Search Results - "Chinn, Sarah C"
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Synthesis of High-Surface-Area Alumina Aerogels without the Use of Alkoxide Precursors
Published in Chemistry of materials (25-01-2005)“…Alumina aerogels were prepared through the addition of propylene oxide to aqueous or ethanolic solutions of hydrated aluminum salts, AlCl3·6H2O or…”
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2
Characterization of local deformation in filled-silicone elastomers subject to high strain – NMR MOUSE and Magnetic Resonance Imaging as a diagnostic tool for detection of inhomogeneities
Published in Polymer degradation and stability (01-08-2006)“…Magnetic Resonance Imaging (MRI) and unilateral Nuclear Magnetic Resonance (NMR) relaxometry with the NMR MOUSE (MObile Universal Surface Explorer) have been…”
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3
The stability of poly( m-carborane-siloxane) elastomers exposed to heat and gamma radiation
Published in Polymer degradation and stability (01-03-2006)“…Poly( m-carboranyl-siloxane) elastomers containing a mixture of di-methyl- and methylphenyl-silyl units were synthesised using the ferric chloride catalysed…”
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Journal Article Conference Proceeding -
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Qualification of automated low-field NMR relaxometry for quality control of polymers in a production setting
Published in Polymer testing (01-12-2007)“…Implementation of a low-field time-domain nuclear magnetic resonance (NMR) scanner as a diagnostic tool in the production of new polymer components is…”
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5
Fiber-based solid phase microextraction using fused silica lined bottles to collect, store, and stabilize a multianalyte headspace gas sample for offline analyses
Published in Journal of Chromatography A (03-07-2015)“…•Developed a new fiber SPME sampling method using fused silica lined bottles.•Fiber SPME using fused silica lined bottles is equivalent to in situ…”
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6
Solid state NMR investigation of γ-irradiated composite siloxanes: Probing the silica/polysiloxane interface
Published in Polymer degradation and stability (01-07-2013)“…We employ silicon-proton (29Si{1H}) cross polarization magic-angle spinning (CP-MAS) to probe directly the interface of a silica-filled polysiloxane elastomer…”
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7
Complexities associated with moisture in foamed polysiloxane composites
Published in Polymer degradation and stability (01-02-2008)“…An understanding of mechanisms of moisture outgassing from silicones and the impact on material mechanical properties is important for compatibility and life…”
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8
Linking Network Microstructure to Macroscopic Properties of Siloxane Elastomers Using Combined Nuclear Magnetic Resonance and Mesoscale Computational Modeling
Published in Macromolecules (25-10-2011)“…It is well established that many fundamental properties of polymer materials are directly governed by chain dynamics, and both experimental and computational…”
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9
First-principles molecular dynamics simulations of condensed-phase V-type nerve agent reaction pathways and energy barriers
Published in Physical chemistry chemical physics : PCCP (14-03-2012)“…Computational studies of condensed-phase chemical reactions are challenging in part because of complexities in understanding the effects of the solvent…”
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10
Determination of the Surface Effects on Sarin Degradation
Published in Journal of physical chemistry. C (03-05-2012)“…While it is well established that the dominant degradation mechanism for the chemical warfare agent, sarin, is hydrolysis via an SN2 mechanism in aqueous…”
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11
Portable, low-cost NMR with laser-lathe lithography produced microcoils
Published in Journal of magnetic resonance (1997) (01-11-2007)“…Nuclear Magnetic Resonance (NMR) is unsurpassed in its ability to non-destructively probe chemical identity. Portable, low-cost NMR sensors would enable…”
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12
Quantification of radiation induced crosslinking in a commercial, toughened silicone rubber, TR55 by H MQ-NMR
Published in Polymer degradation and stability (01-03-2009)“…Radiation induced degradation in a commercial, filled silicone composite has been studied by SPME/GC-MS, DMA, DSC, swelling, and multiple quantum NMR. Analysis…”
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Journal Article -
13
MQ NMR and SPME Analysis of Nonlinearity in the Degradation of a Filled Silicone Elastomer
Published in The journal of physical chemistry. B (05-08-2010)“…Radiation-induced degradation of polymeric materials occurs through numerous, simultaneous, competing chemical reactions. Although degradation is typically…”
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14
Nuclear magnetic resonance and principal component analysis for investigating the degradation of poly[chlorotrifluoroethylene-co-(vinylidene fluoride)] by ionizing radiation
Published in Polymer degradation and stability (01-07-2012)“…Reported here is the application of multivariate statistical analysis to nuclear magnetic resonance (NMR) data for the understanding of irradiative degradation…”
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Journal Article -
15
Modeling (1)H NMR transverse magnetization decay in polysiloxane-silica composites
Published in Chemical engineering science (16-11-2009)“…Nuclear magnetic resonance (NMR) spectroscopy has been used effectively in the analysis of elastomeric, soft materials and has been proven to be both sensitive…”
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16
Modeling 1H NMR transverse magnetization decay in polysiloxane-silica composites
Published in Chemical engineering science (01-11-2009)“…Nuclear magnetic resonance (NMR) spectroscopy has been used effectively in the analysis of elastomeric, soft materials and has been proven to be both sensitive…”
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17
Local Structure of Amorphous (PbO) x [(B2O3)1 - z (Al2O3) z ] y (SiO2) y Dielectric Materials by Multinuclear Solid State NMR
Published in Chemistry of materials (22-03-2005)“…Structural speciation of glasses in the systems PbO−B2O3−SiO2, PbO−B2O3−Al2O3−SiO2, and PbO−Al2O3−SiO2 were studied using solid state 29Si, 27Al, 11B, and…”
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18
Quantification of radiation induced crosslinking in a commercial, toughened silicone rubber, TR55 by 1H MQ-NMR
Published in Polymer degradation and stability (01-03-2009)“…Radiation induced degradation in a commercial, filled silicone composite has been studied by SPME/GC–MS, DMA, DSC, swelling, and multiple quantum NMR. Analysis…”
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Journal Article -
19
Radiation-Induced Cross-Linking in a Silica-Filled Silicone Elastomer As Investigated by Multiple Quantum 1H NMR
Published in Macromolecules (09-08-2005)“…DC745 is a commercially available silicone elastomer consisting of dimethyl, methyl−phenyl, and vinyl−methyl siloxane monomers cross-linked with a peroxide…”
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Journal Article -
20
Thermal Degradation in a Trimodal Poly(dimethylsiloxane) Network Studied by 1H Multiple Quantum NMR
Published in The journal of physical chemistry. B (15-11-2007)“…Thermal degradation of a filled, cross-linked siloxane material synthesized from poly(dimethylsiloxane) chains of three different average molecular weights and…”
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