Search Results - "Claparède, Laurent"
-
1
Impact of ruthenium metallic particles on the dissolution of UO2 in nitric acid
Published in Npj Materials degradation (03-05-2022)“…UO 2 pellets incorporating 3 mol.% of Ru was prepared by using a wet chemistry route and then characterised. The speciation, morphology, as well as spatial…”
Get full text
Journal Article -
2
Multiparametric Dissolution of Thorium–Cerium Dioxide Solid Solutions
Published in Inorganic chemistry (21-11-2011)“…The dissolution of Th1–x Ce x O2 solid solutions samples prepared by thermal conversion of oxalate precursors was studied by varying independently several…”
Get full text
Journal Article -
3
In Situ HT-ESEM Observation of CeO2 Grain Growth During Sintering
Published in Journal of the American Ceramic Society (01-11-2012)“…The CeO2 sintering and grain growth kinetics were determined from in situ experiments performed using an environmental scanning electron microscope (ESEM)…”
Get full text
Journal Article -
4
Understanding the solid/liquid interface evolution during the dissolution of Nd-doped UO2 by macro-/microscopic dual approach
Published in Corrosion science (01-09-2023)“…The chemical durability of Nd-doped UO2 samples was studied using an innovative macro-/microscopic dual approach method. The starting precursor was first…”
Get full text
Journal Article -
5
Dissolution of Th$_{0.25}$U$_{0.75}$O$_2$ sintered pellets: Impact of nitrate ions and nitrous acid
Published in Hydrometallurgy (01-09-2021)“…In order to gain insights on the kinetics of the dissolution of Gen(IV) MOX fuels, sintered pellets of Th$_{0.25}$U$_{0.75}$O$_2$ were prepared as surrogates…”
Get full text
Journal Article -
6
In situ Raman monitoring of studtite formation under alpha radiolysis in $^{18}$O-labeled water
Published in Journal of nuclear materials (01-11-2024)“…Studtite [(UO$_2$)(O$_2$)(H$_2$O)$_2$]·2(H$_2$O) is a secondary phase precipitating during the alteration of uranium-bearing materials. The mechanistic link…”
Get full text
Journal Article -
7
Dissolution of Th0.25U0.75O2 sintered pellets: Impact of nitrate ions and nitrous acid
Published in Hydrometallurgy (01-09-2021)“…In order to gain insights on the kinetics of the dissolution of Gen(IV) MOX fuels, sintered pellets of Th0.25U0.75O2 were prepared as surrogates. Particularly,…”
Get full text
Journal Article -
8
In situ Raman monitoring of studtite formation under alpha radiolysis in 18O-labeled water
Published in Journal of nuclear materials (01-11-2024)“…•An in situ Raman monitoring of isotopically-labeled studtite growth was performed.•The link between studtite formation mechanism and radiolysis effects was…”
Get full text
Journal Article -
9
Influence of Sintering Conditions on the Structure and Redox Speciation of Homogeneous (U,Ce)O2+δ Ceramics: A Synchrotron Study
Published in Inorganic chemistry (15-05-2023)“…Although uranium–cerium dioxides are frequently used as a surrogate material for (U,Pu)O2−δ nuclear fuels, there is currently no reliable data regarding the…”
Get full text
Journal Article -
10
Impact of the atmosphere on the sintering capability and chemical durability of Nd-doped UO2+x mixed oxides
Published in Journal of the European Ceramic Society (01-01-2025)“…In this study, the influence of the working atmosphere on the sinterability and chemical durability of Nd-doped UO2 mixed oxides was investigated. To this end,…”
Get full text
Journal Article -
11
Kinetics of dissolution of Th0.25U0.75O2 sintered pellets in various acidic conditions
Published in Journal of nuclear materials (01-11-2018)“…In order to gain insights into the kinetics of dissolution of Gen(IV) MOX fuels, sintered pellets of Th0.25U0.75O2 were prepared as surrogates. The study of…”
Get full text
Journal Article -
12
Effect of surface orientation on dissolution rate and surface dynamics of UO2 single crystals in nitric acid
Published in Corrosion science (01-11-2020)“…[Display omitted] •UO2 single crystals with (100), (110) and (111) surfaces were dissolved in 2 M HNO3.•Two successive kinetic regimes were identified during…”
Get full text
Journal Article -
13
Dissolution of Th1−xUxO2: Effects of chemical composition and microstructure
Published in Journal of nuclear materials (01-02-2015)“…Dissolution of Th1−xUxO2 samples in concentrated nitric acid showed that thorium enriched solid solutions follow the same trend than thoria while uranium…”
Get full text
Journal Article -
14
Influence of Sintering Conditions on the Structure and Redox Speciation of Homogeneous (U,Ce)O 2+δ Ceramics: A Synchrotron Study
Published in Inorganic chemistry (15-05-2023)“…Although uranium-cerium dioxides are frequently used as a surrogate material for (U,Pu)O nuclear fuels, there is currently no reliable data regarding the…”
Get full text
Journal Article -
15
Impact of the cationic homogeneity on Th0.5U0.5O2 densification and chemical durability
Published in Journal of nuclear materials (01-02-2019)“…In order to study the effects of cationic homogeneity on the life cycle of Th1-xUxO2 ceramics, including sintering and reprocessing (dissolution) steps, five…”
Get full text
Journal Article -
16
Influence of Crystallization State and Microstructure on the Chemical Durability of Cerium–Neodymium Mixed Oxides
Published in Inorganic chemistry (19-09-2011)“…To underline the potential links between the crystallization state and the microstructure of powdered cerium–neodymium oxides and their chemical durability,…”
Get full text
Journal Article -
17
In Situ HT ‐ ESEM Observation of CeO 2 Grain Growth During Sintering
Published in Journal of the American Ceramic Society (01-11-2012)“…The CeO 2 sintering and grain growth kinetics were determined from in situ experiments performed using an environmental scanning electron microscope ( ESEM )…”
Get full text
Journal Article -
18
Impact of the cationic homogeneity on Th^sub 0.5^U^sub 0.5^O^sub 2^ densification and chemical durability
Published in Journal of nuclear materials (01-02-2019)“…In order to study the effects of cationic homogeneity on the life cycle of Th1-xUxO2 ceramics, including sintering and reprocessing (dissolution) steps, five…”
Get full text
Journal Article -
19
Impact of the cationic homogeneity on Th$_{0.5}$U$_{0.5}$O$_2$ densification and chemical durability
Published in Journal of nuclear materials (01-02-2019)“…In order to study the effects of cationic homogeneity on the life cycle of Th$_{1-x}$U$_x$O$_2$ ceramics, including sintering and reprocessing (dissolution)…”
Get full text
Journal Article -
20
Kinetics of dissolution of Th^sub 0.25^U^sub 0.75^O^sub 2^ sintered pellets in various acidic conditions
Published in Journal of nuclear materials (01-11-2018)“…In order to gain insights into the kinetics of dissolution of Gen(IV) MOX fuels, sintered pellets of Th0.25U0.75O2 were prepared as surrogates. The study of…”
Get full text
Journal Article