Search Results - "Clyburne, Jason A C"
-
1
Higher-Order Zincates as Transmetalators in Alkyl-Alkyl Negishi Cross-Coupling
Published in Angewandte Chemie International Edition (09-07-2012)“…Negishi revisited: Higher‐order alkyl zincates have been subjected to Negishi coupling with alkyl bromides. For the first time, coupling takes place in…”
Get full text
Journal Article -
2
NH/PH Isomerization and a Lewis Pair for Carbon Dioxide Capture
Published in Inorganic chemistry (05-08-2013)“…Bis(di-i-propylphosphino)amine 1 reacts with B(C6F5)3 to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide…”
Get full text
Journal Article -
3
Interfacial film formation: Influence on oil spreading rates in lab basin tests and dispersant effectiveness testing in a wave tank
Published in Marine pollution bulletin (15-06-2013)“…•We examined interfacial film formations on seawater from oil and dispersants. The density of Corexit EC9500A is 0.948g/mL.•We evaluated oil spreading rates on…”
Get full text
Journal Article -
4
Simple Ion–Gas Mixtures as a Source of Key Molecules Relevant to Prebiotic Chemistry
Published in Molecules (Basel, Switzerland) (06-12-2021)“…Very simple chemistry can result in the rapid and high-yield production of key prebiotic inorganic molecules. The two reactions investigated here involve such…”
Get full text
Journal Article -
5
Mono‐ and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis‐1,4‐([3]Cumulene)‐p‐carboquinoid System
Published in Angewandte Chemie International Edition (15-01-2018)“…An extended π‐system containing two [3]cumulene fragments separated by a p‐carboquinoid and stabilized by two capping N‐heterocyclic carbenes (NHCs) has been…”
Get full text
Journal Article -
6
Probing the Reactivity of a Stable Silene Using Muonium
Published in Angewandte Chemie (International ed.) (01-01-2008)“…Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1‐CMu and 1‐SiMu,…”
Get full text
Journal Article -
7
Rapid, Reversible, Solid–Gas and Solution-Phase Insertion of CO2 into In–P Bonds
Published in Inorganic chemistry (07-12-2015)“…The P,P-chelated heteroleptic complex bis[bis(diisopropylphosphino)amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with…”
Get full text
Journal Article -
8
Structure of Organic and Metal−Organic Networks Based on a Bifunctional m-Terphenyl Carboxylic Acid
Published in Inorganic chemistry (20-02-2006)“…A series of metal-organic frameworks (MOFs) based upon the ligand 2,6-diphenyl-1,4-dibenzoic acid [Ph2C6H2(CO2H)2]∞ have been prepared and characterized by…”
Get full text
Journal Article -
9
Carbon-Centered Strong Bases in Phosphonium Ionic Liquids
Published in Journal of organic chemistry (01-02-2008)“…Phosphonium ionic liquids (PhosILs), most notably tetradecyl(trihexyl)phosphonium decanoate (PhosIL-C9H19COO), are solvents for bases such as Grignard…”
Get full text
Journal Article -
10
Lactic acid demineralization of green crab (Carcinus maenas) shells: effect of reaction conditions and isolation of an unusual calcium complex
Published in Green chemistry letters and reviews (02-01-2016)“…Chitin and chitosan are potentially useful and environmentally friendly biopolymers with a wide range of value-added applications. Effective and green…”
Get full text
Journal Article -
11
Reaction of Stable N‐Heterocyclic Silylenes and Germylenes with Muonium
Published in Chemistry : a European journal (24-08-2009)“…Very a‐Mu‐sing! Reaction of a germylene with muonium (Mu) yields a germyl radical, in direct analogy to Mu attack at the ylideneic center of the corresponding…”
Get full text
Journal Article -
12
RADMAP: Simple probes for rapid assessment of complex reactivity: A method and case studies on the reaction of hydrogen atoms with unsaturated organic molecules
Published in Journal of molecular graphics & modelling (01-03-2016)“…[Display omitted] •Rapid analysis and visualization of reaction between molecule and a monoatomic probe.•Case studies reported exploring the range of possible…”
Get full text
Journal Article -
13
Detection of a secondary muoniated radical
Published in Physica. B, Condensed matter (15-04-2009)“…Muoniated free radicals are formed by addition of muonium to unsaturated molecules. Successful detection by transverse-field muon spin rotation (μSR) usually…”
Get full text
Journal Article Conference Proceeding -
14
Synthesis and solid state structures of 1,3-dihalo-1,3- bis (dialkylamino)propenium salts and related compounds
Published in Canadian journal of chemistry (01-12-2023)“…1,3-dicholoro-1,3- bis(dialkylamino)propenium salts are prepared by condensing N, N,-dialkylamides with dichloromethylene dimethyliminium chloride (“Viehe's…”
Get full text
Journal Article -
15
Mono‐ and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis‐1,4‐([3]Cumulene)‐p‐carboquinoid System
Published in Angewandte Chemie (15-01-2018)“…An extended π‐system containing two [3]cumulene fragments separated by a p‐carboquinoid and stabilized by two capping N‐heterocyclic carbenes (NHCs) has been…”
Get full text
Journal Article -
16
The Reactions of Imidazol-2-ylidenes with the Hydrogen Atom: A Theoretical Study and Experimental Confirmation with Muonium
Published in Journal of the American Chemical Society (24-09-2003)“…The possible radicals resulting from hydrogen atom addition to the imidazole rings of 1,3-bis(isopropyl)-4,5-dimethylimidazol-2-ylidene (1) and…”
Get full text
Journal Article -
17
An oil spill decision matrix in response to surface spills of various bitumen blends
Published in Environmental science--processes & impacts (19-07-2017)“…Canada's production, transport, and sale of diluted bitumen (dilbit) products are expected to increase by a million barrels per day over the next decade. The…”
Get more information
Journal Article -
18
A Three-Step Laboratory Sequence To Prepare a Carbene Complex of Silver(I) Chloride
Published in Journal of chemical education (01-03-2008)“…We have developed a multistep inorganic synthesis experiment for our second-year undergraduate teaching laboratory that introduces students to modern…”
Get full text
Journal Article -
19
Heavy Metals Make a Chain: A Catenated Bismuth Compound
Published in Chemistry : a European journal (18-06-2020)“…Catenation is common for the light main‐group elements whereas it is rare for the heavy elements. Herein, we report the first example of a neutral molecule…”
Get full text
Journal Article -
20
A Zinc Carboxylate Network Containing Metal Sites with Low Coordination Numbers
Published in Inorganic chemistry (21-02-2005)“…A bifunctional m-terphenyl, 2,6-diphenyl-1,4-dibenzoic acid (Ph2BDC), was synthesized and used in the preparation of a 2-D metal−organic coordination polymer…”
Get full text
Journal Article