Search Results - "Castoldi, L."
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New insights on the adsorption, thermal decomposition and reduction of NOx over Pt- and Ba-based catalysts
Published in Applied catalysis. B, Environmental (01-05-2018)“…[Display omitted] •The adsorption of NO/O2 leads to a fast formation of nitrites.•The nature of the nitrite species depends on the basicity of the adsorption…”
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Oxidation of model soot by NO2 and O2 in the presence of water vapor
Published in Chemical engineering science (14-12-2017)“…[Display omitted] •Model soot (Printex U) oxidation by NO2 and O2 in the presence of H2O.•Soot oxidation initiated by NO2 at low Temperatures.•Synergistic…”
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Pd-Doped SSZ-13 for Low-T NOx Adsorption: an Operando FT-IR Spectroscopy Study
Published in Topics in catalysis (01-08-2023)“…In this study, mechanistic aspects of NO adsorption/desorption over a home-made Pd/SSZ-13 passive NOx adsorber (PNA) catalyst are investigated. Operando FT-IR…”
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In-depth insights into N2O formation over Rh- and Pt-based LNT catalysts
Published in Catalysis today (15-01-2019)“…[Display omitted] •NO can disproportionate to N2O over reduced metal sites.•N2O formation from NO is favored at low temperatures and with poorly reactive…”
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Mechanistic aspects of the release and the reduction of NOx stored on Pt–Ba/Al2O3
Published in Journal of catalysis (01-08-2015)“…[Display omitted] •The NOx release is not driven by the ads–des equilibrium of stored NOx.•15NO isotopic exchange allows decoupling NOx release from its…”
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Pathways for N2O Formation/Reduction During Operation of Commercial LNT Catalysts
Published in Topics in catalysis (01-02-2019)“…In this study the pathways involved in N 2 O formation over a commercial LNT catalyst are addressed, when using H 2 as a reductant. For this purpose, flow…”
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Storage and Reduction of NO x Over LNT Catalysts
Published in Catalysis letters (01-02-2015)“…In this paper, fundamental issues of the NSR technology are addressed. The reaction paths and the mechanism involved in the storage of NOx and the relevance of…”
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On the activity and stability of Pt-K/Al2O3 LNT catalysts for diesel soot and NOx abatement
Published in Applied catalysis. B, Environmental (01-01-2014)“…•The soot decreases the NOx storage activity of Pt-K/Al2O3 catalyst at any temperature in the range 250–350°C.•The stability of the species stored over…”
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Al2O3-supported Pt/Rh catalysts for NOx removal under lean conditions
Published in Applied catalysis. A, General (05-07-2019)“…[Display omitted] •The adsorption of NO/O2 over Pt- and Rh-containing catalysts leads to nitrites at low T and of nitrates at high T.•Pt-based catalysts shows…”
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Study of the effect of Ba loading for catalytic activity of Pt–Ba/Al2O3 model catalysts
Published in Catalysis today (01-10-2004)Get full text
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Soot combustion: Reactivity of alkaline and alkaline earth metal oxides in full contact with soot
Published in Catalysis today (15-07-2008)“…The activity in the soot combustion of K- and Ba-based catalysts in “loose” and “full” contact is investigated in this study. Under loose contact systems…”
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Journal Article Conference Proceeding -
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Catalytic behaviour of hybrid LNT/SCR systems: Reactivity and in situ FTIR study
Published in Journal of catalysis (15-08-2011)“…In the LNT/SCR dual bed during the rich phase the reduction of NO x stored onto LNT catalyst gives NH 3 (I step) and then N 2 (II step). NH 3 slipped from LNT…”
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The NOx storage-reduction on Pt-K/Al2O3 Lean NOx Trap catalyst
Published in Journal of catalysis (15-12-2010)Get full text
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Pt−Ba/Al2O3 NSR Catalysts at Different Ba Loading: Characterization of Morphological, Structural, and Surface Properties
Published in Journal of physical chemistry. C (21-08-2008)“…Morphological, textural, and surface properties of several Pt−Ba/Al2O3 NO x storage reduction (NSR) catalysts at different Ba loading in the range 0−30 wt %…”
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Characterization and reactivity of Ce-promoted PtBa lean NOx trap catalysts
Published in Catalysis today (15-12-2012)“…HRTEM image of the Ce-doped PtBa/Al2O3 catalyst. [Display omitted] ► The presence of Ce does not alter the morphological characteristics of PtBa/Alumina…”
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The influence of CO2 and H2O on the storage properties of Pt-Ba/Al2O3 LNT catalyst studied by FT-IR spectroscopy and transient microreactor experiments
Published in Catalysis today (01-08-2014)“…•The effect of CO2 and H2O on the NOx storage on PtBa/Al2O3 is investigated.•NOx are stored on PtBa catalysts as nitrites and nitrates.•CO2 inhibits nitrite…”
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Effect of potassium on a model soot combustion: Raman and HRTEM evidences
Published in Aerosol science and technology (02-04-2016)“…The effect of potassium on the oxidation of a model carbonaceous material (Printex U, namely, soot for brevity) has been investigated under isothermal…”
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New Insights on the Release and Reduction of NOx Stored over PGM-Based LNT Catalysts
Published in Topics in catalysis (01-03-2017)“…In this work, we have investigated the release and reduction of NO x (nitrates) stored on Rh–Ba/Al 2 O 3 and Pt–Rh–Ba/Al 2 O 3 catalysts and compared with…”
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Effect of soot on the storage-reduction performances of PtBa/Al₂O₃ LNT catalyst
Published in Catalysis today (01-07-2011)“…The effect of soot on the storage-reduction performances of a PtBa/Al₂O₃ catalyst is investigated in this work. It is found that the presence of soot reduces…”
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NOx Adsorption Over Ce/Zr-Based Catalysts Doped with Cu and Ba
Published in Topics in catalysis (01-02-2019)“…In this study, Ce/Zr-based materials without noble metals in their formulation have been prepared, characterized and tested in NO x adsorption at different…”
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