Search Results - "Caro, Jürgen"
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A Two‐Dimensional Lamellar Membrane: MXene Nanosheet Stacks
Published in Angewandte Chemie International Edition (06-02-2017)“…Two‐dimensional (2D) materials are promising candidates for advanced water purification membranes. A new kind of lamellar membrane is based on a stack of 2D…”
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High-Flux Vertically Aligned 2D Covalent Organic Framework Membrane with Enhanced Hydrogen Separation
Published in Journal of the American Chemical Society (15-04-2020)“…In this study, we propose a new concept of vertically aligned 2D covalent organic framework (COF) layers forming a membrane for efficient gas separation on the…”
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Covalent Organic Framework–Covalent Organic Framework Bilayer Membranes for Highly Selective Gas Separation
Published in Journal of the American Chemical Society (15-08-2018)“…Covalent organic frameworks (COFs) have been proposed as alternative candidates for molecular sieving membranes due to their chemical stability. However,…”
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MOF-in-COF molecular sieving membrane for selective hydrogen separation
Published in Nature communications (04-01-2021)“…Covalent organic frameworks (COFs) are promising materials for advanced molecular-separation membranes, but their wide nanometer-sized pores prevent selective…”
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Ultra‐Tuning of the Aperture Size in Stiffened ZIF‐8_Cm Frameworks with Mixed‐Linker Strategy for Enhanced CO2/CH4 Separation
Published in Angewandte Chemie International Edition (02-01-2019)“…ZIF‐8 membrane has the potential for CO2/CH4 separation based on size exclusion. But if traditionally prepared by solvothermal methods, it shows only…”
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Balancing the Grain Boundary Structure and the Framework Flexibility through Bimetallic Metal–Organic Framework (MOF) Membranes for Gas Separation
Published in Journal of the American Chemical Society (27-05-2020)“…Separation is one of the most energy-intensive processes in the chemical industry, and membrane-based separation technology helps to reduce the energy…”
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Steam-Stable Zeolitic Imidazolate Framework ZIF-90 Membrane with Hydrogen Selectivity through Covalent Functionalization
Published in Journal of the American Chemical Society (10-11-2010)“…A novel covalent functionalization strategy was developed to prepare reproducible ZIF-90 molecular sieve membranes by using 3-aminopropyltriethoxysilane as a…”
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Covalent Post-Functionalization of Zeolitic Imidazolate Framework ZIF-90 Membrane for Enhanced Hydrogen Selectivity
Published in Angewandte Chemie International Edition (16-05-2011)“…MOF constrictor: Covalent modification of a ZIF‐90 membrane was achieved by imine condensation of the aldehyde groups of the metal–organic framework (MOF)…”
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Bio-Inspired Polydopamine: A Versatile and Powerful Platform for Covalent Synthesis of Molecular Sieve Membranes
Published in Journal of the American Chemical Society (27-11-2013)“…Inspired by the bioadhesive ability of the marine mussel, a simple, versatile, and powerful synthesis strategy was developed to prepare highly reproducible and…”
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Water Transport with Ultralow Friction through Partially Exfoliated g‐C3N4 Nanosheet Membranes with Self‐Supporting Spacers
Published in Angewandte Chemie International Edition (24-07-2017)“…Two‐dimensional (2D) graphitic carbon nitride (g‐C3N4) nanosheets show brilliant application potential in numerous fields. Herein, a membrane with artificial…”
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High‐Flux Membranes Based on the Covalent Organic Framework COF‐LZU1 for Selective Dye Separation by Nanofiltration
Published in Angewandte Chemie International Edition (03-04-2018)“…Covalent organic frameworks (COFs) are attractive candidates for advanced water‐treatment membranes owing to their high porosity and well‐organized channel…”
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Bicontinuous Zeolitic Imidazolate Framework ZIF-8@GO Membrane with Enhanced Hydrogen Selectivity
Published in Journal of the American Chemical Society (22-10-2014)“…Through layer-by-layer (LBL) deposition of a graphene oxide (GO) suspension on a semicontinuous ZIF-8 layer, we have developed a novel bicontinuous ZIF-8@GO…”
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Bioinspired Ti3C2Tx MXene‐Based Ionic Diode Membrane for High‐Efficient Osmotic Energy Conversion
Published in Angewandte Chemie International Edition (10-10-2022)“…Bioinspired asymmetric nanofluidic ion channels with ionic diode behavior that can boost the osmotic energy (so‐called blue energy) conversion are highly…”
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Remarkably Enhanced Gas Separation by Partial Self-Conversion of a Laminated Membrane to Metal-Organic Frameworks
Published in Angewandte Chemie International Edition (02-03-2015)“…Separation methods based on 2D interlayer galleries are currently gaining widespread attention. The potential of such galleries as high‐performance…”
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In Situ Synthesis of MOF Membranes on ZnAl-CO3 LDH Buffer Layer-Modified Substrates
Published in Journal of the American Chemical Society (15-10-2014)“…We develop here a urea hydrolysis method to in situ prepare asymmetric ZnAl-CO3 layered double hydroxide (LDH) buffer layers with various stable equilibrium…”
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Ultrathin Covalent Organic Framework Membranes Prepared by Rapid Electrophoretic Deposition
Published in Advanced materials (Weinheim) (01-11-2022)“…Covalent organic frameworks (COFs) are a disruptive material platform for various novel applications including nanofiltration for water purification due to…”
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Metal–Organic Framework UiO-66 Layer: A Highly Oriented Membrane with Good Selectivity and Hydrogen Permeance
Published in ACS applied materials & interfaces (12-04-2017)“…The 3D metal–organic framework (MOF) structure UiO-66 [Zr6O4(OH)4(bdc)6], featuring triangular pores of approximately 6 Å, has been successfully prepared as a…”
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Highly Selective CO2 Conversion to Methanol in a Bifunctional Zeolite Catalytic Membrane Reactor
Published in Angewandte Chemie International Edition (09-08-2021)“…The hydrogenation of sequestrated CO2 to methanol can reduce CO2 emission and establish a sustainable carbon circuit. However, the transformation of CO2 into…”
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Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis
Published in Journal of the American Chemical Society (11-11-2009)“…A zeolitic imidazolate framework (ZIF-8) as member of the metal−organic framework family has been crystallized as a thin porous layer on an asymmetric ceramic…”
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Engineering of Defective MOF‐801 Nanostructures within Macroporous Spheres for Highly Efficient and Stable Water Harvesting
Published in Advanced materials (Weinheim) (01-08-2023)“…Water harvesting using the metal‐organic framework (MOF)‐801 is restricted by limited working capacity, powder structuring, and finite stability. To overcome…”
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