Search Results - "Caulton, K. G"

Influence of the [2.1.1]-(2,6)-Pyridinophane Macrocycle Ring Size Constraint on the Structure and Reactivity of Copper Complexes by Vedernikov, A. N, Pink, M, Caulton, K. G

“…The macrocycle [2.1.1]-(2,6)-pyridinophane (L) binds to CuCl to give a monomeric molecule with tridentate binding of the ligand but in a distorted tetrahedral…”
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Facile C(sp2)/OR Bond Cleavage by Ru or Os by Ferrando, German, Gérard, Hélène, Spivak, Gregory J, Coalter, Joseph N, Huffman, John C, Eisenstein, Odile, Caulton, Kenneth G

“…Os(H)3ClL2 (L = P i Pr3 or P t Bu2Me) are shown to be useful “precursors” to “OsHClL2”, which react with vinyl ethers to form first an η2-olefin adduct and…”
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Synthesis and Thermolytic Behavior of Mixed-Valence Homo- and Heterometallic Group 14 Alkoxides by Teff, D. J, Minear, C. D, Baxter, D. V, Caulton, K. G

“…The mixed-valence molecule SnIISnIV(OiPr)6 is conveniently synthesized and is shown to exchange bridging and terminal alkoxides in solution in its…”
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Assessment of the Bonding in CpRu(PR3)X (X = F, Cl, OSiH3, OCH3) by Bickford, C. C, Johnson, T. J, Davidson, E. R, Caulton, K. G

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C−D0 (D0 = π-donor, F) Cleavage in H2CCH(D0) by (Cp2ZrHCl) n :  Mechanism, Agostic Fluorines, and a Carbene of Zr(IV) by Watson, Lori A, Yandulov, Dmitry V, Caulton, Kenneth G

“…Consistent with the C−O cleavage behavior of vinyl ethers, vinyl fluoride reacts with Cp2ZrHCl to give Cp2ZrFCl and C2H4 as primary products. DFT (B3PW91)…”
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Alcohol elimination chemistry of (CuOtBu)4 by LEMMEN, T. H, GOEDEN, G. V, HUFFMAN, J. C, GEERTS, R. L, CAULTON, K. G

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Facile and Reversible Cleavage of C−F Bonds. Contrasting Thermodynamic Selectivity for RuCF2H vs FOsCFH by Huang, Dejian, Koren, Patrick R, Folting, Kirsten, Davidson, Ernest R, Caulton, Kenneth G

“…In the presence of a catalytic amount of F-(CsF), Me3SiRf (Rf = CF3 and C6F5) exchanges Rf with fluoride of the 16-electron complexes MHF(CO)L2 (M = Ru, Os; L…”
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New Entries to and New Reactions of Fluorocarbon Ligands by Huang, Dejian, Caulton, Kenneth G

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Oxidation of coordinated nitric oxide by free nitric oxide by Gwost, D, Caulton, K. G

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Alcohol elimination chemistry of tetrakis(tert-butoxocopper) by Lemmen, T. H, Goeden, G. V, Huffman, J. C, Geerts, R. L, Caulton, K. G

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New Approach to Ru(II) Pincer Ligand Chemistry. Bis(t ert-butylaminomethyl)pyridine Coordinated to Ruthenium(II) by Gemel, Christian, Folting, Kirsten, Caulton, Kenneth G

“…Reaction of 2,6-bis-( t BuNHCH2)2NC5H3 (“N2py”) with RuCl2(PPh3)3 gives two isomers of Ru(N2py)Cl2(PPh3), 5, while reaction with RuCl2(DMSO)4 (DMSO = Me2SO)…”
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tert-Butyl Is Superior to Phenyl as an Agostic Donor to 14-Electron Ir(III) by Cooper, Alan C, Streib, William E, Eisenstein, Odile, Caulton, Kenneth G

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Spectroscopic assessment of the degree of π-stabilization of unsaturation in RuH(X)CO(PtBu2Me)2 by POULTON, J. T, FOLTING, K, STREIB, W. E, CAULTON, K. G

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Solution behavior of triphenylphosphine complexes of ruthenium(II) by Caulton, K. G

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Acetylene isomerization by manganese(I): preparation and structure of (C5H5)2Mn2(CO)4CCH2 by Folting, K, Huffman, J. C, Lewis, L. N, Caulton, K. G

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Homogeneous hydrogenation of carbon monoxide by Huffman, J. C, Stone, J. G, Krusell, W. C, Caulton, K. G

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Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) by Pinkas, Jiri, Huffman, John C, Baxter, David V, Chisholm, Malcolm H, Caulton, Kenneth G

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Structural determination of [(C5H5)2Mo(H)CO][(C5H5)Mo(CO)3] by Adams, M. A, Folting, K, Huffman, J. C, Caulton, K. G

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Reductive nitrosylation of Group VIIIb compounds by Gwost, D, Caulton, K. G

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Intramolecular rearrangements of M(bidentate phosphine)2XY species by Miller, J. S, Caulton, K. G

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