Search Results - "Choppin, G. R"
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Actinide speciation in the environment
Published in Journal of radioanalytical and nuclear chemistry (01-09-2007)“…Nuclear test explosions and nuclear reactor wastes and accidents have released large amounts of radioactivity into the environment. Actinideions in waters…”
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2
Thermodynamic and Spectroscopic Studies of Lanthanides(III) Complexation with Polyamines in Dimethyl Sulfoxide
Published in Inorganic chemistry (04-02-2008)“…The thermodynamic parameters of complexation of Ln(III) cations with tris(2-aminoethyl)amine (tren) and tetraethylenepentamine (tetren) were determined in…”
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3
Complexation of Eu(III), Am(III) and Cm(III) with Dicarboxylates: Thermodynamics and Structural Aspects of the Binary and Ternary Complexes
Published in Journal of solution chemistry (01-03-2009)“…The complexation of Eu(III), Am(III) and Cm(III) with dicarboxylate anions with O, N or S donor groups was measured in I =6.60 mol⋅kg −1 (NaClO 4 ) at…”
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4
Mixed Ligand Complexes of Am3+, Cm3+ and Eu3+ with HEDTA and HEDTA + NTA—Complexation Thermodynamics and Structural Aspects
Published in Journal of solution chemistry (01-05-2012)“…The stability constants and the associated thermodynamic parameters of formation for the 1:1 binary complexes of Am 3+ , Cm 3+ and Eu 3+ with…”
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5
Thermodynamic Stability and Kinetic Inertness of MS-325, a New Blood Pool Agent for Magnetic Resonance Imaging
Published in Inorganic chemistry (23-04-2001)“…Stability constants were measured for complexes formed between a modified DTPA ligand and the metal ions Gd(III), Eu(III), Fe(III), Ca(II), Cu(II), and Zn(II)…”
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6
Spectroscopic and chemical characterizations of molecular size fractionated humic acid
Published in Talanta (Oxford) (01-10-1999)“…A sample of humic acid was divided by ultrafiltration into five fractions of different molecular size (F1; 300 000: F2; 100 000–300 000: F3; 50 000–100 000:…”
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7
Radionuclide separations in radioactive waste disposal
Published in Journal of radioanalytical and nuclear chemistry (01-01-2000)“…Radionuclide separation processes that have been used successfully in the past as well as recent developments in separation techniques are discussed with…”
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8
THERMODYNAMICS OF SOLVENT EXTRACTION
Published in Solvent extraction and ion exchange (01-11-2000)“…The fundamental thermodynamic characteristics of aqueous electrolyte solutions and organic solutions which affect solvent extraction are summarized and the…”
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Coordination Modes in the Formation of the Ternary Am(III), Cm(III), and Eu(III) Complexes with EDTA and NTA: TRLFS, 13C NMR, EXAFS, and Thermodynamics of the Complexation
Published in Inorganic chemistry (02-10-2006)“…The formation and the structure of the ternary complexes of trivalent Am, Cm, and Eu with mixtures of EDTA+NTA (ethylenediamine tetraacetate and…”
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10
Uranyl Ion Extraction into Room Temperature Ionic Liquids: Species Determination by ESI and MALDI-MS
Published in Solvent extraction and ion exchange (11-06-2010)“…The extraction of uranyl nitrate by TBP in two room temperature ionic liquids (RTILS), viz. 1-alkyl-3 -methyl imidazolium (C n mim, n = 4 and 8) cation with…”
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11
Carbon-13 NMR spectroscopic studies on chemically modified and unmodified synthetic and natural humic acids
Published in Talanta (Oxford) (03-07-2002)“…Carbon-13 cross-polarization magic-angle spinning nuclear magnetic resonance spectroscopy ( 13C-CP/MAS-NMR) was applied to study the chemical modification…”
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12
Actinide speciation in aquatic systems
Published in Marine chemistry (06-03-2006)“…Nuclear test explosions and reactor wastes have deposited an estimated 16 × 10 15 Bq of plutonium into the world's aquatic systems. However, plutonium…”
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13
Hydration Number of Tris[1-(2-thienyl)-4,4,4- trifluoro-1,3-butanedionato]lanthanoids in Chloroform across the Lanthanoid Series
Published in Analytical chemistry (Washington) (15-11-1999)“…The hydration numbers of lanthanoid(III) chelates with 2-thenoyltrifluoroacetone prepared by extracting into chloroform have been determined by analyzing the…”
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14
Extraction and mutual separation of actinide(III), (IV), (V) and (VI) ions by N,N'-dimethyl-N,N'-dihexyl-3-oxapentanediamide and thenoyltrifluoroacetone
Published in Journal of radioanalytical and nuclear chemistry (01-11-2000)“…Actinide(III), (IV), (V) and (VI) ions were extracted by N.N'- dimethyl-N,N'-dihexyl-3-oxapentanediamide (DMDHOPDA) and thenoyltrifluoroacetone (HTTA). The…”
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15
Redox speciation of plutonium
Published in Journal of radioanalytical and nuclear chemistry (01-05-1997)“…The oxidation state distribution of plutonium is an important factor in aquatic systems from the point of view of estimating the plutonium residence period…”
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16
Redox speciation of plutonium in natural waters
Published in Journal of radioanalytical and nuclear chemistry (1991)“…To ascertain the range of conditions of pH, ionic strength for which plutonium(V) (the dominant oxidation state of trace concentrations of plutonium in natural…”
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17
Humic acids coagulation: influence of divalent cations
Published in Applied geochemistry (01-10-2003)“…The effects of the ionic strength (maintained by LiCl, NaCl or KCl) and Ca 2+ and Mg 2+ concentration on the coagulation of purified humic acids (HA) was…”
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18
Complexation thermodynamics and structural aspects of actinide–aminopolycarboxylates
Published in Coordination chemistry reviews (01-04-2006)“…The interaction of trivalent actinides with aminopolycarboxylate ligands in aqueous solution is reviewed. The strength of complexation to form binary and…”
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Uranyl Coordination Environment in Hydrophobic Ionic Liquids: An in Situ Investigation
Published in Inorganic chemistry (07-04-2003)“…Different inner-sphere coordination environments are observed for the uranyl nitrate complexes formed with octyl-phenyl-N,N-diisobutylcarbamoylmethylphosphine…”
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20
Sorption of Am cations on suspended silicate: Effects of pH, ionic strength, complexing anions, humic acid and metal ions
Published in Journal of radioanalytical and nuclear chemistry (01-12-2007)“…Sorption of tracer Am to silicate particles was studied as a function of pcH (4 to 9) and of ionic strength [0.20M to 1.50M (NaClO4)] at 298 K. The sorption…”
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