Hydrothermal synthesis of B, S, and N-doped carbon quantum dots for colorimetric sensing of heavy metal ions

In this study, glucose was used as the carbon source to synthesize carbon quantum dots (CQDs) and also aimed to synthesize CQDs doped with heteroatoms such as sulphur, nitrogen, and boron to enhance their functionality. The obtained material has been characterized by several techniques. According to...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances Vol. 14; no. 16; pp. 1814 - 1825
Main Authors: Aygun, Aysenur, Cobas, Ipek, Tiri, Rima Nour Elhouda, Sen, Fatih
Format: Journal Article
Language:English
Published: England Royal Society of Chemistry 03-04-2024
The Royal Society of Chemistry
Subjects:
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:In this study, glucose was used as the carbon source to synthesize carbon quantum dots (CQDs) and also aimed to synthesize CQDs doped with heteroatoms such as sulphur, nitrogen, and boron to enhance their functionality. The obtained material has been characterized by several techniques. According to FL analysis, the highest peaks for CQD, N-CQD, B-CQD, and S-CQD were determined as 432 nm (ex 350), 425 (ex 350), 430 nm (ex 340 nm), and 436 nm (ex 340 nm), respectively. FTIR spectra showed different characteristic peaks for CQD, and the FTIR results show that CQDs have a unique structure. According to TEM analysis, the morphology of all CQDs was found to be spherical and monodisperse with average sizes in the range of 5-7 nm. The characterization results of CQDs show that the addition of heteroatoms changes the properties of CQDs. The synthesized CQDs were also tested as colorimetric sensors for the detection of heavy metals. It was observed that CQDs detected Fe 3+ metal ions, B-CQD and S-CQD detected Fe 3+ and Ag + metal ions, and N-CQDs detected Ca 2+ metal ions. Sensor studies were performed for all CQDs and linear plots were obtained against metal concentrations in the range of 0.06-1.23 μM. LOD values for CQD, N-CQD, S-CQD, and B-CQD were calculated as 0.187 μM (Fe 3+ ), 0.391 μM (Ca 2+ ), 0.224 μM (Fe 3+ )-0.442 μM (Ag + ), and 0.182 μM (Fe 3+ )-0.174 μM (Ag + ), respectively. The results show that the addition of B, N, and S atoms to CQDs plays a role in the improvement and modification of colorimetric sensor properties and has the potential to be used in sensor applications for the detection of heavy metals in areas such as the environment and health. CQDs were synthesized using glucose as the C source, and N-CQDs, B-CQDs, and S-CQDs were synthesized by doping with N, B, and S atoms. The colorimetric sensor properties of the synthesized CQDs for the detection of heavy metals were examined.
Bibliography:https://doi.org/10.1039/d4ra00397g
Electronic supplementary information (ESI) available. See DOI
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:2046-2069
2046-2069
DOI:10.1039/d4ra00397g