Search Results - "Chulanova, Elena A."
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Radical Anions, Radical‐Anion Salts, and Anionic Complexes of 2,1,3‐Benzochalcogenadiazoles
Published in Chemistry : a European journal (14-01-2019)“…By means of cyclic voltammetry (CV) and DFT calculations, it was found that the electron‐acceptor ability of 2,1,3‐benzochalcogenadiazoles 1–3 (chalcogen: S,…”
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Bis(toluene)chromium(I) [1,2,5]Thiadiazolo[3,4‑c][1,2,5]thiadiazolidyl and [1,2,5]Thiadiazolo[3,4‑b]pyrazinidyl: New Heterospin (S 1 = S 2 = 1/2) Radical-Ion Salts
Published in Inorganic chemistry (03-06-2013)“…Bis(toluene)chromium(0), Cr0(η6-C7H8)2 (3), readily reduced [1,2,5]thiadiazolo[3,4-c][1,2,5]thiadiazole (1) and [1,2,5]thiadiazolo[3,4-b]pyrazine (2) in a…”
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Tuning Molecular Electron Affinities against Atomic Electronegativities by Spatial Expansion of a π‐System
Published in Chemphyschem (02-05-2023)“…2,1,3‐Benzochalcogenadiazoles C6R4N2E (E/R; E=S, Se, Te; R=H, F, Cl, Br, I) and C6H2R2N2E (E/R’; E=S, Se, Te; R=Br, I) are 10π‐electron hetarenes. By CV/EPR…”
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Lewis Ambiphilicity of 1,2,5-Chalcogenadiazoles for Crystal Engineering: Complexes with Crown Ethers
Published in Crystal growth & design (02-09-2020)“…The cocrystallization of 1,2,5-chalcogenadiazoles (chalcogen E = S, Se, and Te) with cyclic polyethers 18-crown-6 (18-c-6) and dibenzo-18-crown-6 (db-18-c-6)…”
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5
Acid‐Base and Anion Binding Properties of Tetrafluorinated 1,3‐Benzodiazole, 1,2,3‐Benzotriazole and 2,1,3‐Benzoselenadiazole
Published in Chemphyschem (18-11-2021)“…The influence of fluorination on the acid‐base properties and the capacity of structurally related 6–5 bicyclic compounds – 1,3‐benzodiazole 1,…”
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Halide Complexes of 5,6‐Dicyano‐2,1,3‐Benzoselenadiazole with 1 : 4 Stoichiometry: Cooperativity between Chalcogen and Hydrogen Bonding
Published in ChemPlusChem (Weinheim, Germany) (01-11-2023)“…The [M4−Hal]− (M=the title compound; Hal=Cl, Br, and I) complexes were isolated in the form of salts of [Et4N]+ cation and characterized by XRD, NMR, UV‐Vis,…”
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New Charge‐Transfer Complexes with 1,2,5‐Thiadiazoles as Both Electron Acceptors and Donors Featuring an Unprecedented Addition Reaction
Published in Chemistry : a European journal (18-01-2017)“…The design and synthesis of novel charge‐transfer (CT) complexes are of interest for fundamental chemistry and applications to materials science. In addition…”
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[1,2,5]Selenadiazolo[3,4-b]pyrazines: Synthesis from 3,4-Diamino-1,2,5-selenadiazole and Generation of Persistent Radical Anions
Published in European journal of organic chemistry (01-09-2015)“…Previously unknown 3,4‐diamino‐1,2,5‐selenadiazole (6) was prepared by hydrolysis of [1,2,5]selenadiazolo[3,4‐c][1,2,5]selenadiazole (7b) and used in synthesis…”
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Coordination Polymers between 3,4-Dicyano-1,2,5-telluradiazole and N,N,N′,N′‑Tetramethylethane-1,2-diamine: The Decisive Role of Chalcogen Bonding
Published in Crystal growth & design (19-06-2024)“…One-dimensional coordination polymers [1·2]∞ (two polymorphs) and [1 2·2]∞ were obtained by cocrystallization of 3,4-dicyano-1,2,5-telluradiazole (1) and…”
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Charge-transfer chemistry of chalcogen–nitrogen π-heterocycles
Published in Mendeleev communications (01-09-2018)“…[Display omitted] Recent achievements in the charge-transfer chemistry of 1,2,5-chalcogenadiazoles, 1,2,3-dichalcogenazoles (chalcogen is S, Se, or Te), their…”
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Recognition and sensing of Lewis bases by 1,2,5-chalcogenadiazoles
Published in Mendeleev communications (01-05-2024)“…[Display omitted] Chalcogen bonding-driven interaction of 1,2,5-chalcogena- diazoles with charged and neutral Lewis bases is discussed. It is highlighted that…”
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Novel long-lived π-heterocyclic radical anion: a hybrid of 1,2,5-thiadiazo- and 1,2,3-dithiazolidyls
Published in Mendeleev communications (01-09-2015)“…A long-lived π-heterocyclic radical anion of the hybrid 1,2,5-thiadiazolidyl / 1,2,3-dithiazolidyl type was electrochemically generated and characterized by…”
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A novel sulfur–nitrogen π-heterocyclic radical anion, (6H-1,2,3-benzodithiazol-6-ylidene)malononitrilidyl, and its homo- and heterospin salts
Published in Polyhedron (18-04-2014)“…(6H-1,2,3-benzodithiazol-6-ylidene)malononitrilidyl (5) was generated electrochemically and chemically, and characterized by solution EPR in combination with…”
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