Search Results - "Chandrasekar, Aditi"
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Uncovering Heavy Actinide Covalency: Implications for Minor Actinide Partitioning
Published in Inorganic chemistry (18-03-2019)“…Across the actinide period, the stability of the trivalent oxidation state predominates in the heavy actinides, making their chemical nature close to that of…”
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Alumina-Based Bifunctional Catalyst for Efficient CO2 Fixation into Epoxides at Atmospheric Pressure
Published in Inorganic chemistry (17-10-2022)“…The quest toward sustainability and decarbonization demands the development of methods for efficient carbon dioxide capture and utilization. The nonreductive…”
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Phosphorus-Induced One-Step Synthesis of NiCo2S4 Electrode Material for Efficient Hydrazine-Assisted Hydrogen Production
Published in Inorganic chemistry (02-10-2023)“…Rational control of the reaction parameters is highly important for synthesizing active electrocatalysts. NiCo2S4 is an excellent spinel-based electrocatalyst…”
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Phosphorus-Induced One-Step Synthesis of NiCo 2 S 4 Electrode Material for Efficient Hydrazine-Assisted Hydrogen Production
Published in Inorganic chemistry (02-10-2023)“…Rational control of the reaction parameters is highly important for synthesizing active electrocatalysts. NiCo2S4 is an excellent spinel-based electrocatalyst…”
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Alumina-Based Bifunctional Catalyst for Efficient CO 2 Fixation into Epoxides at Atmospheric Pressure
Published in Inorganic chemistry (17-10-2022)Get full text
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Highly selective separations of U(VI) from a Th(IV) matrix by branched butyl phosphates: Insights from solvent extraction, chromatography and quantum chemical calculations
Published in Separation and purification technology (08-02-2019)“…[Display omitted] •Remarkable separation of U(VI) from Th(IV) matrices at the liquid-liquid interface.•Demonstration by extraction chromatography using coated…”
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Experimental evidence and quantum chemical insights into extraction and third phase aggregation trends in Ce(IV) organophosphates
Published in Separation and purification technology (15-06-2019)“…Solvent extraction behaviour of Ce(IV) which is a surrogate for Pu(IV) has been examined for the first time with TsBP, both experimentally and through DFT…”
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Luminescent Silver Clusters with Covalent Functionalization of Graphene
Published in Journal of physical chemistry. C (05-07-2012)“…Brightly luminescent, atomically precise subnanometer clusters of silver protected by glutathione were covalently functionalized by solution phase thiolated…”
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On the position of La, Lu, Ac and Lr in the periodic table: a perspective
Published in Journal of chemical sciences (Bangalore, India) (01-12-2019)“…The periodic table of elements, organised as blocks of elements that contain similar properties, occupies a central role in chemistry. However, the position of…”
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Counter-Intuitive Stability in Actinide-Encapsulated Metalloid Clusters with Broken Aromaticity
Published in Journal of physical chemistry. C (04-10-2018)“…Aromaticity has been traditionally used for decades to explain the exceptional stability of certain conjugated organic compounds. Only in the recent past, this…”
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Influence of Branching on the Conformational Space: Case Study of Tri-sec-butyl Phosphate Using Matrix Isolation Infrared Spectroscopy and DFT Computations
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (18-10-2018)“…The conformational analysis of long chain phosphates poses a serious challenge due to the presence of rotationally flexible multiple alkyl groups…”
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Structure‐Modulated Complexation of Actinides with Phosphonates: A Combined Experimental and Quantum Chemical Investigation
Published in ChemistrySelect (Weinheim) (31-10-2018)“…Phosphonates have shown promising specificity and remarkable extractability towards actinide elements. Among all the organophosphorous compounds, phosphonates…”
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