Search Results - "Cloitre, Michel"
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A micromechanical model to predict the flow of soft particle glasses
Published in Nature materials (25-09-2011)“…Toothpaste, mayonnaise and other systems are soft particle glasses. In these, the soft particles are jammed so that the glasses behave like weak solids at rest…”
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Microscopic origin of internal stresses in jammed soft particle suspensions
Published in Physical review letters (26-12-2013)“…The long time persistence of mechanical stresses is a generic property of glassy materials. Here we identify the microscopic mechanisms that control internal…”
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Linear Viscoelasticity and Flow of Self-Assembled Vitrimers: The Case of a Polyethylene/Dioxaborolane System
Published in Macromolecules (10-03-2020)“…For vitrimer systems obtained by dynamic cross-linking of polymer chains, incompatibility effects between the cross-links and polymer backbone can lead to…”
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Glassy dynamics and flow properties of soft colloidal pastes
Published in Physical review letters (14-02-2003)“…The local dynamics and the nonlinear rheology of soft colloidal pastes are shown to exhibit a remarkable universal behavior in terms of a unique microscopic…”
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Tunable rheology of dense soft deformable colloids
Published in Current opinion in colloid & interface science (01-12-2014)“…In the last two decades, advances in synthetic, experimental and modeling/simulation methodologies have considerably enhanced our understanding of colloidal…”
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Colloidal Phase Separation of Concentrated PNIPAm Solutions
Published in Langmuir (27-02-2007)“…In the concentration range of 1−6 wt %, solutions of a thermosensitive polymer (poly-N-isopropylacrylamide (PNIPAm), M w = 1.4 × 105 g·mol-1) are shown to…”
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Control of Gelation and Network Properties of Cationically Copolymerized Mono- and Diglycidyl Ethers
Published in Macromolecules (24-07-2018)“…The development of low temperature curing systems has become a major objective in thermoset technologies for both environmental and economic reasons. The use…”
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Phase Behavior and Viscoelastic Properties of Thermoplastic Elastomer Gels Based on ABC Triblock Copolymers
Published in Macromolecules (06-09-2005)“…The structure and the rheological properties of thermoplastic elastomer gels composed of polystyrene-block-polybutadiene-block-poly(methyl methacrylate)…”
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Microscopic Dynamics and Viscoelasticity of Vitrimers
Published in Macromolecules (13-09-2022)“…We implement a hybrid molecular dynamics/Monte Carlo simulation to study the microscopic dynamics and the macroscopic rheology of vitrimers with a fast bond…”
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A review on wall slip in high solid dispersions
Published in Rheologica acta (01-03-2017)“…High solid dispersions are soft materials made of colloidal or non-colloidal particles dispersed at high volume fractions in a liquid matrix. They include hard…”
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Resolving the relaxation complexity of vitrimers: Time-temperature superpositions of a time-temperature non-equivalent system
Published in Polymer (Guilford) (16-04-2024)“…Vitrimers are polymer networks that, thanks to covalent bond exchange, combine desirable properties of thermoplastic and thermosets, such as flowability and…”
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Enriching an Exchangeable Network with One of Its Components: The Key to High‑T g Epoxy Vitrimers with Accelerated Relaxation
Published in Macromolecules (23-08-2022)“…The curing of epoxy-anhydride vitrimers involves anionic copolymerization of epoxide and anhydride along with anionic homopolymerization of excess epoxide,…”
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Colloidal Jamming in Multiarm Star Polymer Melts
Published in Macromolecules (25-06-2019)“…Star polymers with intermediate branching functionalities (64 and 128 arms) are known to exhibit a hybrid viscoelastic response, relaxing stress via a fast…”
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Dual reconfigurable network from a semi-crystalline functional polyolefin
Published in Polymer (Guilford) (26-03-2024)“…A statistical copolymer p(E-co-GMA) of ethylene and glycidyle methacrylate (4.5 wt%) is considered as a starting point towards semicrystalline networks with…”
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Universal Polymeric-to-Colloidal Transition in Melts of Hairy Nanoparticles
Published in ACS nano (26-10-2021)“…Two different classes of hairy self-suspended nanoparticles in the melt state, polymer-grafted nanoparticles (GNPs) and star polymers, are shown to display…”
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Nonmonotonic Stress Relaxation after Cessation of Steady Shear Flow in Supramolecular Assemblies
Published in Physical review letters (22-11-2019)“…Stress relaxation upon cessation of shear flow is known to be described by single-mode or multimode monotonic exponential decays. This is considered to be…”
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Universal Polymeric-to-Colloidal Transition in Melts of Hairy Nanoparticles
Published in ACS nano (08-10-2021)“…Not provided…”
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Order–Disorder Transition in Supramolecular Polymers
Published in Journal of the American Chemical Society (14-12-2011)“…In supramolecular polymers, directional interactions control the constituting units connectivity, but dispersion forces may conspire to make complex…”
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Microscopic origin of internal stresses in jammed soft particles suspensions
Published in Physical review letters (27-12-2013)Get full text
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