Search Results - "Chalmers, Brian A"
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Constrained Phosphine Chalcogenide Selenoethers Supported by peri-Substitution
Published in Molecules (Basel, Switzerland) (01-11-2023)“…A series of phosphorus and selenium peri-substituted acenaphthene species with the phosphino group oxidized by O, S, and Se has been isolated and fully…”
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Synthesis and Structural Studies of peri -Substituted Acenaphthenes with Tertiary Phosphine and Stibine Groups
Published in Molecules (Basel, Switzerland) (18-04-2024)“…Two mixed -substituted phosphine-chlorostibines, Acenap(P Pr )(SbPhCl) and Acenap(P Pr )(SbCl ) (Acenap = acenaphthene-5,6-diyl) reacted cleanly with Grignard…”
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3
(E)-1-(2,5-Dimethylphenyl)-3-phenylprop-2-en-1-one
Published in MolBank (01-08-2024)“…X-ray crystallography has been used to characterize the title compound for the first time; 1H NMR, 13C NMR and IR spectroscopic data have also been updated…”
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4
Structural, Spectroscopic and Computational Examination of the Dative Interaction in Constrained Phosphine-Stibines and Phosphine-Stiboranes
Published in Chemistry : a European journal (11-05-2015)“…A series of phosphine–stibine and phosphine–stiborane peri‐substituted acenaphthenes containing all permutations of pentavalent groups SbClnPh4–n (5–9), as…”
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5
Synthetic and Structural Study of peri -Substituted Phosphine-Arsines
Published in Molecules (Basel, Switzerland) (28-11-2021)“…A series of phosphorus-arsenic -substituted acenaphthene species have been isolated and fully characterised, including single crystal X-ray diffraction…”
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6
Geminally Substituted Tris(acenaphthyl) and Bis(acenaphthyl) Arsines, Stibines, and Bismuthine: A Structural and Nuclear Magnetic Resonance Investigation
Published in Inorganic chemistry (18-07-2016)“…Tris(acenaphthyl)- and bis(acenaphthyl)-substituted pnictogens (iPr2P-Ace)3E (2–4) (E = As, Sb, or Bi; Ace = acenaphthene-5,6-diyl) and (iPr2P-Ace)2EPh (5…”
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Geometrically Enforced Donor-Facilitated Dehydrocoupling Leading to an Isolable Arsanylidine-Phosphorane
Published in Journal of the American Chemical Society (30-04-2014)“…A proximate Lewis basic group facilitates the mild dehydrogenative P–As intramolecular coupling in the phosphine-arsine peri-substituted acenaphthene 3,…”
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8
Phosphine–Stibine and Phosphine–Stiborane peri-Substituted Donor–Acceptor Complexes
Published in MolBank (01-06-2023)“…Two novel Sb(III) and Sb(V) peri-substituted acenaphthene phosphorus−antimony compounds were prepared. The Sb(III) compound, 1, was prepared via reacting the…”
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9
Reactivity Profile of a Peri-Substitution-Stabilized Phosphanylidene-Phosphorane: Synthetic, Structural, and Computational Studies
Published in Inorganic chemistry (07-07-2014)“…The reactions of peri-substitution-stabilized phosphanylidene-phosphorane 1 with [AuCl(tht)] or [PtCl2(cod)] afford binuclear complexes [((1)(AuCl)2)2] 2 and…”
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10
(Decacarbonyl)(1-isopropyl-2-phenyl-1,2,5,6-tetrahydroacenaphtho [5,6-cd][1,2]diphosphole)ditungsten(0)
Published in MolBank (01-06-2023)“…A binuclear tungsten(0) complex with an asymmetric bridging 1,2-diphosphole ligand was prepared by the photolysis of tungsten hexacarbonyl in the presence of…”
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11
Catena-[Triaquabis(μ2-1,4-bis(diphenylphosphoryl)butane)nitrato-κ2O-praseodymium(III)] Nitrate Monohydrate Methanol Solvate
Published in MolBank (01-09-2024)“…The bidentate ligand, 1,4-bis(diphenlyphosphoryl)butane (dppbO2), was used to prepare a 1D polymeric Pr(III) complex which was characterised by single-crystal…”
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12
Heteronuclear Bimetallic Complexes with 3d and 4f Elements
Published in MolBank (01-03-2023)“…Three heteronuclear bimetallic complexes [Cu(MeOH)(L)Ln(NO3)3] (1-Ce; Ln = Ce, 1-Pr; Ln = Pr, and 1-Nd; Ln = Nd) were prepared using H2L…”
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9,14-Diphenyl-9,9a,10,13,13a,14-hexahydro-9,14:10,13-dimethanobenzo[f]tetraphen-15-one
Published in MolBank (01-12-2022)“…X-ray crystallography has been used to characterise the title compound for the first time, 1H NMR, 13C NMR and IR spectroscopic data has also been updated from…”
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14
(9R,9aS,12aR,13S)-9,13-Diphenyl-9,9a,12a,13-tetrahydro-9,13-methanotriphenyleno[2,3-c]furan-10,12,14-trione
Published in MolBank (01-09-2022)“…X-ray crystallography was used to characterise the title compound for the first time, and the 1H NMR, 13C NMR and IR spectroscopic data from earlier reports…”
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15
Sterically Restricted Tin Phosphines, Stabilized by Weak Intramolecular Donor–Acceptor Interactions
Published in Organometallics (27-05-2014)“…Four related sterically restricted peri-substituted acenaphthenes have been prepared containing mixed tin–phosphorus moieties in the proximal 5,6-positions…”
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Phosphine and Selenoether peri-Substituted Acenaphthenes and Their Transition-Metal Complexes: Structural and NMR Investigations
Published in Inorganic chemistry (02-10-2023)“…A series of peri-substituted acenaphthene-based phosphine selenoether bidentate ligands Acenap(iPr2P)(SeAr) (L1–L4, Acenap = acenaphthene-5,6-diyl, Ar = Ph,…”
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17
Dealkanative Main Group Couplings across the peri-Gap
Published in Journal of the American Chemical Society (27-12-2017)“…Here, we highlight the ability of peri-substitution chemistry to promote a series of unique P–P/P–As coupling reactions, which proceed with concomitant C–H…”
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18
A Study of Through-Space and Through-Bond J PP Coupling in a Rigid Nonsymmetrical Bis(phosphine) and Its Metal Complexes
Published in Inorganic chemistry (19-03-2018)“…A series of representative late d-block metal complexes bearing a rigid bis(phosphine) ligand, iPr2P-Ace-PPh2 (L, Ace = acenaphthene-5,6-diyl), was prepared…”
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19
Peri-Substituted Phosphorus–Tellurium Systems–An Experimental and Theoretical Investigation of the P···Te through-Space Interaction
Published in Inorganic chemistry (02-03-2015)“…A series of peri-substituted phosphorus–tellurium systems R′Te–Acenap–PR2 (R′ = Ph, p-An, Nap, Mes, Tip; Acenap = acenaphthene-5,6-diyl (–C12H8); R = i Pr, Ph)…”
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Simple and Inexpensive Method for the Detection of Carbon Monoxide Released from Thermal Cheletropic Decarbonylation Reactions
Published in Journal of chemical education (09-11-2021)“…This work presents a simple protocol that demonstrates the use of an inexpensive household carbon monoxide detector as a useful tool to detect the release of…”
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