Search Results - "Choe, Wonyoung"
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Evolution of form in metal–organic frameworks
Published in Nature communications (04-01-2017)“…Self-assembly has proven to be a widely successful synthetic strategy for functional materials, especially for metal–organic materials (MOMs), an emerging…”
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Stepwise Synthesis of Metal–Organic Frameworks: Replacement of Structural Organic Linkers
Published in Journal of the American Chemical Society (06-07-2011)“…We demonstrate how a single-crystal to single-crystal transformation resulting from bridging-linker replacement is possible in extended 2D and 3D metal–organic…”
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Cross-linking Zr-based metal-organic polyhedra via postsynthetic polymerization
Published in Chemical science (Cambridge) (2017)“…Metal organic polyhedra (MOPs) have potential as supramolecular building blocks, but utilizing MOPs for postsynthetic polymerization has not been explored…”
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MOP × MOF: Collaborative Combination of Metal–Organic Polyhedra and Metal–Organic Framework for Proton Conductivity
Published in ACS applied materials & interfaces (03-04-2019)“…We report a hybrid solid system, UMOM-100-a and UMOM-100-b, synthesized by incorporation of Cu-based metal–organic polyhedra (MOPs) into a porous metal–organic…”
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MOF × Biopolymer: Collaborative Combination of Metal–Organic Framework and Biopolymer for Advanced Anticancer Therapy
Published in ACS applied materials & interfaces (07-08-2019)“…Metal–organic framework (MOF) nanoparticles with high porosity and greater tunability have emerged as new drug delivery vehicles. However, premature drug…”
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Rapid access to polycyclic N-heteroarenes from unactivated, simple azines via a base-promoted Minisci-type annulation
Published in Nature communications (03-05-2022)“…Conventional synthetic methods to yield polycyclic heteroarenes have largely relied on metal-mediated arylation reactions requiring pre-functionalised…”
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Formation of trigons in a metal-organic framework: The role of metal-organic polyhedron subunits as meta-atoms
Published in Chemical science (Cambridge) (28-06-2019)“…Shape control of metal-organic materials on the meso- and macroscale has been an important theme due to emerging properties. Particularly, chemical etching has…”
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Origamic metal-organic framework toward mechanical metamaterial
Published in Nature communications (01-12-2023)“…Origami, known as paper folding has become a fascinating research topic recently. Origami-inspired materials often establish mechanical properties that are…”
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Discovery of Zr-based metal-organic polygon: Unveiling new design opportunities in reticular chemistry
Published in Nano research (01-02-2021)“…Metal-based secondary building unit and the shape of organic ligands are the two crucial factors for determining the final topology of metal-organic materials…”
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10
An Annulative Synthetic Strategy for Building Triphenylene Frameworks by Multiple C−H Bond Activations
Published in Angewandte Chemie International Edition (24-04-2017)“…C−H activation is a versatile tool for appending aryl groups to aromatic systems. However, heavy demands on multiple catalytic cycle operations and…”
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Pillared Porphyrin Homologous Series: Intergrowth in Metal−Organic Frameworks
Published in Inorganic chemistry (19-01-2009)“…We report three new porphyrin-based, pillared paddle-wheel homologous series: porphyrin paddle-wheel frameworks PPF-3, -4, and -5. These compounds are…”
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Self-Assembly and Properties of Nonmetalated Tetraphenyl-Porphyrin on Metal Substrates
Published in Journal of physical chemistry. C (27-05-2010)“…The structure−electronic structure relationship of nonmetalated meso-tetraphenyl porphyrin (2H-TPP) on the (111) surfaces of Ag, Cu, and Au was studied with a…”
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Structural Variation in Porphyrin Pillared Homologous Series: Influence of Distinct Coordination Centers for Pillars on Framework Topology
Published in Crystal growth & design (01-07-2009)“…A new series of porphyrin paddlewheel frameworks (PPFs) has been assembled from 5,10,15,20-tetrakis(4-carboxyl)-21H,23H-porphine (TCPP), Zn(NO3)2·6H2O, and…”
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Parsimonious Topology Based on Frank-Kasper Polyhedra in Metal–Organic Frameworks
Published in JACS Au (22-07-2024)“…A new topology previously unknown in metal–organic frameworks (MOFs) provides an important clue to uncovering a new series of polyhedral MOFs. We report a…”
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Isolation and Reactivity of Arylnickel(II) Complexes in Nickel-Catalyzed Borylation of Aryl Fluorosulfates
Published in JACS Au (22-04-2024)“…Aryl fluorosulfates have emerged as versatile SuFExable substrates, harnessing the reactivity of the S–F bond. In this study, we unveil their alternative…”
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Highly Tunable Heterometallic Frameworks Constructed from Paddle-Wheel Units and Metalloporphyrins
Published in Crystal growth & design (01-04-2009)“…Seven new heterometallic frameworks have been synthesized with specific control over the metallic composition of each structure. Using Mn, Fe, Ni, V, and Pt…”
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Classification of Structural Motifs in Porphyrinic Coordination Polymers Assembled from Porphyrin Building Units, 5,10,15,20-Tetrapyridylporphyrin and Its Derivatives
Published in Journal of chemical crystallography (01-04-2009)“…In this review, we classify 1D, 2D, and 3D structural motifs found in porphyrinic coordination polymers assembled from 5,10,15,20-tetrapyridylporphyrin (TPyP)…”
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Synthesis of α,β-unsaturated ketones through nickel-catalysed aldehyde-free hydroacylation of alkynes
Published in Communications chemistry (03-02-2022)“…α,β-Unsaturated ketones are common feedstocks for the synthesis of fine chemicals, pharmaceuticals, and natural products. Transition metal-catalysed…”
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Nanozyme Based on Porphyrinic Metal–Organic Framework for Electrocatalytic CO2 Reduction
Published in Small structures (01-01-2023)“…Mimicry of natural enzyme systems is an important approach for catalyst design. To create an enzyme‐inspired catalyst, it is essential to mimic both the active…”
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Metal-organic framework based on hinged cube tessellation as transformable mechanical metamaterial
Published in Science advances (01-05-2019)“…Mechanical metamaterials exhibit unusual properties, such as negative Poisson's ratio, which are difficult to achieve in conventional materials. Rational…”
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