2 on Titanate Nanotubes Decorated with Nanoparticle Elemental Copper and CdS Quantum Dots
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (14-05-2015)“…The conversion of CO2 and water into value-added fuels with visible light is difficult to achieve in inorganic photocatalytic systems. However, we synthesized…”
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Water Dramatically Accelerates the Decomposition of α‑Hydroxyalkyl-Hydroperoxides in Aerosol Particles
Published in The journal of physical chemistry letters (03-10-2019)“…α-Hydroxyalkyl-hydroperoxides (α-HHs), from the addition of water to Criegee intermediates in the ozonolysis of olefins, are reactive components of organic…”
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10
Can the pH at the air/water interface be different from the pH of bulk water?
Published in Proceedings of the National Academy of Sciences - PNAS (21-08-2018)Get full text
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Comment on “Liquid–Gas Interface of Iron Aqueous Solutions and Fenton Reagents”
Published in The journal of physical chemistry letters (28-07-2022)“…A recent Letter in this Journal (Gladich et al. J. Phys. Chem. Lett. 13, 2994–3001) reported that photoelectron spectroscopy could not detect any products on…”
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Dynamics of Lithium Dendrite Growth and Inhibition: Pulse Charging Experiments and Monte Carlo Calculations
Published in The journal of physical chemistry letters (15-05-2014)“…Short-circuiting via dendrites compromises the reliability of Li-metal batteries. Dendrites ensue from instabilities inherent to electrodeposition that should…”
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13
Reactivity of Monoterpene Criegee Intermediates at Gas–Liquid Interfaces
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (04-10-2018)“…Biogenic monoterpenes are major sources of Criegee intermediates (CIs) in the troposphere. Recent studies underscored the importance of their heterogeneous…”
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14
Role of Ferryl Ion Intermediates in Fast Fenton Chemistry on Aqueous Microdroplets
Published in Environmental science & technology (02-11-2021)“…In the aqueous environment, FeII ions enhance the oxidative potential of ozone and hydrogen peroxide by generating the reactive oxoiron species (ferryl ion,…”
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15
Cooperative Hydration of Pyruvic Acid in Ice
Published in Journal of the American Chemical Society (16-08-2006)“…About 3.5 ± 0.3 water molecules are still involved in the exothermic hydration of 2-oxopropanoic acid (PA) into its monohydrate (2,2-dihydroxypropanoic acid,…”
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Protonation and Oligomerization of Gaseous Isoprene on Mildly Acidic Surfaces: Implications for Atmospheric Chemistry
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (21-06-2012)“…In a global process linking the Earth’s climate with its ecosystems, massive photosynthetic isoprene (ISOP) emissions are converted to light-scattering haze…”
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Vacuum-assisted headspace single-drop microextraction: Eliminating interfacial gas-phase limitations
Published in Analytica chimica acta (27-12-2019)“…Gas-phase limitations have been neglected in headspace single-drop microextraction (HS-SDME) and rate control has been assumed to primarily reside in the…”
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18
Brønsted basicity of the air–water interface
Published in Proceedings of the National Academy of Sciences - PNAS (13-11-2012)“…Differences in the extent of protonation of functional groups lying on either side of water–hydrophobe interfaces are deemed essential to enzymatic catalysis,…”
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In Situ Mass Spectrometric Detection of Interfacial Intermediates in the Oxidation of RCOOH(aq) by Gas-Phase OH-Radicals
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (12-06-2014)“…Products and intermediates of the oxidation of aqueous alkanoic acids initiated by gas-phase hydroxyl radicals, ·OH(g), at the air–water interface were…”
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Stepwise Oxidation of Aqueous Dicarboxylic Acids by Gas-Phase OH Radicals
Published in The journal of physical chemistry letters (05-02-2015)“…A leading source of uncertainty in predicting the climate and health effects of secondary organic aerosol (SOA) is how its composition changes over their…”
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