Search Results - "Castilla, Ana M"
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1
Salen-Complex-Mediated Formation of Cyclic Carbonates by Cycloaddition of CO2 to Epoxides
Published in Angewandte Chemie International Edition (17-12-2010)“…Metal complexes of salen ligands are an important class of compounds, and they have been widely studied in the past. Among their successful catalytic…”
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2
Ligand Aspect Ratio as a Decisive Factor for the Self-Assembly of Coordination Cages
Published in Journal of the American Chemical Society (17-02-2016)“…It is possible to control the geometry and the composition of metallasupramolecular assemblies via the aspect ratio of their ligands. This point is…”
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3
Drying Affects the Fiber Network in Low Molecular Weight Hydrogels
Published in Biomacromolecules (13-11-2017)“…Low molecular weight gels are formed by the self-assembly of a suitable small molecule gelator into a three-dimensional network of fibrous structures. The gel…”
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4
Stereochemical Communication within Tetrahedral Capsules
Published in Chemistry letters (05-03-2014)“…The creation of isolated chirotopic environments that mimic enzyme binding pockets has been a long-term goal in supramolecular chemistry. Metal–organic cages…”
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5
Self-sorted Oligophenylvinylene and Perylene Bisimide Hydrogels
Published in Scientific reports (21-08-2017)“…We describe two component hydrogels with networks composed of self-sorted fibres. The component gelators are based on 1,4-distyrylbenzene (OPV3) and perylene…”
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6
Chemical Signals Turn On Guest Binding through Structural Reconfiguration of Triangular Helicates
Published in Angewandte Chemie International Edition (18-10-2013)“…Be my guest: The function of a system based on self‐assembled ZnII complexes can be controlled by external chemical stimuli. The complexes are based on a…”
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7
Efficient Long-Range Stereochemical Communication and Cooperative Effects in Self-Assembled Fe4L6 Cages
Published in Journal of the American Chemical Society (19-09-2012)“…A series of large, optically active Fe4L6 cages was prepared from linear 5,5′-bis(2-formylpyridines) incorporating varying numbers (n = 0–3) of oligo-p-xylene…”
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8
Covalently Crosslinked Nanogels: An NMR Study of the Effect of Monomer Reactivity on Composition and Structure
Published in Polymers (18-02-2019)“…Covalently crosslinked nanogels are widely explored as drug delivery systems and sensors. Radical polymerization provides a simple, inexpensive, and broadly…”
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9
Stereochemistry in Subcomponent Self-Assembly
Published in Accounts of chemical research (15-07-2014)“…Conspectus As Pasteur noted more than 150 years ago, asymmetry exists in matter at all organization levels. Biopolymers such as proteins or DNA adopt…”
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10
Using Aggregation-Induced Emission to Understand Dipeptide Gels
Published in Gels (09-02-2018)“…We describe the formation of structured liquids and gels from a functionalised dipeptide based on tetraphenylethylene. Tetraphenylethylene is well-known to be…”
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11
Modular Synthesis of Heterobimetallic Salen Structures Using Metal Templation
Published in Organic letters (19-11-2009)“…A modular and general synthetic method is disclosed for nonsymmetrical heterobimetallic bis-salphen structures starting from a series of synthetically…”
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12
DABCO-Directed Self-Assembly of Bisporphyrins (DABCO=1,4-Diazabicyclo[2.2.2]octane)
Published in Chemistry : a European journal (18-03-2005)“…Three isomeric zinc bisporphyrins have been prepared by covalently linking together two aminoporphyrins with an isophthalic acid derivative. The porphyrins…”
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13
Sequence-Dependent Guest Release Triggered by Orthogonal Chemical Signals
Published in Journal of the American Chemical Society (24-02-2016)“…Three ZnII 4L4 coordination cages, assembled from trisiminopyridine ligands, exhibit differences in their guest-binding selectivities and reactivity with…”
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14
Light-Powered Reversible Guest Release and Uptake from Zn4L4 Capsules
Published in Journal of the American Chemical Society (08-02-2023)“…A strategy for light-powered guest release from a tetrahedral capsule has been developed by incorporating azobenzene units at its vertices. A new Zn4L4…”
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15
Post-assembly modification of kinetically metastable Fe(II)2L3 triple helicates
Published in Journal of the American Chemical Society (11-06-2014)“…We report the covalent post-assembly modification of kinetically metastable amine-bearing Fe(II)2L3 triple helicates via acylation and azidation. Covalent…”
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16
Light-Powered Reversible Guest Release and Uptake from Zn 4 L 4 Capsules
Published in Journal of the American Chemical Society (22-02-2023)“…A strategy for light-powered guest release from a tetrahedral capsule has been developed by incorporating azobenzene units at its vertices. A new Zn L…”
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17
Quantification of Stereochemical Communication in Metal-Organic Assemblies
Published in Angewandte Chemie (International ed.) (26-08-2016)“…The derivation and application of a statistical mechanical model to quantify stereochemical communication in metal–organic assemblies is reported. The factors…”
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18
Quantification of Stereochemical Communication in Metal-Organic Assemblies
Published in Angewandte Chemie (26-08-2016)“…The derivation and application of a statistical mechanical model to quantify stereochemical communication in metal–organic assemblies is reported. The factors…”
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19
Chemical Signals Turn On Guest Binding through Structural Reconfiguration of Triangular Helicates
Published in Angewandte Chemie (18-10-2013)Get full text
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20
Metall-Salen-vermittelte Bildung cyclischer Carbonate durch Cycloaddition von CO2 an Epoxide
Published in Angewandte Chemie (17-12-2010)“…Salen‐Metall‐Komplexe bilden eine wichtige Klasse von Verbindungen und wurden in der Vergangenheit ausführlich untersucht. Zu ihren katalytische Anwendungen,…”
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