Search Results - "Chen, Yan‐Cong"
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Magnetic hysteresis up to 80 kelvin in a dysprosium metallocene single-molecule magnet
Published in Science (American Association for the Advancement of Science) (21-12-2018)“…Single-molecule magnets (SMMs) containing only one metal center may represent the lower size limit for molecule-based magnetic information storage materials…”
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A Dysprosium Metallocene Single‐Molecule Magnet Functioning at the Axial Limit
Published in Angewandte Chemie International Edition (11-09-2017)“…ion of a chloride ligand from the dysprosium metallocene [(Cpttt)2DyCl] (1Dy Cpttt=1,2,4‐tri(tert‐butyl)cyclopentadienide) by the triethylsilylium cation…”
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Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet
Published in Angewandte Chemie International Edition (24-04-2017)“…An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide…”
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Luminescent single-molecule magnets based on lanthanides: Design strategies, recent advances and magneto-luminescent studies
Published in Coordination chemistry reviews (01-01-2019)“…[Display omitted] •Briefly state the design strategies for luminescent lanthanide single-molecule magnets (SMMs).•Systematically survey the recent advances of…”
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A Single-Site Platinum CO Oxidation Catalyst in Zeolite KLTL: Microscopic and Spectroscopic Determination of the Locations of the Platinum Atoms
Published in Angewandte Chemie (International ed.) (18-08-2014)“…A stable site‐isolated mononuclear platinum catalyst with a well‐defined structure is presented. Platinum complexes supported in zeolite KLTL were synthesized…”
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Recent advances in the design of magnetic molecules for use as cryogenic magnetic coolants
Published in Coordination chemistry reviews (01-12-2014)“…•The cryogenic magnetocaloric effect in different magnetic systems is discussed.•The assembly strategies toward 3d-, 4f- and 3d–4f based molecular magnetic…”
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Recent advances in guest effects on spin-crossover behavior in Hofmann-type metal-organic frameworks
Published in Coordination chemistry reviews (15-03-2017)“…[Display omitted] •Systematic summary of guest effects in spin-crossover Hofmann clathrates.•Molecular volume calculated by a convenient formula is applied to…”
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Symmetry-Supported Magnetic Blocking at 20 K in Pentagonal Bipyramidal Dy(III) Single-Ion Magnets
Published in Journal of the American Chemical Society (02-03-2016)“…Single-molecule magnets (SMMs) that can be trapped in one of the bistable magnetic states separated by an energy barrier are among the most promising…”
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Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown
Published in Angewandte Chemie International Edition (01-03-2021)“…Combining Ising‐type magnetic anisotropy with collinear magnetic interactions in single‐molecule magnets (SMMs) is a significant synthetic challenge. Herein we…”
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Guest‐Driven Light‐Induced Spin Change in an Azobenzene Loaded Metal–Organic Framework
Published in Angewandte Chemie International Edition (20-12-2021)“…Stimuli‐responsive materials that can be reversibly switched by light are of immense interest. Among them, photo‐responsive spin crossover (SCO) complexes have…”
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Guest‐Switchable Multi‐Step Spin Transitions in an Amine‐Functionalized Metal–Organic Framework
Published in Angewandte Chemie International Edition (20-11-2017)“…Materials with hysteretic multi‐step spin‐crossover (SCO) have potential application in high‐order data storage. Here, an unprecedented hysteretic four‐step…”
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Uranocenium: Synthesis, Structure, and Chemical Bonding
Published in Angewandte Chemie International Edition (22-07-2019)“…ion of iodide from [(η5‐C5iPr5)2UI] (1) produced the cationic uranium(III) metallocene [(η5‐C5iPr5)2U]+ (2) as a salt of [B(C6F5)4]−. The structure of 2…”
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A Stable Silanol Triad in the Zeolite Catalyst SSZ‐70
Published in Angewandte Chemie International Edition (26-06-2020)“…Nests of three silanol groups are located on the internal pore surface of calcined zeolite SSZ‐70. 2D 1H double/triple‐quantum single‐quantum correlation NMR…”
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Magnetization Dynamics on Isotope‐Isomorphic Holmium Single‐Molecule Magnets
Published in Angewandte Chemie International Edition (20-12-2021)“…Here we reported the deuteration of the metal‐binding equatorial water molecules in a reported HoIII single‐molecule magnet (SMM) with pentagonal‐bipyramidal…”
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Single‐Crystal Transformation Engineering the Spin Change of Metal–Organic Frameworks via Cluster Deconstruction
Published in Angewandte Chemie International Edition (13-11-2023)“…Spin crossover (SCO) materials with new architectures will expand and enrich the research in the SCO field. Here, we report two metal–organic frameworks (MOFs)…”
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Spin-crossover modulation via single-crystal to single-crystal photochemical [2 + 2] reaction in Hofmann-type frameworks
Published in Chemical science (Cambridge) (28-08-2019)“…This study reports the first modulation of spin-crossover (SCO) behavior a photochemical [2 + 2] cycloaddition reaction. Here we construct two no-solvent…”
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Light- and temperature-assisted spin state annealing: accessing the hidden multistability
Published in Chemical science (Cambridge) (28-03-2020)“…Among responsive multistable materials, spin crossover (SCO) systems are of particular interest for stabilizing multiple spin states with various stimulus…”
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Anion-Templated Assembly and Magnetocaloric Properties of a Nanoscale {Gd38} Cage versus a {Gd48} Barrel
Published in Chemistry : a European journal (25-10-2013)“…The comprehensive study reported herein provides compelling evidence that anion templates are the main driving force in the formation of two novel nanoscale…”
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Desolvation-Driven 100-Fold Slow-down of Tunneling Relaxation Rate in Co(II)-Dy(III) Single-Molecule Magnets through a Single-Crystal-to-Single-Crystal Process
Published in Scientific reports (17-11-2015)“…Single-molecule magnets (SMMs) are regarded as a class of promising materials for spintronic and ultrahigh-density storage devices. Tuning the magnetic…”
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Effect of Bridging Ligands on Magnetic Behavior in Dinuclear Dysprosium Cores Supported by Polyoxometalates
Published in Inorganic chemistry (22-01-2019)“…A family of dinuclear dysprosium cores bridged by different ligands within a polyoxometalates (POMs) framework, (TBA)8.5H1.5[(PW11O39)2Dy2X2(H2O)2]·6H2O (X =…”
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