Search Results - "Castro, Luís C"
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Nickel Catalysts/N,N′-Bidentate Directing Groups: An Excellent Partnership in Directed C–H Activation Reactions
Published in Chemistry letters (05-04-2015)“…This review focuses on chelation-assisted regioselective C–H activation with C–C or/and C–N bond formation using nickel(0) or -(II) as the catalysts, where…”
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Chelation-Assisted Nickel-Catalyzed Oxidative Annulation via Double C−H Activation/Alkyne Insertion Reaction
Published in Chemistry : a European journal (22-01-2016)“…A nickel/NHC system for regioselective oxidative annulation by double C−H bond activation and concomitant alkyne insertion is described. The catalytic reaction…”
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Selective Reduction of Esters to Aldehydes under the Catalysis of Well-Defined NHC-Iron Complexes
Published in Angewandte Chemie International Edition (29-07-2013)“…On a direct course to the aldehyde: Hydrosilylation catalyzed by a well‐defined N‐heterocyclic‐carbene–iron complex under UV irradiation enabled the selective…”
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Metal-Free Borylation of Heteroarenes Using Ambiphilic Aminoboranes: On the Importance of Sterics in Frustrated Lewis Pair C–H Bond Activation
Published in Journal of the American Chemical Society (18-10-2017)“…Two novel frustrated Lewis pair (FLP) aminoboranes, (1-Pip-2-BH2-C6H4)2 (2; Pip = piperidyl) and (1-NEt2-2-BH2-C6H4)2 (3; NEt2 = diethylamino), were…”
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Palladium(II)-Catalyzed ortho-CH Arylation/Alkylation of N-Benzoyl α-Amino Ester Derivatives
Published in Chemistry : a European journal (14-04-2014)“…The palladium‐catalyzed arylation/alkylation of ortho‐CH bonds in N‐benzoyl α‐amino ester derivatives is described. In such a system both the NH‐amido and the…”
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4,4′-Bipyridyl-Catalyzed Reduction of Nitroarenes by Bis(neopentylglycolato)diboron
Published in Organic letters (20-12-2019)“…4,4′-Bipyridyl worked as an organocatalyst for the reduction of nitroarenes by bis(neopentylglycolato)diboron (B2nep2), followed by hydrolysis to give the…”
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Direct Synthesis of Indoles from Azoarenes and Ketones with Bis(neopentylglycolato)diboron Using 4,4′-Bipyridyl as an Organocatalyst
Published in Journal of organic chemistry (19-02-2021)“…Multifunctionalized indole derivatives were prepared by reducing azoarenes in the presence of ketones and bis(neopentylglycolato)diboron (B2nep2) with a…”
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Metal-free borylative dearomatization of indoles: exploring the divergent reactivity of aminoborane C-H borylation catalysts
Published in Chemical science (Cambridge) (14-06-2018)“…While the dearomatization of indoles by carbon-boron bond forming reactions is new and quite promising, they are so far mainly metal-catalyzed. Here, we…”
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Size-Selective Separation of Rare Earth Elements Using Functionalized Mesoporous Silica Materials
Published in ACS applied materials & interfaces (03-07-2019)“…The separation and preconcentration of rare earth elements (REEs) from mineral concentrates in an economically and environmentally sustainable manner are…”
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Practical and Scalable Synthesis of Borylated Heterocycles Using Bench-Stable Precursors of Metal-Free Lewis Pair Catalysts
Published in Organic process research & development (16-11-2018)“…A practical and scalable metal-free catalytic method for the borylation and borylative dearomatization of heteroarenes has been developed. This synthetic…”
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Iron Dihydride Complex as the Pre-catalyst for Efficient Hydrosilylation of Aldehydes and Ketones Under Visible Light Activation
Published in Advanced synthesis & catalysis (01-05-2011)“…A general and efficient hydrosilylation of aldehydes and ketones into the corresponding alcohols using the well‐defined bis(diphenylphosphinoethane)iron…”
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Chronic effects of clofibric acid in zebrafish (Danio rerio): A multigenerational study
Published in Aquatic toxicology (01-03-2015)“…•Clofibric acid (CA) induces multigenerational effects in zebrafish (Danio rerio).•CA impacts fish lipid metabolism, with similarities to those reported in…”
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Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction
Published in European journal of inorganic chemistry (01-08-2012)“…A series of 6 cyclopentadienyl phosphanyl‐pyridine piano‐stool iron complexes was prepared in good yields, characterized, and studied in the catalytic…”
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Iron piano-stool phosphine complexes for catalytic hydrosilylation reaction
Published in Inorganica Chimica Acta (15-01-2012)“…A family of six cyclopentadienyl–iron carbonyl complexes bearing phosphine ligands (PPh3, PMe2Ph and PCy3) with iodide or PF6 as a counter-anion were prepared…”
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Iron-Catalyzed Hydrosilylation of Esters
Published in Advanced synthesis & catalysis (09-07-2012)“…The first hydrosilylation of esters catalyzed by a well defined iron complex has been developed. Esters are converted to the corresponding alcohols at 100 °C,…”
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N‐Heterocyclic Carbene Iron Silyl Hydride Complexes
Published in Israel journal of chemistry (01-12-2017)“…Reaction of N‐heterocyclic carbene iron(0) tetracarbonyl complexes with hydrosilanes (triphenylsilane, methyldiphenylsilane and diphenylsilane) under UV…”
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Brain and testis: more alike than previously thought?
Published in Open biology (01-06-2021)“…Several strands of evidence indicate the presence of marked similarities between human brain and testis. Understanding these similarities and their…”
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NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines
Published in Chemical communications (Cambridge, England) (04-01-2012)“…A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and…”
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La conformación de la frontera chileno-boliviana y los campesinos aymaras durante la chilenización (Tarapacá, 1895-1929)
Published in Historia crítica (Bogotá, Colombia) (2014)“…Mediante documentación administrativa, y en el contexto de la chilenización de la región de Tarapacá y la nueva demarcación fronteriza entre Chile y Bolivia…”
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The Preservation of PPAR γ Genome Duplicates in Some Teleost Lineages: Insights into Lipid Metabolism and Xenobiotic Exploitation
Published in Genes (04-01-2022)“…Three peroxisome proliferator-activated receptor paralogues ( , and ) are currently recognized in vertebrate genomes. PPARγ is known to modulate nutrition,…”
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