Degradation of Carbon Fiber-Reinforced Polymer Composites in Salt Water and Rapid Evaluation by Electrochemical Impedance Spectroscopy

The electrochemical impedance spectroscopy and weight gain tests were performed on carbon fiber/vinyl ester and carbon fiber/bismaleimide composites in 3.5% NaCl solution to study the electrochemical and water absorption behaviors. The microstructure morphology and the flexural property of the compo...

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Bibliographic Details
Published in:Materials Vol. 16; no. 4; p. 1676
Main Authors: Zhang, Hanlu, Kong, Fabao, Dun, Yuchao, Chen, Xueping, Chen, Quankai, Zhao, Xuhui, Tang, Yuming, Zuo, Yu
Format: Journal Article
Language:English
Published: Switzerland MDPI AG 17-02-2023
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Summary:The electrochemical impedance spectroscopy and weight gain tests were performed on carbon fiber/vinyl ester and carbon fiber/bismaleimide composites in 3.5% NaCl solution to study the electrochemical and water absorption behaviors. The microstructure morphology and the flexural property of the composites in the long-term exposure process were analyzed with the scanning electron microscope and four-point bending tests. The results revealed that after long-time immersion (>200 d), the water absorption of the two composites is less than 0.5%. This has little effect on the microstructural integrity, only with slight damage on the fiber/resin interfaces, but results in a significant decrease (about 84%) in the composite flexural property. The variation of the water absorption percentage shows good consistency with that of the resin capacitance ( ) and is negatively related to the variation of the resin resistance ( ) and the low-frequency impedance (| | ) of the composites. A good linear relationship exists between the variations of phase angles in the middle-frequency range (0.1-10 Hz) and the | | . The phase angle at 10 Hz ( ) may be suggested as a suitable parameter to rapidly evaluate the performance of carbon fiber-reinforced polymer composites, just like for evaluating the protective performance of polymer-coated metals in the literature.
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These authors contributed equally to this work.
ISSN:1996-1944
1996-1944
DOI:10.3390/ma16041676