Search Results - "Clyburne, Jason A. C."

Higher-Order Zincates as Transmetalators in Alkyl-Alkyl Negishi Cross-Coupling by McCann, Lucas C., Hunter, Howard N., Clyburne, Jason A. C., Organ, Michael G.

“…Negishi revisited: Higher‐order alkyl zincates have been subjected to Negishi coupling with alkyl bromides. For the first time, coupling takes place in…”
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NH/PH Isomerization and a Lewis Pair for Carbon Dioxide Capture by Barry, Brian M, Dickie, Diane A, Murphy, Luke J, Clyburne, Jason A. C, Kemp, Richard A

“…Bis(di-i-propylphosphino)amine 1 reacts with B(C6F5)3 to form an adduct with concomitant N/P H-isomerization. This species reacts smoothly with carbon dioxide…”
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Interfacial film formation: Influence on oil spreading rates in lab basin tests and dispersant effectiveness testing in a wave tank by King, Thomas L., Clyburne, Jason A.C., Lee, Kenneth, Robinson, Brian J.

“…•We examined interfacial film formations on seawater from oil and dispersants. The density of Corexit EC9500A is 0.948g/mL.•We evaluated oil spreading rates on…”
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Simple Ion–Gas Mixtures as a Source of Key Molecules Relevant to Prebiotic Chemistry by Paula, Samuel, Goulding, Liam S., Robertson, Katherine N., Clyburne, Jason A. C.

“…Very simple chemistry can result in the rapid and high-yield production of key prebiotic inorganic molecules. The two reactions investigated here involve such…”
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Mono‐ and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis‐1,4‐([3]Cumulene)‐p‐carboquinoid System by Barry, Brian M., Soper, R. Graeme, Hurmalainen, Juha, Mansikkamäki, Akseli, Robertson, Katherine N., McClennan, William L., Veinot, Alex J., Roemmele, Tracey L., Werner‐Zwanziger, Ulrike, Boeré, René T., Tuononen, Heikki M., Clyburne, Jason A. C., Masuda, Jason D.

“…An extended π‐system containing two [3]cumulene fragments separated by a p‐carboquinoid and stabilized by two capping N‐heterocyclic carbenes (NHCs) has been…”
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Probing the Reactivity of a Stable Silene Using Muonium by McCollum, Brett M, Abe, Takashi, Brodovitch, Jean-Claude, Clyburne, Jason A.C, Iwamoto, Takeaki, Kira, Mitsuo, Percival, Paul W, West, Robert

“…Taking the silenic route: Addition of a hydrogen atom analogue, muonium (Mu), to stable silene 1 gives rise to two distinct radical species, 1‐CMu and 1‐SiMu,…”
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Rapid, Reversible, Solid–Gas and Solution-Phase Insertion of CO2 into In–P Bonds by Dickie, Diane A, Barker, Madeline T, Land, Michael A, Hughes, Kira E, Clyburne, Jason A. C, Kemp, Richard A

“…The P,P-chelated heteroleptic complex bis­[bis­(diisopropylphosphino)­amido]indium chloride [(i-Pr2P)2N]2InCl was prepared in high yield by treating InCl3 with…”
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Structure of Organic and Metal−Organic Networks Based on a Bifunctional m-Terphenyl Carboxylic Acid by Dickie, Diane A, Schatte, Gabriele, Jennings, Michael C, Jenkins, Hilary A, Khoo, Sarah Y. L, Clyburne, Jason A. C

“…A series of metal-organic frameworks (MOFs) based upon the ligand 2,6-diphenyl-1,4-dibenzoic acid [Ph2C6H2(CO2H)2]∞ have been prepared and characterized by…”
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Carbon-Centered Strong Bases in Phosphonium Ionic Liquids by Ramnial, Taramatee, Taylor, Stephanie A, Bender, Marissa L, Gorodetsky, Brian, Lee, Peter T. K, Dickie, Diane A, McCollum, Brett M, Pye, Cory C, Walsby, Charles J, Clyburne, Jason A. C

“…Phosphonium ionic liquids (PhosILs), most notably tetradecyl(trihexyl)phosphonium decanoate (PhosIL-C9H19COO), are solvents for bases such as Grignard…”
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Lactic acid demineralization of green crab (Carcinus maenas) shells: effect of reaction conditions and isolation of an unusual calcium complex by Greene, Bradley H. C., Robertson, Katherine N., Young, John C. O'C., Clyburne, Jason A. C.

“…Chitin and chitosan are potentially useful and environmentally friendly biopolymers with a wide range of value-added applications. Effective and green…”
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Reaction of Stable N‐Heterocyclic Silylenes and Germylenes with Muonium by McCollum, Brett M., Brodovitch, Jean‐Claude, Clyburne, Jason A. C., Mitra, Amitabha, Percival, Paul W., Tomasik, Adam, West, Robert

“…Very a‐Mu‐sing! Reaction of a germylene with muonium (Mu) yields a germyl radical, in direct analogy to Mu attack at the ylideneic center of the corresponding…”
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RADMAP: Simple probes for rapid assessment of complex reactivity: A method and case studies on the reaction of hydrogen atoms with unsaturated organic molecules by Long, Andrew K., Fawcett, Jason A., Clyburne, Jason A.C., Pye, Cory C.

“…[Display omitted] •Rapid analysis and visualization of reaction between molecule and a monoatomic probe.•Case studies reported exploring the range of possible…”
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Detection of a secondary muoniated radical by McCollum, Brett M., Brodovitch, Jean-Claude, Clyburne, Jason A.C., Percival, Paul W., West, Robert

“…Muoniated free radicals are formed by addition of muonium to unsaturated molecules. Successful detection by transverse-field muon spin rotation (μSR) usually…”
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Synthesis and solid state structures of 1,3-dihalo-1,3- bis (dialkylamino)propenium salts and related compounds by Land, Michael A., Turrie, Katrina D., Robertson, Katherine N., Clyburne, Jason A. C.

“…1,3-dicholoro-1,3- bis(dialkylamino)propenium salts are prepared by condensing N, N,-dialkylamides with dichloromethylene dimethyliminium chloride (“Viehe's…”
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Mono‐ and Bis(imidazolidinium ethynyl) Cations and Reduction of the Latter To Give an Extended Bis‐1,4‐([3]Cumulene)‐p‐carboquinoid System by Barry, Brian M., Soper, R. Graeme, Hurmalainen, Juha, Mansikkamäki, Akseli, Robertson, Katherine N., McClennan, William L., Veinot, Alex J., Roemmele, Tracey L., Werner‐Zwanziger, Ulrike, Boeré, René T., Tuononen, Heikki M., Clyburne, Jason A. C., Masuda, Jason D.

“…An extended π‐system containing two [3]cumulene fragments separated by a p‐carboquinoid and stabilized by two capping N‐heterocyclic carbenes (NHCs) has been…”
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The Reactions of Imidazol-2-ylidenes with the Hydrogen Atom:  A Theoretical Study and Experimental Confirmation with Muonium by McKenzie, Iain, Brodovitch, Jean-Claude, Percival, Paul W, Ramnial, Taramatee, Clyburne, Jason A. C

“…The possible radicals resulting from hydrogen atom addition to the imidazole rings of 1,3-bis(isopropyl)-4,5-dimethylimidazol-2-ylidene (1) and…”
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An oil spill decision matrix in response to surface spills of various bitumen blends by King, Thomas L, Robinson, Brian, Cui, Fangda, Boufadel, Michel, Lee, Kenneth, Clyburne, Jason A C

“…Canada's production, transport, and sale of diluted bitumen (dilbit) products are expected to increase by a million barrels per day over the next decade. The…”
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A Three-Step Laboratory Sequence To Prepare a Carbene Complex of Silver(I) Chloride by Canal, John P, Ramnial, Taramatee, Langlois, Lisa D, Abernethy, Colin D, Clyburne, Jason A. C

“…We have developed a multistep inorganic synthesis experiment for our second-year undergraduate teaching laboratory that introduces students to modern…”
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Heavy Metals Make a Chain: A Catenated Bismuth Compound by Riley, Robert D., Dickie, Diane A., Land, Michael A., Kemp, Richard A., Macdonald, Charles L. B., Werner‐Zwanziger, Ulrike, Robertson, Katherine N., Clyburne, Jason A. C.

“…Catenation is common for the light main‐group elements whereas it is rare for the heavy elements. Herein, we report the first example of a neutral molecule…”
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A Zinc Carboxylate Network Containing Metal Sites with Low Coordination Numbers by Dickie, Diane A, Jennings, Michael C, Jenkins, Hilary A, Clyburne, Jason A. C

“…A bifunctional m-terphenyl, 2,6-diphenyl-1,4-dibenzoic acid (Ph2BDC), was synthesized and used in the preparation of a 2-D metal−organic coordination polymer…”
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