Search Results - "Colby, Ralph H."
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Structure and linear viscoelasticity of flexible polymer solutions: comparison of polyelectrolyte and neutral polymer solutions
Published in Rheologica acta (01-05-2010)“…The current state of understanding for solution conformations of flexible polymers and their linear viscoelastic response is reviewed. Correlation length, tube…”
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2
Rheology of Entangled Polyelectrolyte Solutions
Published in Macromolecules (09-02-2021)“…Polyelectrolyte solution dynamics have been carefully studied experimentally and theoretically for unentangled solutions and thought to be reasonably well…”
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Journal Article -
3
Glass transition temperature from the chemical structure of conjugated polymers
Published in Nature communications (14-02-2020)“…The glass transition temperature ( T g ) is a key property that dictates the applicability of conjugated polymers. The T g demarks the transition into a…”
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Journal Article -
4
Viscoelasticity of Reversible Gelation for Ionomers
Published in Macromolecules (24-02-2015)“…Linear viscoelasticity (LVE) of low-ion-content and low-molecular-weight (nonentangled) randomly sulfonated polystyrene shows a sol–gel transition when the…”
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Journal Article -
5
Electrostatic and Hydrophobic Interactions in NaCMC Aqueous Solutions: Effect of Degree of Substitution
Published in Macromolecules (24-04-2018)“…The rheology of water-soluble polyelectrolytes at intermediate and high concentrations is controlled by entanglement, hydrophobic, and electrostatic…”
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Journal Article -
6
Viscosity and Scaling of Semiflexible Polyelectrolyte NaCMC in Aqueous Salt Solutions
Published in Macromolecules (10-01-2017)“…We investigate the viscosity dependence on concentration and molecular weight of semiflexible polyelectrolyte sodium carboxymethylcellulose (NaCMC) in aqueous…”
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Journal Article -
7
Network dynamics in nanofilled polymers
Published in Nature communications (25-04-2016)“…It is well accepted that adding nanoparticles (NPs) to polymer melts can result in significant property improvements. Here we focus on the causes of mechanical…”
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Journal Article -
8
Hierarchical Sticker and Sticky Chain Dynamics in Self-Healing Butyl Rubber Ionomers
Published in Macromolecules (11-06-2019)“…We present a detailed comparison of the microscopic dynamics and the macroscopic mechanical behavior of novel butyl rubber ionomers with tunable dynamics of…”
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Journal Article -
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Mechanical Reinforcement of Polymer Nanocomposites from Percolation of a Nanoparticle Network
Published in ACS macro letters (21-04-2015)“…Nanometer-sized particles that are well dispersed in a polymer melt, presumably due to strongly favorable particle–polymer interactions, can form fractal…”
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Journal Article -
10
Onset of Flow-Induced Crystallization Kinetics of Highly Isotactic Polypropylene
Published in Macromolecules (09-06-2015)“…Brief intervals of shear prior to a temperature quench accelerate crystallization, resulting in much smaller spherulites. Crystallization kinetics of five…”
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Journal Article -
11
Lifetime of Flow-Induced Precursors in Isotactic Polypropylene
Published in Macromolecules (13-10-2015)“…Brief intervals of strong flow stretch chains in a semicrystalline polymer melt to form flow-induced precursors, which accelerate crystallization kinetics and…”
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Journal Article -
12
Structure of sodium carboxymethyl cellulose aqueous solutions: A SANS and rheology study
Published in Journal of polymer science. Part B, Polymer physics (01-04-2015)“…We report a small angle neutron scattering (SANS) and rheology study of cellulose derivative polyelectrolyte sodium carboxymethyl cellulose with a degree of…”
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Journal Article -
13
Glass Transition Temperature of Conjugated Polymers by Oscillatory Shear Rheometry
Published in Macromolecules (11-07-2017)“…The stiff backbones of conjugated polymers can lead to a rich phase behavior that includes both crystalline and liquid crystalline phases, making measurements…”
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Journal Article -
14
Synthesis and Lithium Ion Conduction of Polysiloxane Single-Ion Conductors Containing Novel Weak-Binding Borates
Published in Chemistry of materials (26-06-2012)“…Three borate monomers: lithium triphenylstyryl borate (B1), a variant with three ethylene oxides between the vinyl and the borate (B2) and a third with…”
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Journal Article -
15
Segmental Dynamics and Dielectric Constant of Polysiloxane Polar Copolymers as Plasticizers for Polymer Electrolytes
Published in ACS applied materials & interfaces (10-02-2016)“…Dielectric relaxation spectroscopy was used to investigate the segmental dynamics of a series of siloxane-based polar copolymers combining pendant cyclic…”
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16
Anisotropic self-assembly of spherical polymer-grafted nanoparticles
Published in Nature materials (01-04-2009)“…It is easy to understand the self-assembly of particles with anisotropic shapes or interactions (for example, cobalt nanoparticles or proteins) into highly…”
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Journal Article -
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Solvent-non-solvent rapid-injection for preparing nanostructured materials from micelles to hydrogels
Published in Nature communications (26-08-2019)“…Due to their distinctive molecular architecture, ABA triblock copolymers will undergo specific self-assembly processes into various nanostructures upon…”
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Journal Article -
18
Dual Nakamura model for primary and secondary crystallization applied to nonisothermal crystallization of poly(ether ether ketone)
Published in Polymer engineering and science (01-10-2021)“…Non‐isothermal crystallization kinetics has been traditionally predicted using the Nakamura crystal growth model, which is an integral form of the Avrami…”
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Journal Article -
19
Molecular Mobility, Ion Mobility, and Mobile Ion Concentration in Poly(ethylene oxide)-Based Polyurethane Ionomers
Published in Macromolecules (12-08-2008)“…The segmental and local chain dynamics as well as the transport of Na+ and Li+ cations in a series of model poly(ethylene oxide)-based polyurethane ionomers is…”
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Journal Article -
20
Transition in Crystal Morphology for Flow-Induced Crystallization of Isotactic Polypropylene
Published in Macromolecules (09-08-2016)“…Deformation applied to a semicrystalline polymer melt prior to quenching can dramatically increase the concentration of nuclei and even transform the final…”
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