Intramolecular hydroalkoxylation in Brønsted acidic ionic liquids and its application to the synthesis of (±)-centrolobine

The SO(3)H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.

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Bibliographic Details
Published in:Organic & biomolecular chemistry Vol. 9; no. 2; p. 374
Main Authors: Jeong, Yunkyung, Kim, Do-Young, Choi, Yunsil, Ryu, Jae-Sang
Format: Journal Article
Language:English
Published: England 21-01-2011
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Summary:The SO(3)H-tethered imidazolium and triazolium salts, nonvolatile and recyclable Brønsted acidic ionic liquids, efficiently mediate intramolecular hydroalkoxylations of alkenyl alcohols. They have been successfully employed in the synthesis of (±)-centrolobine.
ISSN:1477-0539
DOI:10.1039/c0ob00701c