HMDST as Useful Tool in Organic Synthesis: A Further Step in the Delivery of Sulfur Functionalities

Bis(trimethylsilyl)sulfide (HMDST) was demostrated to be a very efficient reagent in the delivery of sulfur functionalities, allowing us to synthesize a wide range of thiocarbonyl compounds. The most reactive derivatives were trapped with suitable dienes, leading to the synthesis of different hetero...

Full description

Saved in:

Bibliographic Details
Published in:	Phosphorus, sulfur, and silicon and the related elements Vol. 180; no. 5-6; pp. 1247 - 1251
Main Authors:	Capperucci, Antonella, Degl'Innocenti, Alessandro, Nocentini, Tiziano, Castagnoli, Giulio, Malesci, Irene, Cerreti, Arianna
Format:	Journal Article
Language:	English
Published:	Taylor & Francis Group 02-03-2005
Subjects:	Cycloadditions heterocycles silyl sulfides thiocarbonyl componds
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Description
Summary:	Bis(trimethylsilyl)sulfide (HMDST) was demostrated to be a very efficient reagent in the delivery of sulfur functionalities, allowing us to synthesize a wide range of thiocarbonyl compounds. The most reactive derivatives were trapped with suitable dienes, leading to the synthesis of different heterocyclic molecules with an high degree of chemo- and regioselectivity. Recently, the mildness of this methodology also allowed us to obtain particularly reactive thiooxocompounds, such as thioformylsilanes, α,β-unsaturated thioaldehydes, thioketones, thioacylsilanes, and thioacylstannanes.
ISSN:	1042-6507 1563-5325
DOI:	10.1080/10426500590911430