Search Results - "Chen, Peter P"
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Alkane Oxidation: Methane Monooxygenases, Related Enzymes, and Their Biomimetics
Published in Chemical reviews (12-07-2017)“…Methane monooxygenases (MMOs) mediate the facile conversion of methane into methanol in methanotrophic bacteria with high efficiency under ambient conditions…”
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Probing substrate binding inside a paramagnetic cavity: a NMR spectroscopy toolbox for combined experimental and theoretical investigation
Published in Chemical science (Cambridge) (24-09-2024)“…Protein cavities often rely on the paramagnetic metal present in their active site in order to catalyse various chemical transformations in biology. The…”
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Efficient Room-Temperature Oxidation of Hydrocarbons Mediated by Tricopper Cluster Complexes with Different Ligands
Published in Advanced synthesis & catalysis (26-11-2012)“…Six tricopper cluster complexes of the type [CuICuICuI(L)]1+ supported by a series of multidentate ligands (L) have been developed as oxidation catalysts…”
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The MoMo Quintuple Bond as a Ligand to Stabilize Transition-Metal Complexes
Published in Angewandte Chemie International Edition (27-07-2015)“…Herein, we report the employment of the MoMo quintuple bonded amidinate complex to stabilize Group 10 metal fragments {(Et3P)2M} (M=Pd, Pt) and give rise to…”
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Efficient catalytic oxidation of hydrocarbons mediated by tricopper clusters under mild conditions
Published in Journal of catalysis (01-09-2012)“…Two tricopper clusters have been developed as oxidation catalysts capable of converting cyclohexane to cyclohexanol/cyclohexanone with high efficiency at room…”
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Development of the Tricopper Cluster as a Catalyst for the Efficient Conversion of Methane into MeOH
Published in ChemCatChem (01-02-2014)“…Following recent progress towards understanding the structure of the particulate methane monooxygenase in methanotrophic bacteria, it is now possible to…”
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Paramagnetic NMR Shifts for Saddle-Shaped Five-Coordinate Iron(III) Porphyrin Complexes with Intermediate-Spin Structure
Published in Angewandte Chemie International Edition (10-09-2012)“…Calculable results: Complex density functional calculations and spin distribution analyses have been performed for planar and saddled iron(III) porphyrin…”
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Redox Potentiometry Studies of Particulate Methane Monooxygenase: Support for a Trinuclear Copper Cluster Active Site
Published in Angewandte Chemie International Edition (01-01-2007)“…A pocketful of coppers: Redox potentiometry and EPR experiments have confirmed that the active site of the particulate methane monooxygenase (pMMO), a…”
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Dioxygen Activation of a Trinuclear CuICuICuI Cluster Capable of Mediating Facile Oxidation of Organic Substrates: Competition between O-Atom Transfer and Abortive Intercomplex Reduction
Published in Chemistry : a European journal (26-03-2012)“…The dioxygen activation of a series of CuICuICuI complexes based on the ligands (L) 3,3′‐(1,4‐diazepane‐…”
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Different Antiferromagnetic Coupling between 5,5′‐ and 10,10′‐Linked Iron(III) Corrole Dimers
Published in European journal of inorganic chemistry (10-03-2017)“…Two FeIII corroles were connected through a single meso–meso linkage at different positions, that is, 5,5′‐linkage and 10,10′‐linkage, which led to the…”
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Facile O-atom insertion into C{cjs0807}C and C{cjs0807}H bonds by a trinuclear copper complex designed to harness a singlet oxene
Published in Proceedings of the National Academy of Sciences - PNAS (11-09-2007)“…Two trinuclear copper [CuICuICuI(L)]¹⁺ complexes have been prepared with the multidentate ligands (L)…”
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Myosin binding protein-C phosphorylation is the principal mediator of protein kinase A effects on thick filament structure in myocardium
Published in Journal of molecular and cellular cardiology (01-11-2012)“…Abstract Phosphorylation of cardiac myosin binding protein-C (cMyBP-C) is a regulator of pump function in healthy hearts. However, the mechanisms of regulation…”
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The characterization of the saddle shaped nickel(III) porphyrin radical cation: an explicative NMR model for a ferromagnetically coupled metallo-porphyrin radical
Published in Chemical communications (Cambridge, England) (01-01-2014)“…Ni(III)(OETPP˙)(Br)2 is the first Ni(III) porphyrin radical cation with structural and (1)H and (13)C paramagnetic NMR data for porphyrinate systems…”
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14
Advanced Magnetic Resonance Studies of Tetraphenylporphyrinatoiron(III) Halides
Published in Applied magnetic resonance (01-11-2020)“…High-Frequency and -Field EPR (HFEPR) studies of Fe(TPP)X (X = F, Cl, Br; I, TPP 2− = meso -tetraphenylporphyrinate dianion) and far-IR magnetic spectroscopic…”
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Methane oxidation by the copper methane monooxygenase: Before and after the cryogenic electron microscopy structure of particulate methane monooxygenase from Methylococcus capsulatus (Bath)
Published in Journal of the Chinese Chemical Society (Taipei) (01-08-2022)“…The particulate methane monooxygenase (pMMO) is a copper monooxygenase that converts methane into methanol in methanotrophic bacteria. As this enzyme converts…”
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GATA3 expression in primary lung carcinomas: correlation with histopathologic features and TTF-1, napsin A, and p40 expression
Published in Human pathology (01-05-2023)“…This study assessed the expression of GATA3 in primary lung carcinomas and correlated it with tumor histology and immunostains routinely utilized in the work…”
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Theoretical modeling of the hydroxylation of methane as mediated by the particulate methane monooxygenase
Published in Journal of inorganic biochemistry (01-04-2006)“…We present here the results of density functional theory (DFT) calculations directed toward elucidation of the C H bond activation mechanism that might be…”
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Copper–obatoclax derivative complexes mediate DNA cleavage and exhibit anti-cancer effects in hepatocellular carcinoma
Published in Chemico-biological interactions (25-02-2015)“…•Obatoclax and compound 7 selectively coordinate with copper ion.•Structure–activity relationship of copper–obatoclax derivatives in DNA…”
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An Unusual Cause of Obstructive Jaundice: a Metastatic Renal Cell Carcinoma
Published in The American journal of gastroenterology (01-11-2024)Get full text
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Transmural variation in myosin heavy chain isoform expression modulates the timing of myocardial force generation in porcine left ventricle
Published in The Journal of physiology (01-11-2008)“…Recent studies have shown that the sequence and timing of mechanical activation of myocardium vary across the ventricular wall. However, the contributions of…”
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