Search Results - "Cherkinsky, Marina"
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Reaction of selenium and tellurium halides with propargyl alcohols. The regio- and stereoselectivity of addition to the triple bond
Published in Journal of physical organic chemistry (01-11-2010)“…A convenient method to incorporate selenium into an organic molecule is reported. Various aspects of the reaction of SeCl2 with propargyl alcohols, i.e.,…”
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Synthesis and reactivity of dipropargylic disulfides: tandem rearrangements, cyclization, and oxidative dimerization
Published in Tetrahedron (06-03-2010)“…Synthesis and facile rearrangement and cyclization reaction of new dipropargylic disulfides are described. A possible mechanism for these transformations…”
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One-pot three-component preparation of novel selenium-containing spiroketals
Published in Journal of physical organic chemistry (01-02-2013)“…The one‐pot three‐component preparation of novel selenium‐containing spiroketals with potential biological activity is described. When in situ prepared…”
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Synthesis and cascade reactions of diallenyl α-disulfones and sulfinyl sulfones
Published in Tetrahedron letters (17-09-2007)“…The synthesis and reactivity of diallenic α-disulfones and diallenic sulfinyl sulfones are described. Both types of compound exhibit enhanced reactivity…”
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Chalcogen Halides Plus Propargyl Alcohols-Fascinating Reaction Pathways and Products
Published in Phosphorus, sulfur, and silicon and the related elements (01-05-2011)“…A convenient method to incorporate selenium into an organic molecule is reported. Selenium halides undergo smooth 1,2-addition to the triple bond of various…”
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Thermal rearrangements of bis-allenyl thiosulfonates. Synthesis of novel thienothiophene and thieno-oxathiine derivatives
Published in Tetrahedron letters (23-12-2002)“…The synthesis and thermal rearrangement of bis-allenyl thiosulfonates are described. Bis-γ,γ-disubstituted allenyl thiosulfonates have been prepared by…”
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Base-Catalyzed Reactivity of Sulfur- and Selenium-Bridged Cyclic Alkynes: Tandem Isomerization and Cycloaromatization versus Isomerization and Nucleophilic Addition
Published in European journal of organic chemistry (01-09-2002)“…The synthesis and base‐catalyzed reactivity of some novel sulfur‐ and selenium‐bridged cyclic di‐ and tetralkynes, derived from 1,2‐ and 1,4‐dihydroxybenzene…”
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A new approach to the synthesis of 2-vinylthiophenes and selenophenes; competition between free radical and anionic cycloaromatization of bridged di- and tetrapropargylic sulfides and selenides
Published in Tetrahedron (07-04-2003)“…A series of unknown di- and tetrapropargylic sulfides and selenides have been prepared. In the presence of t-BuOK in dry THF these compounds underwent…”
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Preparation of trichlorothioacetamides and their unexpected rearrangement to thiooxamides
Published in Tetrahedron letters (10-12-1998)“…The preparation of several N-monosubstituted trichlorothioacetamides by thionation of the corresponding acetamides, with the use of Heimgartner's reagent is…”
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Rearrangements of Trihalomethyl Ketones
Published in Tetrahedron (23-06-2000)“…Trihalomethyl ketones have been prepared and their reactivity under basic conditions was investigated in terms of competition between 1,2- vs. 1,3-elimination…”
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A new synthesis of N-sulfinylamines via β-elimination of chloroform from trichloromethanesulfinamides
Published in Tetrahedron letters (20-01-1997)“…The synthesis of various N-monosubstituted trichloromethanesulfinamides by two alternative and novel procedures is described. All these compounds have been…”
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Brominated vinyl ketene thioacetal, ene- and diene acetals; potential four-carbon synthons
Published in Tetrahedron (19-02-1999)“…A novel and convenient procedure for the preparation of conjugated vinyl ketene thioacetals is described: it involves addition of CBr 4 to acrolein, followed…”
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