Search Results - "Chaloux, Brian L"
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Comparing Proton Conduction in Potassium and Ammonium Borosulfate—Isostructural Inorganic Polyelectrolytes Exhibiting High Proton Mobility
Published in Advanced energy and sustainability research (01-08-2022)“…A scalable new method for the synthesis of borosulfate compounds in sulfuric acid providing control over product crystallite size is reported as an alternative…”
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2
Long, Directional Interactions in Cofacial Silicon Phthalocyanine Oligomers
Published in The journal of physical chemistry. A, Molecules, spectroscopy, kinetics, environment, & general theory (17-11-2011)“…Single crystal structures have been determined for the three cofacial, oxygen-bridged, silicon phthalocyanine oligomers,…”
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3
Facile Proton Transport in Ammonium Borosulfate—An Unhumidified Solid Acid Polyelectrolyte for Intermediate Temperatures
Published in Advanced materials (Weinheim) (01-10-2020)“…High proton conductivity is reported for unhumidified ammonium borosulfate, NH4[B(SO4)2], a solid acid coordination polymer that contains 1D, hydrogen‐bonded…”
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4
Manipulation of the Thermochromic Transition Temperature in a Classic Metal–Organic Complex by Selective Anion Doping
Published in Inorganic chemistry (13-06-2022)“…The origin of thermochromism displayed by the hybrid material [Ni(dieten)2](BF4)2 (dieten = N,N-diethylethylenediamine) is explored by anion substitution of…”
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5
Carbon-boron clathrates as a new class of sp3-bonded framework materials
Published in Science advances (10-01-2020)“…The realization of a novel guest/host carbon-boron sp 3 framework opens the door for a new class of 3D carbon-based materials. Carbon-based frameworks composed…”
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Exploring the Effects of Reaction Conditions on Morphology and Stability of Sonochemically Generated Ti–Al–B Fuel Powders
Published in Energy & fuels (17-09-2020)“…Sonochemically mediated dehydrogenation of in situ generated complex metal hydrides is a promising methodology for the synthesis of mixed-metal powders for…”
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7
Nanoarchitecture through Strained Molecules: Cubane-Derived Scaffolds and the Smallest Carbon Nanothreads
Published in Journal of the American Chemical Society (21-10-2020)“…Relative to the rich library of small-molecule organics, few examples of ordered extended (i.e., nonmolecular) hydrocarbon networks are known. In particular,…”
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8
Molecular dynamics study of hydroxide ion diffusion in polymer electrolytes
Published in Electrochemistry communications (01-07-2022)“…•Computational models for poly(4-dimethylaminomethyl styrene) (pDMAMS) and copolymers comprising DMAMS and 4-butylstyrene are developed.•Glass transition…”
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9
Synthesis and characterization of a high-temperature polycyanophosphate resin
Published in Phosphorus, sulfur, and silicon and the related elements (03-05-2024)“…A phosphorus-containing polymer with very high thermo-oxidative stability was synthesized for the first time by addition of silver nitrate to tricyanophosphine…”
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10
Mild Solvothermal Growth of Robust Carbon Phosphonitride Films
Published in Chemistry of materials (11-09-2018)“…Solvothermal growth of thin (1–2 μm thick), uniform films of carbon phosphonitride on fused quartz substrates has been achieved by self-reaction of 1 m P(CN)3…”
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11
Linear perfluoroalkyl carboxylate reduction dynamics with solvated electrons from ferrocyanide and sulfite
Published in Environmental science. Advances (27-11-2023)“…The initial reduction dynamics of perfluoroalkyl substances (PFASs) by the hydrated electron, e aq − , is a topic of great interest and importance due to the…”
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12
Surprising Stability of Cubane under Extreme Pressure
Published in The journal of physical chemistry letters (19-04-2018)“…The chemical stability of solid cubane under high-pressure was examined with in situ Raman spectroscopy and synchrotron powder X-ray diffraction (PXRD) in a…”
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13
Synthesis and Structure of Sn14Cl6(CH2SiMe3)12: Toward Nanoclusters of 4‑Coordinate α‑Sn
Published in Inorganic chemistry (07-05-2018)“…Orange crystals of a Sn14 cluster have been isolated in up to 22% yield from a reaction between Me3SiCH2SnCl3, SnCl4, and LiAlH4. The structure determined by…”
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Submicron-thick single anion-conducting polymer electrolytes
Published in RSC applied interfaces (14-05-2024)“…Non-line-of-sight techniques are well suited for fabrication of thin and conformal solid-state electrolyte (SSE) coatings, especially within…”
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15
Synthesis and Structure of Sn 14 Cl 6 (CH 2 SiMe 3 ) 12 : Toward Nanoclusters of 4-Coordinate α-Sn
Published in Inorganic chemistry (07-05-2018)“…Orange crystals of a Sn cluster have been isolated in up to 22% yield from a reaction between Me SiCH SnCl , SnCl , and LiAlH . The structure determined by…”
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16
From Linear Molecular Chains to Extended Polycyclic Networks: Polymerization of Dicyanoacetylene
Published in Chemistry of materials (22-08-2017)“…Dicyanoacetylene (C4N2) is an unusual energetic molecule with alternating triple and single bonds (think miniature, nitrogen-capped carbyne), which represents…”
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Non-line-of-sight synthesis and characterization of a conformal submicron-thick cationic polymer deposited on 2D and 3D substrates
Published in RSC applied interfaces (14-05-2024)“…The non-line-of-sight nature of initiated chemical vapor deposition (iCVD) makes it an amenable technique for depositing thin, conformal polymer films on…”
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Impact of Submicellar Aggregation on Reduction Kinetics of Perfluorooctanoate by the Hydrated Electron
Published in Environmental science & technology letters (08-03-2022)“…Disagreements persist regarding the rate constants for the initial reduction of perfluorooctanoate (PFOA) by the hydrated electron, eaq –, with published…”
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P(CN)3 Precursor for Carbon Phosphonitride Extended Solids
Published in Chemistry of materials (14-07-2015)Get full text
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20
Tetrazolation of Side Chains and Anhydrous Conductivity in a Hydrophobic Polymer
Published in Macromolecules (08-07-2014)“…1H-Tetrazoles possess the lowest pK a within the azole family of nitrogen-containing heterocycles, making them attractive amphoteric moieties for anhydrous…”
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