Positive and negative ion emission from perfluorinated poly-ethers
Positive and negative ion ejection in the mass range below 200 Dalton is observed for perfluorinated poly-ether surfaces subjected to electron- and ion-beam irradiation. The exciting projectiles are Ar + ions of 300 and 4000 eV and electrons of 3000 eV. The main positive ions found are fragments of...
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Published in: | Chemical physics letters Vol. 336; no. 5; pp. 431 - 438 |
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Main Authors: | , , , , , , |
Format: | Journal Article |
Language: | English |
Published: |
Amsterdam
Elsevier B.V
23-03-2001
Elsevier Science |
Subjects: | |
Online Access: | Get full text |
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Summary: | Positive and negative ion ejection in the mass range below 200 Dalton is observed for perfluorinated poly-ether surfaces subjected to electron- and ion-beam irradiation. The exciting projectiles are Ar
+ ions of 300 and 4000 eV and electrons of 3000 eV. The main positive ions found are fragments of CF
3
+ ions. Larger ions are found with lower probability. The main negative ion observed is F. The results show that the liquid–vacuum interface is formed by CF
3 groups from the polymer. |
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ISSN: | 0009-2614 1873-4448 |
DOI: | 10.1016/S0009-2614(01)00119-1 |